2010 Publications

• Ando, S.; Facchetti, A.; Marks, T. J., Synthesis and Characterization of Solution-Processable Core-Cyanated Perylene-3,4;9,10-bis(dicarboximide) Derivatives. Org. Lett., 2010, 12, 4852-4855.

• Bagnis, D.; Beverina, L.; Huang, H.; Silvestri, F.; Yao, Y.; Yan, H.; Pagani, G. A.; Marks, T. J.; Facchetti, A., Marked Alkyl- vs. Alkenyl-Substituent Effects on Squaraine Dye Solid-State Structure, Carrier Mobility, and Bulk Heterojunction Solar Cell Efficiency. J. Am. Chem. Soc., 2010, 132, 4074-4075.

• Bullock, J. E.; Vagnini, M. T.; Ramanan, C.; Co, D. T.; Wilson, T. M.; Dicke, J. W.; Marks, T. J.; Wasielewski, M. R., Photophysics and Redox Properties of Rylene Imide and Diimide Dyes Alkylated Ortho to the Imide Groups. J. Phys. Chem. B, 2010, 114, 1794-1802.

• Chattopadhyay, S.; Uysal, A.; Stripe, B.; Ha, Y.-G.; Marks, T. J.; Karapetrova, E. A.; Dutta, P., How water meets a very hydrophobic surface. Phys Rev Lett, 2010, 105, 037803/1-037803/4.

• Delferro, M.; McInnis, J. P.; Marks, T. J., Ethylene Polymerization Characteristics of an Electron-Deficient Nickel(II) Phenoxyiminato Catalyst Modulated by Non-Innocent Intramolecular Hydrogen Bonding. Organometallics, 2010, 29, 5040-5049.

• Dzudza, A.; Marks, T. J., Efficient intramolecular hydroalkoxylation of unactivated alkenols mediated by recyclable lanthanide triflate ionic liquids: scope and mechanism. Chemistry, 2010, 16, 3403-3422.

• Guo, N.; DiBenedetto, S. A.; Tewari, P.; Lanagan, M. T.; Ratner, M. A.; Marks, T. J., Nanoparticle, Size, Shape, and Interfacial Effects on Leakage Current Density, Permittivity, and Break down Strength of Metal Oxide-Polyolefin Nanocomposites: Experiment and Theory. Chem. Mater., 2010, 22, 1567-1578.

• Ha, Y.-g.; Jeong, S.; Wu, J.; Kim, M.-g.; Dravid, V. P.; Facchetti, A.; Marks, T. J., Flexible Low-Voltage Organic Thin-Film Transistors Enabled by Low-Temperature, Ambient Solution-Processable Inorganic/Organic Hybrid Gate Dielectrics. J. Am. Chem. Soc., 2010, 132, 17426-17434.

• Hains, A. W.; Liu, J.; Martinson, A. B. F.; Irwin, M. D.; Marks, T. J., Anode Interfacial Tuning via Electron-Blocking/Hole-Transport Layers and Indium Tin Oxide Surface Treatment in Bulk-Heterojunction Organic Photovoltaic Cells. Adv. Funct. Mater., 2010, 20, 595-606.

• Hains, A. W.; Ramanan, C.; Irwin, M. D.; Liu, J.; Wasielewski, M. R.; Marks, T. J., Designed Bithiophene-Based Interfacial Layer for High-Efficiency Bulk-Heterojunction Organic Photovoltaic Cells: Importance of Interfacial Energy Level Matching. ACS Appl. Mater. Interfaces, 2010, 2, 175-185.

• Hu, L.; Li, J.; Liu, J.; Gruner, G.; Marks, T., Flexible organic light-emitting diodes with transparent carbon nanotube electrodes: problems and solutions. Nanotechnology, 2010, 21, 155202/1-155202/10.

• Irwin, M. D.; Liu, J.; Leever, B. J.; Servaites, J. D.; Hersam, M. C.; Durstock, M. F.; Marks, T. J., Consequences of Anode Interfacial Layer Deletion. HCl-Treated ITO in P3HT:PCBM-Based Bulk-Heterojunction Organic Photovoltaic Devices. Langmuir, 2010, 26, 2584-2591.

Jeong, S.; Ha, Y.-G.; Moon, J.; Facchetti, A.; Marks, T. J., Role of Gallium Doping in Dramatically Lowering Amorphous-Oxide Processing Temperatures for Solution-Derived Indium Zinc Oxide Thin-Film Transistors. Adv. Mater.2010, 22, 1346-1350.

• Kim, C.; Chen, M.-C.; Chiang, Y.-J.; Guo, Y.-J.; Youn, J.; Huang, H.; Liang, Y.-J.; Lin, Y.-J.; Huang, Y.-W.; Hu, T.-S.; Lee, G.-H.; Facchetti, A.; Marks, T. J., Functionalized dithieno[2,3-b:3′,2′-d]thiophenes (DTTs) for organic thin-film transistors. Org. Electron., 2010, 11, 801-813.

• Kim, C.; Huang, P.-Y.; Jhuang, J.-W.; Chen, M.-C.; Ho, J.-C.; Hu, T.-S.; Yan, J.-Y.; Chen, L.-H.; Lee, G.-H.; Facchetti, A.; Marks, T. J., Novel soluble pentacene and anthradithiophene derivatives for organic thin-film transistors. Org. Electron., 2010, 11, 1363-1375.

• Kim, C.; Quinn, J. R.; Facchetti, A.; Marks, T. J., Pentacene Transistors Fabricated on Photocurable Polymer Gate Dielectrics: Tuning Surface Viscoelasticity and Device Response. Adv. Mater., 2010, 22, 342-346.

• Kim, M.-G.; Kim, H. S.; Ha, Y.-G.; He, J.; Kanatzidis, M. G.; Facchetti, A.; Marks, T. J., High-Performance Solution-Processed Amorphous Zinc-Indium-Tin Oxide Thin-Film Transistors. J. Am. Chem. Soc., 2010, 132, 10352-10364.

• Letizia, J. A.; Cronin, S.; Ortiz, R. P.; Facchetti, A.; Ratner, M. A.; Marks, T. J., Phenacyl-Thiophene and Quinone Semiconductors Designed for Solution Processability and Air-Stability in High Mobility n-Channel Field-Effect Transistors. Chem. – Eur. J., 2010, 16, 1911-1928.

• Letizia, J. A.; Rivnay, J.; Facchetti, A.; Ratner, M. A.; Marks, T. J., Variable Temperature Mobility Analysis of n-Channel, p-Channel, and Ambipolar Organic Field-Effect Transistors. Adv. Funct. Mater., 2010, 20, 50-58.

• Li, T. C.; Spokoyny, A. M.; She, C.; Farha, O. K.; Mirkin, C. A.; Marks, T. J.; Hupp, J. T., Ni(III)/(IV) Bis(dicarbollide) as a Fast, Noncorrosive Redox Shuttle for Dye-Sensitized Solar Cells. J. Am. Chem. Soc., 2010, 132, 4580-4582.

• Li, Z.; Fredin, L. A.; Tewari, P.; DiBenedetto, S. A.; Lanagan, M. T.; Ratner, M. A.; Marks, T. J., In Situ Catalytic Encapsulation of Core-Shell Nanoparticles Having Variable Shell Thickness: Dielectric and Energy Storage Properties of High-Permittivity Metal Oxide Nanocomposites. Chem. Mater., 2010, 22, 5154-5164.

• Liu, J.; Buchholz, D. B.; Chang, R. P. H.; Facchetti, A.; Marks, T. J., High-Performance Flexible Transparent Thin-Film Transistors Using a Hybrid Gate Dielectric and an Amorphous Zinc Indium Tin Oxide Channel. Adv. Mater. (Weinheim, Ger.), 2010, 22, 2333-2337.

• Liu, J.; Buchholz, D. B.; Hennek, J. W.; Chang, R. P. H.; Facchetti, A.; Marks, T. J., All-Amorphous-Oxide Transparent, Flexible Thin-Film Transistors. Efficacy of Bilayer Gate Dielectrics. J. Am. Chem. Soc., 2010, 132, 11934-11942.

• Liu, J.; Hains, A. W.; Wang, L.; Marks, T. J., Low-indium content bilayer transparent conducting oxide thin films as effective anodes in organic photovoltaic cells. Thin Solid Films, 2010, 518, 3694-3699.

• Marks, T. J., Materials for organic and hybrid inorganic/organic electronics. MRS Bull., 2010, 35, 1018-1027.

•  Motiei, L.; Yao, Y.; Choudhury, J.; Yan, H.; Marks, T. J.; van der Boom, M. E.; Facchetti, A., Self-propagating molecular assemblies as interlayers for efficient inverted bulk-heterojunction solar cells. J. Am. Chem. Soc., 2010, 132, 12528-12530.

• Motta, A.; Fragala, I. L.; Marks, T. J., Atom-efficient carbon-oxygen bond formation processes. DFT analysis of the intramolecular hydroalkoxylation/cyclization of alkynyl alcohols mediated by lanthanide catalysts. Organometallics, 2010, 29, 2004-2012.

• Ortiz, R. P.; Facchetti, A.; Marks, T. J., High-k Organic, Inorganic, and Hybrid Dielectrics for Low-Voltage Organic Field-Effect Transistors. Chem. Rev. (Washington, DC, U. S.), 2010, 110, 205-239.

• Ortiz, R. P.; Herrera, H.; Blanco, R.; Huang, H.; Facchetti, A.; Marks, T. J.; Zheng, Y.; Segura, J. L., Organic n-Channel Field-Effect Transistors Based on Arylenediimide-Thiophene Derivatives. J. Am. Chem. Soc., 2010, 132, 8440-8452.

• Ortiz, R. P.; Yan, H.; Facchetti, A.; Marks, T. J., Azine- and azole-functionalized oligo’ and polythiophene semiconductors for organic thin-film transistors. Materials 2010, 3, 1533-1558.

• Ponce, O. R.; Facchetti, A.; Marks, T. J., High-k organic, inorganic, and hybrid dielectrics for low-voltage organic field-effect transistors. Chem Rev, 2010, 110, 205-39.

• Ponce, O. R.; Herrera, H.; Blanco, R.; Huang, H.; Facchetti, A.; Marks, T. J.; Zheng, Y.; Segura, J. L., Organic n-channel field-effect transistors based on arylenediimide-thiophene derivatives. J Am Chem Soc, 2010, 132, 8440-52.

• Rao, M.; Ponce Ortiz, R.; Facchetti, A.; Marks, T. J.; Narayan, K. S., Studies of photogenerated charge carriers from donor-acceptor interfaces in organic field effect transistors. Implications for Organic solar cells. J. Phys. Chem. C 2010, 114, 20609-20613.

• Schlitz, R. A.; Yoon, K. H.; Fredin, L. A.; Ha, Y.-g.; Ratner, M. A.; Marks, T. J.; Lauhon, L. J., Weibull Analysis of Dielectric Breakdown in a Self-Assembled Nanodielectric for Organic Transistors. J. Phys. Chem. Lett., 2010, 1, 3292-3297.

• Seo, S.; Marks, T. J., Lanthanide-Catalyst-Mediated Tandem Double Intramolecular Hydroalkoxylation/Cyclization of Dialkynyl Dialcohols: Scope and Mechanism. Chem. – Eur. J., 2010, 16, 5148-5162.

• Servaites, J. D.; Yeganeh, S.; Marks, T. J.; Ratner, M. A., Efficiency Enhancement in Organic Photovoltaic Cells: Consequences of Optimizing Series Resistance. Adv. Funct. Mater., 2010, 20, 97-104.

•Silvestri, F.; Marrocchi, A.; Seri, M.; Kim, C.; Marks, T. J.; Facchetti, A.; Taticchi, A., Solution-Processable Low-Molecular Weight Extended Arylacetylenes: Versatile p-Type Semiconductors for Field-Effect Transistors and Bulk Heterojunction Solar Cells. J. Am. Chem. Soc., 2010, 132, 6108-6123.

• Sosa, N. E.; Chen, C.; Liu, J.; Xie, S.-J.; Marks, T. J.; Hersam, M. C., Nanoscale Structure, Composition, and Charge Transport Analysis of Transparent Conducting Oxide Nanowires Written by Focused Ion Beam Implantation. J. Am. Chem. Soc. 2010, 132, 7347-7354.

•Spokoyny, A. M.; Li, T. C.; Farha, O. K.; Machan, C. W.; She, C.; Stern, C. L.; Marks, T. J.; Hupp, J. T.; Mirkin, C. A., Electronic tuning of nickel-based bis(dicarbollide) redox shuttles in dye-sensitized solar cells. Angew. Chem., Int. Ed., 2010, 49, 5339-5343.

• Szarko, J. M.; Guo, J.-C.; Liang, Y.-Y.; Lee, B.-D.; Rolczynski, B. S.; Strzalka, J.; Xu, T.; Loser, S.; Marks, T. J.; Yu, L.-P.; Chen, L.-X., When function follows form: effects of donor copolymer side chains on film morphology and BHJ solar cell performance. Adv. Mater. (Weinheim, Ger.), 2010, 22, 5468-5472.

• Weiss, C. J.; Marks, T. J., Organozirconium Complexes as Catalysts for Markovnikov-Selective Intermolecular Hydrothiolation of Terminal Alkynes: Scope and Mechanism. J. Am. Chem. Soc., 2010, 132, 10533-10546.

• Weiss, C. J.; Marks, T. J., Organo-f-element catalysts for efficient and highly selective hydroalkoxylation and hydrothiolation. Dalton Trans, 2010, 39, 6576-6588.

• Weiss, C. J.; Wobser, S. D.; Marks, T. J., Lanthanide- and Actinide-Mediated Terminal Alkyne Hydrothiolation for the Catalytic Synthesis of Markovnikov Vinyl Sulfides. Organometallics, 2010, 29, 6308-6320.

• Yi, F.; Ou, F.; Liu, B.; Huang, Y.; Ho, S.-T.; Wang, Y.; Liu, J.; Marks, T. J.; Huang, S.; Luo, J.; Jen, A. K. Y.; Dinu, R.; Jin, D., Electro-optic modulator with exceptional power-size performance enabled by transparent conducting electrodes. Opt. Express 2010, 18, 6779-6796.

• Youn, J.; Chen, M.-C.; Liang, Y.-j.; Huang, H.; Ortiz, R. P.; Kim, C.; Stern, C.; Hu, T.-S.; Chen, L.-H.; Yan, J.-Y.; Facchetti, A.; Marks, T. J., Novel Semiconductors Based on Functionalized Benzo[d,d’]thieno[3,2-b;4,5-b’]dithiophenes and the Effects of Thin Film Growth Conditions on Organic Field Effect Transistor Performance. Chem. Mater., 2010, 22, 5031-5041.