2018 Publications

• Mouat, A.R.; Whitford, C.; Chen, B.R.; Perras, F.A.; Pruski, M.; Bedzyk, M.J.; Delferro, M.; Stair, P.C.; Marks, T.J.; Synthesis of Supported Pd0 Nanoparticles from a Single-Site Palladium Surface Complex by Alkene Reduction, Chem. Mater. 2018, 30, 1032-1044. DOI: 10.1021/acs.chemmater.7b04909.

• Islam, S.M.; Peng, L.; Zeng, L.; Malliakas, C.D.; Chung, D.D.Y.; Buchholz, D.B.; Chasapis, T.; Li, R.; Chrissafis, K.; Medvedeva, J.E.; Trimarchi, G.G.; Grayson, M. Marks, T.J.; Bedzyk, M.J.; Chang, R.P.H.; Dravid, V.P.; Kanatzidis, M.G.; Multi-Level Switching in Phase Change K2Sb8Se13, J. Amer. Chem. Soc. 2018, 140,9261–9268. DOI: 10.1021/jacs.8b05542.

• Gao, Y.; Chen, X.; Zhang, J.; Chen, J.; Motta, A.; Lohr, T.L.; Marks, T.J. Catalyst Nuclearity Effects on Stereo- and Regio-Induction in Pyridylamido-Hafnium-Catalyzed Propylene and 1-Octene Polymerizations. Macromolecules 2018, 51, 2401-2410. DOI: 10.1021/acs.macromol.8b00181.

• Wang, G.; Eastham, N.D.; Aldrich, T.J.; Ma, B.; Manley, E.F.; Chen, Z.; Chen, L.X.; Olvera de la Cruz, M.; Chang, R.P.H.; Facchetti, A.; Marks, T.J.; Photoactive Blend Morphology Engineering through Tunable Aggregation in All-Polymer Solar Cells, Advan. Energy Mater. 2018, 8, 1702173. DOI: 10.1002/aenm.201702173.

• Stalzer, M.M.; Lohr, T.L.; Marks, T.J.; Synthesis, Characterization, and Volatility Properties of N-alkyl β-Diketiminate Manganese Complexes, Inorg. Chem.2018, 57,3017–3024. DOI: 10.1021/acs.inorgchem.7b02476

• Eastham, N.D.; Logsdon, J.L.; Manley, E.F.; Aldrich, T.J.; Leonardi, M.J.; Wang, G.; Powers-Riggs, N.E.; Young, R.M.; Chen, L.X.; Wasielewski, M.R.; Melkonyan, F.S.; Chang, R.P.H.; Marks, T.J.; Hole-Transfer Dependence on Energy Level Alignment and Blend Morphology in Polymer:ITIC Photovoltaics, Advan. Mater. 2018, 30, 1704263. DOI: 10.1002/adma.201704263.

• Chen, J.; Liao, Q.; Wang, G.; Yan, Z.; Wang, H.; Wang, Y.; Zhang, X.; Facchetti, A.; Marks, T.J.; Guo, X.; Improving Photovoltaic Performance of Polymer Semiconductors via Optimizing Intramolecular Noncovalent Sulfur-Oxygen Interactions, Macromolecules 2018, 51, 3874–3885. DOI: 10.1021/acs.macromol.8b00161.

• Chen, Y.; Wang, G.; Yang, L.; Wu, J.; Huang, Y.; Lu, Z.; Marks, T.J.; Facchetti, A.;  Novel Unsymmetric Squaraine-Based Small Molecules for Organic Solar Cells, J. Mater. Chem. C. 2018, 6, 847-854. DOI: 10.1039/c7tc04639a

• Guo, P.; Diroll, B.T.; Huang, W.; Zeng, L.; Wang, B.; Bedzyk, M.J.; Facchetti, A.; Marks, T.J.; Chang, R.P.H.; Schaller, R.D.; Low-Loss Near-Infrared Hyperbolic Metamaterials with Epitaxial ITO/In2O3 Multilayers, ACS Photonics, 2018, 5, 2000–2007. DOI: 10.1021/acsphotonics.7b01485.

• Ke, W.; Priyanka, P.; Vegiraju, S.; Stoumpos, C.; Spanopoulos, I.; Soe, C.; Marks, T.J.; Chen, M.-C.; Kanatzidis, M.; Dopant-Free Tetrakis-triphenylamine Hole Transporting Material for Efficient Tin-Based Perovskite Solar Cells, J. Amer. Chem. Soc. 2018, 140, 388–393. DOI: 10.1021/jacs.7b10898.

• Kwon, S.M.; Won, J.; Jo, J.-W.; Kim, J.; Kim, H.-J.; Kwon, H.; Kim, J.; Ahn, S.; Kim, Y.-H.; Lee, M.-J.; Lee, H.; Marks, T.J.; Kim, M.-G.; Park, S.K.; High-Performance and Scalable Metal-Chalcogenide Semiconductors and Devices via Chalco-Gel Routes, Science Advances, 2018, 4, eaap9104. DOI: 10.1126/sciadv.aap9104

• Wang, B.; Huang, W.; Chi, L.; Al-Hashimi, M.; Marks, T.J.; Facchetti, A.; High-k Gate Dielectrics for Emerging Flexible and Stretchable Electronics, Chem. Rev. 2018, 118, 5690-5754.  DOI: 10.1021/acs.chemrev.8b00045.

• Senanayak, S.; Sangwan, V.; McMorrow, J.; Everaerts, K.; Chen, Z.; Facchetti, A.; Hersam, M.; Marks, T. J.; Narayan, K.; Self-Assembled Photochromic Molecular Dipoles for High Performance Polymer Thin-Film Transistors, ACS Appl. Mater. Interfaces, 2018, 10, 21492-21498. DOI: 10.1021/acsami.8b05401.

• Huang, W.; Zhuang, X.; Melkonyan, F.S.; Wang, B.; Zeng, L.; Wang, G.; Han, S.; Bedzyk, M.; Yu, J.; Marks, T.J.; Facchetti, A.; UV/Ozone Induced Interfacial Trap Effects in Organic Transistors for High-Sensitivity NO2 Detection, Advan. Mater. 2018, in press. DOI: 10.1002/adma.201701706.

• Swick, S.M.; Zhu, W.; Matta, M.; Aldrich, T.J.; Harbuzaru, A.; Navarrete, J.T.L.; Ortiz, R.P.; Kohlstedt, K.L.; Schatz, G.C.; Facchetti, A.; Melkonyan, F.S.; Marks, T.J.; Low Reorganization Energy π-Extended Post-Fullerene Acceptors for Organic Solar Cells, PNAS, 2018, 115, E8341-E8348. DOI:10.1073/pnas.1807535115.

• Huang, W.; Guo, P.; Zeng, L.; Li, R.; Wang, B.; Wang, G.; Zhang, X.; Chang, R.P.H.; Yu, J.; Bedzyk, M.J.; Marks, T.J.; Facchetti, A.; Metal Composition and Polyethylenimine Doping Capacity Effects on Semiconducting Metal Oxide-Polymer Blend Charge Transport, J. Amer. Chem. Soc., 2018, 140, 5457–5473. DOI: 10.1021/jacs.8b01252.

• Zhang, J.; Motta, A.; Gao, Y.; Stalzer, M.; Delferro, M.; Liu, B.; Lohr, T.; Marks, T.J.; Cationic Pyridylamido Adsorbate on Brønsted Acidic Sulfated Zirconia: A Molecular Supported Organohafnium Catalyst for Olefin Homo- and Co-Polymerization, ACS Catalysis, 2018, 8, 4893–4901. DOI: 10.1021/acscatal.8b00611.

• Zeng, L.; Turrisi, R.; Fu, B.; Emery, J.D.; Walker, A.R.; Ratner, M.A.; Hersam, M.C.; Facchetti, A.F.; Marks, T.J.; Bedzyk, M.J.; Measuring Dipole Inversion in Self-Assembled Nano-Dielectric Molecular Layers, ACS Appl. Mater. Interfac., 2018, 10, 6484–6490. DOI: 10.1021/acsami.7b16160.

• Wang, S.; Sun, H.; Erdmann, T.; Wang, G.; Fazzi, D.; Lappan, U.; Chen, Z.; Berggren, M.; Crispin, X.; Kiriy, A.; Voit, B.; Marks, T.J.; Fabiano, S.; Facchetti, A.; A chemically doped naphtalenediimide–bithiazole polymer for n-type organic thermoelectrics, Advan. Mater. 2018, 30, 1801898. DOI: 10.1002/adma.201801898.

• Zhang, X.; Wang, B.; Huang, W.; Zeng, L.; Wang, G.; Zhu W.; Chen, Y.; Bedzyk, M.J.; Zhang, W.; Medvedeva, J.E.; Facchetti, A.; Marks, T.J.; Boron Doping in Solution-Processed Metal Oxide Films for High-Performance Thin-Film Transistors–Theory and Experiment, J.Amer. Chem. Soc. 2018, 140, 12501–12510. DOI: 10.1021/jacs.8b06395.

• Gili, A.; Schlicker, L.; Bekheet, M.; Görke, O.; Penner, S.; Grünbacher, M.; Götsch, T.; Littlewood, P.; Marks, T.J.; Stair, P.; Schomäcker, R.; Doran, A.; Selve, S.; Simon, U.; Gurlo1, A.; Surface carbon as chemical intermediate towards syngas on the Ni/MnO catalyst for the dry reforming of methane, ACS Catalysis, 2018, 8,  8739–8750. DOI: 10.1021/acscatal.8b01820.

• Moody, M.J.; Henning, A.; Jurca, T.; Shang, J.Y.; Bergeron, H.; Balla, I.; Olding, J.N.; Weiss, E.A.; Hersam, M.C.; Lohr, T.L.; Marks, T.J.; Lauhon, L.J.; Atomic Layer Deposition of Molybdenum Oxides with Tunable Stoichiometry Enables Controllable Doping of MoS2 Chem. Mater. 2018, 30, 3628-3632. DOI: 10.1021/acs.chemmater.8b01171.

• Lou, A. J.-T.; Righetto, S.; Barger, C.; Zuccaccia, C.; Cariati, E.; Macchioni, A.; Marks, T.J.; Benzzolium-Based Twisted Chromophores: Large Hyperpolarizability and Reduced Sensitivity to Polar Environments, J.Amer. Chem. Soc. 2018, 140, 8746–8755. DOI: 10.1021/jacs.8b04320

• Manley, E.F.; Harschneck, T.; Eastham, N.D.; Leonardi, M.J.; Zhou, N.; Chang, R.P.H.; Chen, L.X.; Marks, T.J.; Side Chain and Solvent Direction of Morphology in Small-Molecule Organic Solar Cell Film Formation. In-Situ Microstructure Analysis, Advan. Energy Mater.  2018, 1800611.  DOI:10.1002/aenm.201800611.

• Chen, Y.; Wang, B.; Huang, W.; Zhang, X.; Wang, G.; Leonardi, M.; Huang, Y.; Lu, Z.; Marks, T.J.; Facchetti, A.; Nitroacetylactone as a (co)Fuel for the Combustion Synthesis of High-Performance Indium-Gallium-Zinc Oxide Transistors, Chem. Mater. 2018, in press. DOI: 10.1021/acs.chemmater.8b00663

• Zeng, L.; Moghadam, M.M; Buchholz, D.B.; Li, R.; Keane, D.T.; Dravid, V.P.; Chang, R.P.H.; Voorhees, P.W.; Marks, T.J.; Bedzyk, M.J.; Processing-Dependent Thermal Stability of a Prototypical Amorphous Metal Oxide, Phys. Rev. Mater. 2018, 2, 053401-053410. DOI: 10.1103/PhysRevMaterials.2.053401.

• Invergo, A.M.; Liu, S.; Mouat, A.R.; Delferro, M.; Lohr, T.L.; Marks, T.J.  How Close is too Close?  Polymerization Behavior and Monomer Dependent Reorganization of a Bimetallic Salphen Organotitanium Catalyst, Organometallics 2018, 37, 2429–2436. DOI 10.1021/acs.organomet.8b00220.

• Aldrich, T.J.; Dudnik, A.S.; Eastham, N.D.; Manley, E.F.; Chen, L.X.; Chang, R.P.H.; Melkonyan, F.S.; Facchetti, A.; Marks, T.J.; Defect Identification and Suppression in the Environmentally Benign Tin-Free Catalytic Synthesis of Photovoltaic Copolymers, Macromolecules 2018, 51, 9140–9155.DOI: 10.1021/acs.macromol.8b02297.

• Shen, D.; Wang, G.; Liu, Z.; Li, P.; Cai, K.; Cheng, C.; Shi, Y.; Han, J.-M.; Kung, C.-W.; Shi, Y. Gong, X.; Chen, H.; Botros, Y.Y.; Facchetti, A.; Farha, O.K.; Marks, T.J.; Stoddart, J.F.; Epitaxial Growth of CD-MOFs Based on a Host-Guest Strategy, J.Amer. Chem. Soc.  2018, 140, 11402–11407. DOI: 10.1021/jacs.8b06609

• Lou, A. J.-T.; Righetto, S.; Cariati, E.; Marks, T.J.; Organic Salts Enhance the Large Hyperpolarizability of a Halochromic π-Twisted Chromophore, Chem. Eur. J.  2018, 24, 15801-15805.  DOI:org/10.1002/chem.201804365.

• He, X.; Lu, J.; Desanker, M.; Invergo, A.M.; Lohr, T.L.; Ren, N.; Lockwood, F.E.; Marks, T.J.; Chung, Y.-W.; Wang, Q.J.; Boundary Lubrication Mechanisms for High-Performance Friction Modifiers, ACS Appl. Mater. Interfaces, 2018, 10, 40203–40211.  DOI: 10.1021/acsami.8b11075.

• Lou, S.J.; Zhou, N.; Guo, X.; Chang, R.P.H.; Marks, T.J.; Chen, L.X.; Effects of 1,8-Diiodooctane on Domain Nanostructure and Charge Separation Dynamics in PC71BM-Based Bulk Heterojunction Solar Cells, J. Mater. Chem. A, 2018, 6, 23805 – 23818. DOI: 10.1039/C8TA06865H.

• Wang, G.; Melkonyan, F.; Facchetti, A.; Marks, T.J.; All-Polymer Solar Cells: Recent Progress, Challenges, and Perspectives, Angew. Chem. Int. Ed. 2018, in press. DOI: org/10.1002/ange.201808976.

• Chen, Y.; Yang, L.; Wu, J.; Wang, G.; Huang, W.; Melkonyan, F.; Lu, Z.; Huang, Y.; Marks, T.J.; Facchetti, A.; Performance, Morphology, and Charge Recombination Correlations in Ternary Squaraine Solar Cells, Chem. Mater. 2018, 30, 6810–6820. DOI: 10.1021/acs.chemmater.8b02746.

• Guo, P.; Huang, W.; Stoumpos, C.C.; Mao, L.; Gong, J.; Zeng, L.; Diroll, B.T.; Xia, Y.; Ma, X.; Gosztola, D.J.; Xu, T.; Ketterson, J.B.; Bedzyk, M.J.; Facchetti, A.; Marks, T.J.; Kanatzidis, M.G.; Schaller, R.D.; Hyperbolic Dispersion Arising from Anisotropic Excitons in Two-Dimensional Perovskites, Phys. Rev. Lett., 2018, 121, 127401.

• Littlewood, P.; Weitz, E.; Marks, T.J.; Stair, P.C.; Kinetic Isoconversion Loop Catalysis (KILCat): A Reactor Operation Mode to Investigate Slow Catalyst Deactivation Processes, with Ni/Al2O3 for the Dry Reforming of Methane, Indust. Eng. Chem. 2018, in press. DOI: 10.1021/acs.iecr.8b04320.

• Moffitt, S.L.; Ma, Q.; Buchholz, D.B.; Chang, R.P.H.; Mason, T.O.; Marks, T.J.; Bedzyk, M.J.; Surface chemistry and stability of amorphous Zn-Sn-O thin films, J. Phys. Chem. C, 2018, 122 , 28151–28157. DOI: 10.1021/acs.jpcc.8b09412.

• Zhang, X.; Wang, B.; Huang, W.; Wang, G.; Zhu, W.; Wang, Z.; Zhang, W.; Facchetti, A.; Marks, T.J.; Oxide-Polymer Heterojunction Diodes with a Nanoscopic Phase Separated Insulating Layer, NanoLetters 2018, in press. DOI: 10.1021/acs.nanolett.8b04284.