2013 Publications

• Liu, S.; Motta, A.; Delferro, M.; Marks, T. J., Synthesis, Characterization, and Heterobimetallic Cooperation in a Titanium-Chromium Catalyst for Highly Branched Polyethylenes. J. Am. Chem. Soc., 2013, 135, 8830-8833.

• Assary, R. S.; Atesin, A. C.; Li, Z.; Curtiss, L. A.; Marks, T. J., Reaction Pathways and Energetics of Etheric C-O Bond Cleavage Catalyzed by Lanthanide Triflates. ACS Catal., 2013, 3, 1908-1914.

• Fredin, L. A.; Li, Z.; Lanagan, M. T.; Ratner, M. A.; Marks, T. J., Substantial Recoverable Energy Storage in Percolative Metallic Aluminum-Polypropylene Nanocomposites. Adv. Funct. Mater., 2013, 23, 3560-3569.

• Fredin, L. A.; Li, Z.; Lanagan, M. T.; Ratner, M. A.; Marks, T. J., Sustainable High Capacitance at High Frequencies: Metallic Aluminum-Polypropylene Nanocomposites. ACS Nano, 2013, 7, 396-407.

• Marks, T. J., Introduction to the “Recent Advances in f-Element Organometallic Chemistry” Special Issue of Organometallics. Organometallics, 2013, 32, 1133-1136.

• Motta, A.; Fragala, I. L.; Marks, T. J., Insight into Group 4 Metallocenium-Mediated Olefin Polymerization Reaction Coordinates Using a Metadynamics Approach. J. Chem. Theory Comput., 2013, 9, 3491-3497.

• Twist, C. P.; Bassanetti, I.; Snow, M.; Delferro, M.; Bazzi, H.; Chung, Y.-W.; Marchio, L.; Marks, T. J.; Wang, Q. J., Silver-Organic Oil Additive for High-Temperature Applications. Tribol. Lett., 2013, 52, 261-269.

• Williams, L. A.; Guo, N.; Motta, A.; Delferro, M.; Fragala, I. L.; Miller, J. T.; Marks, T. J., Surface structural-chemical characterization of a single-site d0 heterogeneous arene hydrogenation catalyst having 100% active sites. Proc. Natl. Acad. Sci. U. S. A., 2013, 110, 413-418.

• Wobser, S. D.; Marks, T. J., Organothorium-catalyzed hydroalkoxylation/cyclization of alkynyl alcohols. Scope, mechanism, and ancillary ligand effects. Organometallics 2013, 32, 2517-2528.

• Wobser, S. D.; Stephenson, C. J.; Delferro, M.; Marks, T. J., Carbostannolysis Mediated by Bis(pentamethylcyclopentadienyl)lanthanide Catalysts. Utility in Accessing Organotin Synthons. Organometallics, 2013, 32, 1317-1327

• Zhu, Q.; Wegener, S. L.; Xie, C.; Uche, O.; Neurock, M.; Marks, T. J., Sulfur as a selective ‘soft’ oxidant for catalytic methane conversion probed by experiment and theory. Nat. Chem., 2013, 5, 104-109.

• Zolper, T.; Li, Z.; Jungk, M.; Stammer, A.; Stoegbauer, H.; Marks, T.; Chung, Y.-W.; Wang, Q., Traction Characteristics of Siloxanes with Aryl and Cyclohexyl Branches. Tribol. Lett., 2013, 49, 301-311.

• Zolper, T. J.; Seyam, A.; Li, Z.; Chen, C.; Jungk, M.; Stammer, A.; Marks, T. J.; Chung, Y.-W.; Wang, Q., Friction and Wear Protection Performance of Synthetic Siloxane Lubricants. Tribol. Lett., 2013, 51, 365-376.

• Zolper, T. J.; Seyam, A. M.; Chen, C.; Jungk, M.; Stammer, A.; Stoegbauer, H.; Marks, T. J.; Chung, Y.-W.; Wang, Q., Energy Efficient Siloxane Lubricants Utilizing Temporary Shear-Thinning. Tribol. Lett., 2013, 49, 525-538.

• Savoie, B. M.; Jackson, N. E.; Marks, T. J.; Ratner, M. A., Reassessing the use of one-electron energetics in the design and characterization of organic photovoltaics. Physical Chemistry Chemical Physics, 2013, 15, 4538-4547.

• Savoie, B. M.; Movaghar, B.; Marks, T. J.; Ratner, M. A., Simple Analytic Description of Collection Efficiency in Organic Photovoltaics. The Journal of Physical Chemistry Letters, 2013, 4, 704-709.

• Bachrach, M.; Morlanes-Sanchez, N.; Marks, T. J.; Notestein, J. M., Hydrodenitrogenation by Pd/Ta-Al2O3 catalysts. Prepr. – Am. Chem. Soc., Div. Energy Fuels, 2013, 58, 1107-1108.

• Bartollini, E.; Seri, M.; Tortorella, S.; Facchetti, A.; Marks, T. J.; Marrocchi, A.; Vaccaro, L., Sustainable synthetic approach to π-conjugated arylacetylenic semiconductors for bulk heterojunction solar cells. RSC Adv., 2013, 3, 9288-9295.

• Behnam, A.; Sangwan, V. K.; Zhong, X.; Lian, F.; Estrada, D.; Jariwala, D.; Hoag, A. J.; Lauhon, L. J.; Marks, T. J.; Hersam, M. C.; Pop, E., High-Field Transport and Thermal Reliability of Sorted Carbon Nanotube Network Devices. ACS Nano, 2013, 7, 482-490.

• Dongaonkar, S.; Loser, S.; Sheets, E. J.; Zaunbrecher, K.; Agrawal, R.; Marks, T. J.; Alam, M. A., Universal statistics of parasitic shunt formation in solar cells, and its implications for cell to module efficiency gap. Energy Environ. Sci., 2013, 6, 782-787.

•  Eaton, S. W.; Shoer, L. E.; Karlen, S. D.; Dyar, S. M.; Margulies, E. A.; Veldkamp, B. S.; Ramanan, C.; Hartzler, D. A.; Savikhin, S.; Marks, T. J.; Wasielewski, M. R., Singlet exciton fission in polycrystalline thin films of a slip-stacked perylenediimide. J. Am. Chem. Soc., 2013, 135 , 14701-14712.

•  Everaerts, K.; Emery, J. D.; Jariwala, D.; Karmel, H. J.; Sangwan, V. K.; Prabhumirashi, P. L.; Geier, M. L.; McMorrow, J. J.; Bedzyk, M. J.; Facchetti, A.; Hersam, M. C.; Marks, T. J., Ambient-Processable High Capacitance Hafnia-Organic Self-Assembled Nanodielectrics. J. Am. Chem. Soc., 2013, 135, 8926-8939.

• Everaerts, K.; Zeng, L.; Hennek, J. W.; Camacho, D. I.; Jariwala, D.; Bedzyk, M. J.; Hersam, M. C.; Marks, T. J., Printed Indium Gallium Zinc Oxide Transistors. Self-Assembled Nanodielectric Effects on Low-Temperature Combustion Growth and Carrier Mobility. ACS Appl. Mater. Interfaces, 2013, 5, 11884-11893.

• Geier, M. L.; Prabhumirashi, P. L.; McMorrow, J. J.; Xu, W.; Seo, J.-W. T.; Everaerts, K.; Kim, C. H.; Marks, T. J.; Hersam, M. C., Subnanowatt Carbon Nanotube Complementary Logic Enabled by Threshold Voltage Control. Nano Lett., 2013, 13, 4810-4814.

• Guerrero, A.; Loser, S.; Garcia-Belmonte, G.; Bruns, C. J.; Smith, J.; Miyauchi, H.; Stupp, S. I.; Bisquert, J.; Marks, T. J., Solution-processed small molecule:fullerene bulk-heterojunction solar cells: impedance spectroscopy deduced bulk and interfacial limits to fill-factors. Phys. Chem. Chem. Phys., 2013, 15, 16456-16462

• Guo, X.; Quinn, J.; Chen, Z.; Usta, H.; Zheng, Y.; Xia, Y.; Hennek, J. W.; Ortiz, R. P.; Marks, T. J.; Facchetti, A., Dialkoxybithiazole: A New Building Block for Head-to-Head Polymer Semiconductors. J. Am. Chem. Soc., 2013, 135, 1986-1996.

• Guo, X.; Zhou, N.; Lou, S. J.; Smith, J.; Tice, D. B.; Hennek, J. W.; Ortiz, R. P.; Navarrete, J. T. L.; Li, S.; Strzalka, J.; Chen, L. X.; Chang, R. P. H.; Facchetti, A.; Marks, T. J., Polymer solar cells with enhanced fill factors. Nat. Photonics, 2013, 7, 825-833.

• Heitzer, H. M.; Marks, T. J.; Ratner, M. A., First-Principles Calculation of Dielectric Response in Molecule-Based Materials. J. Am. Chem. Soc., 2013, 135, 9753-9759.

• Hennek, J. W.; Smith, J.; Yan, A.; Kim, M.-G.; Zhao, W.; Dravid, V. P.; Facchetti, A.; Marks, T. J., Oxygen “Getter” Effects on Microstructure and Carrier Transport in Low Temperature Combustion-Processed a-InXZnO (X = Ga, Sc, Y, La) Transistors. J. Am. Chem. Soc., 2013, 135, 10729-10741.

• Huang, H.; Chen, Z.; Ortiz, R. P.; Newman, C.; Usta, H.; Lou, S.; Youn, J.; Noh, Y.-Y.; Baeg, K.-J.; Chen, L. X.; Facchetti, A.; Marks, T. J., Correction to “Combining Electron-Neutral Building Blocks with Intramolecular Conformational Locks’ Affords Stable, High-Mobility P- and N-Channel Polymer Semiconductors”. J. Am. Chem. Soc., 2013, 135, 10966-10973.

• Jariwala, D.; Sangwan, V. K.; Late, D. J.; Johns, J. E.; Dravid, V. P.; Marks, T. J.; Lauhon, L. J.; Hersam, M. C., Band-like transport in high mobility unencapsulated single-layer MoS2 transistors. Appl. Phys. Lett., 2013, 102, 173107/1-173107/4.

• Jariwala, D.; Sangwan, V. K.; Lauhon, L. J.; Marks, T. J.; Hersam, M. C., Carbon nanomaterials for electronics, optoelectronics, photovoltaics, and sensing. Chem. Soc. Rev. 2013, 42, 2824-2860.

• Jariwala, D.; Sangwan, V. K.; Wu, C.-C.; Prabhumirashi, P. L.; Geier, M. L.; Marks, T. J.; Lauhon, L. J.; Hersam, M. C., Gate-tunable carbon nanotube-MoS2 heterojunction p-n diode. Proc. Natl. Acad. Sci. U. S. A., 2013, 110, 18076-18080,S18076/1-S18076/6.

•  Li, H.; Zhu, Z.; Fahrenbach, A. C.; Savoie, B. M.; Ke, C.; Barnes, J. C.; Lei, J.; Zhao, Y.-L.; Lilley, L. M.; Marks, T. J.; Ratner, M. A.; Stoddart, J. F., Mechanical Bond-Induced Radical Stabilization. J. Am. Chem. Soc., 2013, 135, 456-467.

• Luck, K. A.; Shastry, T. A.; Loser, S.; Ogien, G.; Marks, T. J.; Hersam, M. C., Improved uniformity in high-performance organic photovoltaics enabled by (3-aminopropyl)triethoxysilane cathode functionalization. Phys. Chem. Chem. Phys., 2013, 15, 20966-20972.

• Marks, T. J., Seeing is believing: a versatile new approach to optically transparent electrodes. NPG Asia Mater., 2013, 5, e67.

• Marks, T. J., Plastic solar cells with interface engineering. Prepr. – Am. Chem. Soc., Div. Energy Fuels, 2013, 58, 348-360.

• Mas-Montoya, M.; Ortiz, R. P.; Curiel, D.; Espinosa, A.; Allain, M.; Facchetti, A.; Marks, T. J., Isomeric carbazolocarbazoles: synthesis, characterization and comparative study in Organic Field Effect Transistors. J. Mater. Chem. C, 2013, 1, 1959-1969.

• Ponce, O. R.; Herrera, H.; Mancheno, M. J.; Seoane, C.; Segura, J. L.; Mayorga, B. P.; Casado, J.; Lopez, N. J. T.; Facchetti, A.; Marks, T. J., Molecular and electronic-structure basis of the ambipolar behavior of naphthalimide-terthiophene derivatives: implementation in organic field-effect transistors. Chemistry, 2013, 19, 12458-67.

• Prado, M. C.; Jariwala, D.; Marks, T. J.; Hersam, M. C., Optimization of graphene dry etching conditions via combined microscopic and spectroscopic analysis. Appl. Phys. Lett., 2013, 102, 193111/1-193111/4.

• Sangwan, V. K.; Arnold, H. N.; Jariwala, D.; Marks, T. J.; Lauhon, L. J.; Hersam, M. C., Low-frequency electronic noise in single-layer MoS2 transistors. Nano Lett., 2013, 13, 4351-4355.

• Sangwan, V. K.; Jariwala, D.; Filippone, S. A.; Karmel, H. J.; Johns, J. E.; Alaboson, J. M. P.; Marks, T. J.; Lauhon, L. J.; Hersam, M. C., Quantitatively enhanced reliability and uniformity of high-κ dielectrics on graphene enabled by self-assembled seeding layers. Nano Lett., 2013, 13, 1162-1167.

•  Sczygelski, E.; Sangwan, V. K.; Wu, C.-C.; Arnold, H. N.; Everaerts, K.; Marks, T. J.; Hersam, M. C.; Lauhon, L. J., Extrinsic and intrinsic photoresponse in monodisperse carbon nanotube thin film transistors. Appl. Phys. Lett., 2013, 102, 083104/1-083104/5.

• Seo, S.; Yu, X.; Marks, T. J., Unconventional isomerization of allylic alcohols to allylcarbinols mediated by lanthanide catalysts. Tetrahedron Lett., 2013, 54, 1828-1831.

•  Shastry, T. A.; Seo, J.-W. T.; Lopez, J. J.; Arnold, H. N.; Kelter, J. Z.; Sangwan, V. K.; Lauhon, L. J.; Marks, T. J.; Hersam, M. C., Large-Area, Electronically Monodisperse, Aligned Single-Walled Carbon Nanotube Thin Films Fabricated by Evaporation-Driven Self-Assembly. Small, 2013, 9, 45-51.

• Tselev, A.; Sangwan, V. K.; Jariwala, D.; Marks, T. J.; Lauhon, L. J.; Hersam, M. C.; Kalinin, S. V., Near-field microwave microscopy of high-κ oxides grown on graphene with an organic seeding layer. Appl. Phys. Lett., 2013, 103, 243105/1-243105/5.

• Uysal, A.; Chu, M.; Stripe, B.; Timalsina, A.; Chattopadhyay, S.; Schleputz, C. M.; Marks, T. J.; Dutta, P., What X rays can tell us about the interfacial profile of water near hydrophobic surfaces. Phys. Rev. B: Condens. Matter Mater. Phys., 2013, 88, 035431/1-035431/8.

• Wu, C.-C.; Jariwala, D.; Sangwan, V. K.; Marks, T. J.; Hersam, M. C.; Lauhon, L. J., Elucidating the Photoresponse of Ultrathin MoS2 Field-Effect Transistors by Scanning Photocurrent Microscopy. J. Phys. Chem. Lett., 2013, 4, 2508-2513.

•  Youn, J.; Kewalramani, S.; Emery, J. D.; Shi, Y.; Zhang, S.; Chang, H.-C.; Liang, Y.-j.; Yeh, C.-M.; Feng, C.-Y.; Huang, H.; Stern, C.; Chen, L.-H.; Ho, J.-C.; Chen, M.-C.; Bedzyk, M. J.; Facchetti, A.; Marks, T. J., Fused Thiophene Semiconductors: Crystal Structure-Film Microstructure Transistor Performance Correlations. Adv. Funct. Mater., 2013, 23, 3850-3865.

• Yu, X.; Zhou, N.; Han, S.; Lin, H.; Buchholz, D. B.; Yu, J.; Chang, R. P. H.; Marks, T. J.; Facchetti, A., Flexible spray-coated TIPS-pentacene organic thin-film transistors as ammonia gas sensors. J. Mater. Chem. C, 2013, 1, 6532-6535.

• Yu, X.; Zhou, N.; Smith, J.; Lin, H.; Stallings, K.; Yu, J.; Marks, T. J.; Facchetti, A., Synergistic Approach to High-Performance Oxide Thin Film Transistors Using a Bilayer Channel Architecture. ACS Appl. Mater. Interfaces, 2013, 5, 7983-7988.

• Zolper, T.; Li, Z.; Jungk, M.; Stammer, A.; Stoegbauer, H.; Marks, T.; Chung, Y.-W.; Wang, Q., Traction Characteristics of Siloxanes with Aryl and Cyclohexyl Branches. Tribol. Lett., 2013, 49, 301-311.

• Zolper, T. J.; Seyam, A.; Li, Z.; Chen, C.; Jungk, M.; Stammer, A.; Marks, T. J.; Chung, Y.-W.; Wang, Q., Friction and Wear Protection Performance of Synthetic Siloxane Lubricants. Tribol. Lett., 2013, 51, 365-376.

•  Zolper, T. J.; Seyam, A. M.; Chen, C.; Jungk, M.; Stammer, A.; Stoegbauer, H.; Marks, T. J.; Chung, Y.-W.; Wang, Q., Energy Efficient Siloxane Lubricants Utilizing Temporary Shear-Thinning. Tribol. Lett., 2013, 49, 525-538.