2023 Publications
620. Rational Design and Reticulation of Infinite qbe Rod Secondary Building Units into Metal–Organic Frameworks through a Global Desymmetrization Approach for Inverse C3H8/C3H6 Separation
Gong, W.; Xie, Y.; Yamano, A.; Ito, S.; Reinheimer, E. W.; Dong, J.; Malliakas, C. D.; Proserpio, D. M.; Cui, Y.; Farha, O. K. Angew. Chem., Int. Ed. 2023, e202318475 https://doi.org/10.1002/anie.202318475
![anie202318475-toc-0001-m](https://sites.northwestern.edu/omarkfarha/files/2024/01/anie202318475-toc-0001-m-1f20203376d6e413.jpg)
![anie.v63.4.cover](https://sites.northwestern.edu/omarkfarha/files/2024/01/anie.v63.4.cover_-f9fdeb61d917d9e3.jpg)
619. Modulator-Dependent Dynamics Synergistically Enabled Record SO2 Uptake in Zr(IV) Metal–Organic Frameworks Based on Pyrene-Cored Molecular Quadripod Ligand
Gong, W.; Xie, Y.; Yamano, A.; Ito, S.; Tang, X.; Reinheimer, E. W.; Malliakas, C. D.; Dong, J.; Cui, Y.; Farha, O. K. J. Am. Chem. Soc. 2023, 145, 49, 26890–26899 https://doi.org/10.1038/s41536-023-00331-1
![untitled](https://sites.northwestern.edu/omarkfarha/files/2024/01/we-eae77734cc512375.jpeg)
![wei](https://sites.northwestern.edu/omarkfarha/files/2024/01/wei-dbd1c97839bc529b.jpg)
618. Topical Application of Synthetic Melanin Promotes Tissue Repair
Biyashev, D.; Siwicka, Z. E.; Onay, U. V.; Demczuk, M.; Xu, D.; Ernst, M. K.; Evans, S. T.; Nguyen, C. V.; Son, F. A.; Paul, N. K.; McCallum, N. C.; Farha, O. K.; Miller, S. D.; Gianneschi, N. C. NPJ Regen. Med., 2023, 8, 61 https://doi.org/10.1038/s41536-023-00331-1
![41536_2023_331_Fig1_HTML](https://sites.northwestern.edu/omarkfarha/files/2023/11/41536_2023_331_Fig1_HTML.png)
![biyashev](https://sites.northwestern.edu/omarkfarha/files/2024/01/biyashev-3e5f8aebb97a0450.jpg)
617. Ortho-Alkoxy-benzamide Directed Formation of a Single Crystalline Hydrogen-bonded Crosslinked Organic Framework and Its Boron Trifluoride Uptake and Catalysis
Li, F.; Li, E.; Samanta, K.; Zheng, Z.; Wu, L.; Chen, A. D.; Farha, O. K.; Staples, R.; Niu, J.; Schmidt-Rohr, K.; Ke, C. Angew. Chem., Int. Ed., 2023, e202311601
https://doi.org/10.1002/anie.202311601
![Screenshot 2023-10-30 170748](https://sites.northwestern.edu/omarkfarha/files/2023/10/Screenshot-2023-10-30-170748.png)
![li](https://sites.northwestern.edu/omarkfarha/files/2024/01/li-f4cf6d42565c1413.jpg)
616. Robust Carborane-Based Metal–Organic Frameworks for Hexane Separation
Idrees, K. B.; Kirlikovali, K. O.; Setter, C; Xie, H.; Brand, H.; Lal, B.; Sha, F.; Smoljan, C. S.; Wang, X.; Islamoglu, T.; Macreadie, L. K.; Farha, O. K. J. Am. Chem. Soc. 2023, 145, 23433–23441 https://doi.org/10.1021/jacs.3c04641
![karam](https://sites.northwestern.edu/omarkfarha/files/2023/10/karam.jpeg)
![karam cover](https://sites.northwestern.edu/omarkfarha/files/2023/11/karam-cover.jpg)
615. Humidity-Responsive Polymorphism in CALF-20: A Resilient MOF Physisorbent for CO2 Capture
Chen, Z.; Ho, C.; Wang, X.; Vornholt, S. M.; Rayder, T. M.; Islamoglu, T.; Farha, O. K.; Paesani, F.; Chapman, K. W. ACS Materials Lett. 2023, 5, 2942–2947. https://doi.org/10.1021/acsmaterialslett.3c00930
![zhihengyu](https://sites.northwestern.edu/omarkfarha/files/2023/10/zhihengyu.jpeg)
![chen](https://sites.northwestern.edu/omarkfarha/files/2024/01/chen-e87d2fa396e9cee7.jpg)
614. Metal–Organic Frameworks for Water Vapor Adsorption
Shi, L.; Kirlikovali, K. O.; Chen,Z.; Farha, O. K. Chem, 2023, 10, 1-20. https://doi.org/10.1016/
j.chempr.2023.09.005
![shi](https://sites.northwestern.edu/omarkfarha/files/2023/10/shi-1.jpg)
613. Challenges and Opportunities: Metal–Organic Frameworks for Direct Air Capture
Bose, S.; Sengupta, D.; Rayder, T. M.; Wang, X.; Kirlikovali, K. O.; Sekizkardes, A. K.; Islamoglu, T.; Farha, O. K. Adv. Funct. Mater. 2023, Just Accepted Article. https://doi.org/10.1002/adfm.202307478
![sree](https://sites.northwestern.edu/omarkfarha/files/2023/10/sree.jpg)
![bose](https://sites.northwestern.edu/omarkfarha/files/2024/01/bose-aa48e2d5a1d2094a.jpg)
612. Expanding the Library of Ions for Moisture-Swing Carbon Capture
Hegarty,J.; Shindel, B.; Sukhareva, D.; Barsoum, M. L.; Farha, O. K.; Dravid, V. Environ. Sci. Technol. 2023, Just Accepted Article. https://doi.org/10.1021/acs.est.3c02543
![hagerty](https://sites.northwestern.edu/omarkfarha/files/2023/10/hagerty.jpeg)
![hegarty](https://sites.northwestern.edu/omarkfarha/files/2024/01/hegarty-41fbeb6491795bd5.jpg)
611. Balancing chemical warfare agent degradation and permeability in a zirconium-based metal-organic framework fiber composite
Ma, K.; Jung, D.; Mahle, J. J.; Akpinar, I.; Peterson, G. W.; Farha, O. K. Cell Rep. Phys. Sci. 2023, 101608. https://doi.org/10.1016/j.xcrp.2023.101608
![kaikai](https://sites.northwestern.edu/omarkfarha/files/2023/10/kaikai.jpg)
![kaikai cover](https://sites.northwestern.edu/omarkfarha/files/2023/10/kaikai-cover.jpg)
610. Defect-induced confinement in zirconium metal-organic frameworks for enhanced hydrogen adsorption
Duncan, J.; Sengupta, D.; Bose, S.; Kirlikovali, K. O.; Farha, O. K. SCENV, 2023, 100032. doi.org/10.1016/j.scenv.2023.100032
![josh](https://sites.northwestern.edu/omarkfarha/files/2023/08/josh.jpg)
![josh cover](https://sites.northwestern.edu/omarkfarha/files/2023/08/josh-cover.jpg)
609. Investigating the Mechanical Stability of Flexible Metal–Organic Frameworks
Son, F. A.; Fahy, K. M.; Gaidimas, M. A.; Smoljan, C. S.; Wasson, M. C.; Farha, O. K. Commun. Chem. 2023, 6, 185 https://doi.org/10.1038/s42004-023-00981-8
![flo](https://sites.northwestern.edu/omarkfarha/files/2023/10/flo.png)
608. Air-Stable Cu(I) Metal–Organic Framework for Hydrogen Storage
Sengupta, D.; Melix, P.; Bose, S.; Duncan, J.; Wang, X.; Mian, M. R.; Kirlikovali, K. O.; Joodaki, F.; Islamoglu, T.; Yildirim, T.; Snurr, R. Q.; Farha, O. K. J. Am. Chem. Soc. 2023, 145, 20492–20502 https://doi.org/10.1021/jacs.3c06393
![untitled](https://sites.northwestern.edu/omarkfarha/files/2023/10/deb.jpeg)
![deb cover](https://sites.northwestern.edu/omarkfarha/files/2023/10/deb-cover.jpg)
607. Influence of Linker Identity on the Photochemistry of Uranyl-Organic Frameworks
Knapp, J. G.; Livshits, M. Y.; Gilhula, J. C.; Hanna, S. L.; Piedmonte, I. D.; Rice, N. T.; Wang, X.; Stein, B. W.; Kozimor, S. A.; Farha, O. K. ACS Appl. Mater. Interfaces, 2023, 15, 43667–43677. https://doi.org/10.1021/jacs.3c06393
![julia](https://sites.northwestern.edu/omarkfarha/files/2023/10/julia.jpeg)
![Applied Materials and Interfaces](https://sites.northwestern.edu/omarkfarha/files/2023/10/julia-cover.jpg)
606. Mapping the Complete Reaction Energy Landscape of a Metal–Organic Framework Phase Transformation
Hanna, S. L.; Barsoum, M.; Debela, T. T.; Malliakas, C. D.; Gaidimas, M. A.; Knapp, J. G.; Kirlikovali, K. O.; Hendon, C. H.; Dravid, V. P.; Farha, O. K. ACS Materials Lett. 2023, 5, 2518–2527 https://doi.org/10.1021/acsmaterialslett.3c00598
![sylvia](https://sites.northwestern.edu/omarkfarha/files/2023/10/sylvia-1.jpeg)
![sylvia cover](https://sites.northwestern.edu/omarkfarha/files/2023/10/sylvia-cover.jpg)
605. Suitability of a diamine functionalized metal–organic framework for direct air capture
Bose, S.; Sengupta, D.; Malliakas, C. D.; Idrees, K. B.; Xie, H.; Wang, X.; Barsoum, M. L.; Barker, N. M.; Dravid, V. P.; Islamoglu, T.; Farha, O. K. Chem. Sci. 2023, 14, 9380-9388 https://doi.org/10.1039/D3SC02554C
![sree](https://sites.northwestern.edu/omarkfarha/files/2023/10/sree.gif)
![sree cover](https://sites.northwestern.edu/omarkfarha/files/2023/10/sree-cover.png)
604. Mechanistic Determination of Metal–Organic Framework Degradation Under Humid Conditions Through Ex-situ STEM-PDF
Barsoum, M. L.; dos Reis, R.;Farha, O. K.; Dravid, V. P. Microsc. Microanal., 2023, 29, 1786–1787, doi.org/10.1093/micmic/ozad067.924
![mike](https://sites.northwestern.edu/omarkfarha/files/2023/08/mike.jpeg)
![mike cover](https://sites.northwestern.edu/omarkfarha/files/2023/08/mike-cover.jpeg)
603. Rationally Tailored Mesoporous Hosts for Optimal Protein Encapsulation
Sha, F.; Xie, H.; Son, F. A.; Kim, K. S.; Gong, W.; Su, S.; Ma, K.; Wang, Sha, F.; Xie, H.; Son, F. A.; Kim, K. S.; Gong, W.; Su, S.; Ma, K.; Wang, X.; Wang, X.; Farha, O. K. J. Am. Chem. Soc. 2023, 145, 16383–16390 doi.org/10.1021/jacs.3c01989
![fanrui](https://sites.northwestern.edu/omarkfarha/files/2023/08/fanrui.jpeg)
![fanrui cover](https://sites.northwestern.edu/omarkfarha/files/2023/08/fanrui-cover.jpg)
602. Fibrous Zr-MOF Nanozyme Aerogels with Macro-Nanoporous Structure for Enhanced Catalytic Hydrolysis of Organophosphate Toxins
Ma, K.; Cheung, Y. H.; Kirlikovali, K. O.; Xie, H.; Idrees, K. B.; Wang, X.; Islamoglu, T.; Xin, J. H.; Farha, O. K. Adv. Mater. 2023, 145, e2300951. doi.org/10.1002/adma.202300951
![adma202300951-fig-0006-m](https://sites.northwestern.edu/omarkfarha/files/2023/07/adma202300951-fig-0006-m.jpg)
601. Reticular Chemistry in Its Chiral Form: Axially Chiral Zr(IV)-Spiro Metal–Organic Framework as a Case Study
Gong, W.; Chen, X.; Fahy, K. M.; Dong, J.; Liu, Y.; Farha, O. K.; Cui, Y. J. Am. Chem. Soc. 2023, 145, 13869–13878. doi.org/10.1021/jacs.3c03036
![untitled](https://sites.northwestern.edu/omarkfarha/files/2023/07/images_large_ja3c03036_0008.jpeg)
![jacsat.2023.145.issue-25.xlargecover](https://sites.northwestern.edu/omarkfarha/files/2023/07/jacsat.2023.145.issue-25.xlargecover.jpg)
600. Metal–Organic Frameworks with a Bioinspired Porous Polymer Coating for Sieving Separation
Su, S.; Zhou, X.; Gong, X.; Idrees, K. B.; Kirlikovali, K. O.; Islamoglu, T.; Farha, O. K.; Gianneschi. N. C. J. Am. Chem. Soc. 2023, 145, 13195–13203. doi.org/10.1002/adfm.202301607
![images_large_ja3c02195_0007](https://sites.northwestern.edu/omarkfarha/files/2023/07/images_large_ja3c02195_0007.jpeg)
![jacsat.2023.145.issue-24.xlargecover](https://sites.northwestern.edu/omarkfarha/files/2023/07/jacsat.2023.145.issue-24.xlargecover.jpg)
599. Evidence of a Uranium-Paddlewheel Node in a Catecholate-Based Metal-Organic Framework
Knapp, J. G.; Wang, X.; Rosen, A. S.; Wang, X.; Gong, X.; Schneider, M.; Elkin, T.; Kirlikovali, K. O.; Fairley, M.; Krzyaniak, M. D.; Wasielewski, M. R.; Gianneschi, N. C.; Snurr, R. Q.; Farha, O. K. Angew. Chem. Int. Ed. Engl. 2023, 62, e202305526 . doi.org/10.1002/adfm.202301607
![anie202305526-toc-0001-m](https://sites.northwestern.edu/omarkfarha/files/2023/07/anie202305526-toc-0001-m.jpg)
![anie202306854-toc-0001-m](https://sites.northwestern.edu/omarkfarha/files/2023/07/anie202306854-toc-0001-m.jpg)
598. Functional Textiles with Smart Properties: Their Fabrications and Sustainable Applications
Zhang, Y.; Xia, X.; Ma, K.; Xia, G.; Wu, M.; Cheung, Y. H.; Yu, H.; Zou, B.; Zhang, X.; Farha, O. K.; Xin, J. H. Adv. Func. Mater. 2023, 33, 2301607. doi.org/10.1002/adfm.202301607
![adfm202301607-fig-0001-m](https://sites.northwestern.edu/omarkfarha/files/2023/05/adfm202301607-fig-0001-m.jpg)
![zhang](https://sites.northwestern.edu/omarkfarha/files/2023/08/zhang.jpg)
597. Unveiling Unexpected Modulator-CO2 Dynamics within a Zirconium Metal–Organic Framework
Rayder, T. M.; Formalik, F.; Vornholt, S. M.; Frank, H.; Lee, S.; Alzayer, M.; Chen, Z.; Sengupta, D.; Islamoglu, T.; Paesani, F.; Chapman, K. W.; Snurr, R. Q.; Farha, O. K. J. Am. Chem. Soc. 2023, 145, 11195–11205. doi.org/10.1021/jacs.3c01146
![images_large_ja3c01146_0011](https://sites.northwestern.edu/omarkfarha/files/2023/07/images_large_ja3c01146_0011-1.jpeg)
![jacsat.2023.145.issue-20.xlargecover](https://sites.northwestern.edu/omarkfarha/files/2023/07/jacsat.2023.145.issue-20.xlargecover.jpg)
596. Photoreactive Carbon Dioxide Capture by a Zirconium–Nanographene Metal–Organic Framework
Zheng, X.; Drummer, M. C.; He, H.; Rayder, T. M.; Niklas, J.; Weingartz, N.P.; Bolotin, I. L.; Singh, V.; Kramar, B. V.; Chen, L. X.; Hupp, J. T.; Poluektov, O. G.; Farha, O. K.; Zapol, P.; Glusac, K. D. J. Phys. Chem. Lett. 2023, 14, pp. 4334–4341. doi.org/10.1021/acs.jpclett.3c00049
![images_large_jz3c00049_0008](https://sites.northwestern.edu/omarkfarha/files/2023/05/images_large_jz3c00049_0008.jpeg)
![Picture1](https://sites.northwestern.edu/omarkfarha/files/2023/05/Picture1.jpg)
595. Boosting the Ceramics with In Situ MOF-Derived Nanocarbons
Duden, E. I.; Bayrak, K. G.; Balkan, M.; Cakan, N.; Demiroglu, A.; Ayas, E.; Caglar, M.; Turan, S.; Islamoglu, T.; Farha, O. K.; Erkartal, M.; Sen, U. ACS Materials Lett. 2023, 5, pp. 1537–1545. doi.org/10.1021/acsmaterialslett.3c00302
![images_large_tz3c00302_0007](https://sites.northwestern.edu/omarkfarha/files/2023/05/images_large_tz3c00302_0007.jpeg)
![Applied Materials and Interfaces](https://sites.northwestern.edu/omarkfarha/files/2023/07/amlcef.2023.5.issue-6.xlargecover.jpg)
594. Expanding Linker Dimensionality in Metal-organic Frameworks for sub-Ångstrom Pore Control for Separation Applications
Macreadie, L. K.; Idrees, K. B.; Smoljan, C. S.; Farha, O. K. Angew. Chem. Int. Ed. 2023, Just Accepted Article doi.org/10.1002/anie.202304094
![Screenshot 2023-05-16 134911](https://sites.northwestern.edu/omarkfarha/files/2023/05/Screenshot-2023-05-16-134911.png)
![anie202306612-toc-0001-m](https://sites.northwestern.edu/omarkfarha/files/2023/07/anie202306612-toc-0001-m.jpg)
593. Energy–Structure–Property Relationships in Uranium Metal–Organic Frameworks
Hanna, S. L.; Farha, O. K. Chem. Sci. 2023, 14, 4219-4229 doi.org/10.1039/D3SC00788J
![d3sc00788j-s1](https://sites.northwestern.edu/omarkfarha/files/2023/05/d3sc00788j-s1.gif)
![Screenshot 2023-05-16 133003](https://sites.northwestern.edu/omarkfarha/files/2023/05/Screenshot-2023-05-16-133003.png)
592. Reticular Chemistry in Pore Engineering of a Y-Based Metal–Organic Framework for Xenon/Krypton Separation
Song, X.; Huang, Q.; Liu, J.; Xie, H.; Idrees, K. B.; Hou, S.; Yu, L.; Wang, X.; Liu, F.; Qiao, Z.; Wang, H.; Chen, Y.; Li, Z.; Farha, O. K. ACS Appl. Mater. Interfaces 2023, 15, 18229–18235. doi.org/10.1021/acsami.3c01229
![images_large_am3c01229_0006](https://sites.northwestern.edu/omarkfarha/files/2023/05/images_large_am3c01229_0006.jpeg)
![Applied Materials and Interfaces](https://sites.northwestern.edu/omarkfarha/files/2023/05/aamick.2023.15.issue-14.xlargecover.jpg)
591. Engineering Metal–Organic Frameworks for Selective Separation of Hexane Isomers Using 3-Dimensional Linkers
Smoljan, C. S.; Li, Z.; Xie, H.; Setter, C. J.; Idrees, K. B.; Son, F. A.; Formalik, F.; Shafaie, S.; Islamoglu, T.; Macreadie, L. K.; Snurr, R. Q.; Farha, O. K. J. Am. Chem. Soc. 2023, 145, pp. 6434–6441. doi.org/10.1021/jacs.2c13715
![images_large_ja2c13715_0006](https://sites.northwestern.edu/omarkfarha/files/2023/05/images_large_ja2c13715_0006.jpeg)
![jacsat.2023.145.issue-11.xlargecover](https://sites.northwestern.edu/omarkfarha/files/2023/05/jacsat.2023.145.issue-11.xlargecover.jpg)
590. Zirconium-Based Metal–Organic Frameworks as Reusable Antibacterial Peroxide Carriers for Protective Textiles
Ma, K.; Cheung, Y. H,; Xie, H.; Wang, X.; Evangelopoulos, M.; Kirlikovali, K. O.; Su, S.; Wang, X.; Mirkin, C. A.; Xin, J. H.; Farha, O.K. Chem. Mater. 2023, 35, pp. 2342–2352. doi.org/10.1021/acs.chemmater.2c03288
![untitled](https://sites.northwestern.edu/omarkfarha/files/2023/03/images_large_cm2c03288_0008.jpeg)
![Screenshot 2023-05-16 125418](https://sites.northwestern.edu/omarkfarha/files/2023/05/Screenshot-2023-05-16-125418.png)
589. Pore Aperture Control Toward Size-Exclusion-Based Hydrocarbon Separations
Lal, B.; Idrees, K. B.; Xie, H.; Smoljan, C. S.; Shafaie, S.; Islamoglu, T.; Farha, O. K. Angew. Chem. Int. Ed. 2023, 62, e202219053. doi.org/10.1002/anie.202219053
![lal](https://sites.northwestern.edu/omarkfarha/files/2023/10/lal.jpg)
![lal cover](https://sites.northwestern.edu/omarkfarha/files/2023/10/lal-cover.jpg)
588. Adsorption of a PFAS Utilizing MOF-808: Development of an Undergraduate Laboratory Experiment in a Capstone Course
VanOursouw, T. M.; Rottiger, T.; Wadzinski, K. A.; VanderWaal, B. E.; Snyder, M. J.; Bittner, R. T.; Farha, O. K.; Riha, S. C.; Mondloch, J. E. J. Chem. Educ. 2023, 100, pp. 861-868. https://doi.org/10.1021/acs.jchemed.2c00910
![images_large_ed2c00910_0007](https://sites.northwestern.edu/omarkfarha/files/2023/02/images_large_ed2c00910_0007.jpeg)
![jceda8_v100i002](https://sites.northwestern.edu/omarkfarha/files/2023/03/jceda8_v100i002.jpg)
587. Reticular Design of Precise Linker Installation into a Zirconium Metal–Organic Framework to Reinforce Hydrolytic Stability
Chen, Y.; Idrees, K. B.; Mian, M. R.; Son, F.A.; Zhang, C.; Wang, X.; Farha, O. K. J. Am. Chem. Soc. 2023, 145, pp. 3055-3063. https://doi.org/10.1021/jacs.2c11830
![images_large_ja2c11830_0007](https://sites.northwestern.edu/omarkfarha/files/2023/01/images_large_ja2c11830_0007.jpeg)
![jacsat_v145i005](https://sites.northwestern.edu/omarkfarha/files/2023/03/jacsat_v145i005.jpg)
586. Programmed Polarizability Engineering in a Cyclen-Based Cubic Zr(IV) Metal–Organic Framework to Boost Xe/Kr Separation
Gong, W.; Xie, Y.; Wang, X.; Kirlikovali O.K. Idrees, K. B.; Sha, F.; Xie, H.; Liu, Y.; Chen, B.; Cui, Y.; Farha, O.K. J. Am. Chem. Soc. 2023, 145, pp. 2679-2689. https://doi.org/10.1021/jacs.2c13171
![images_large_ja2c13171_0010](https://sites.northwestern.edu/omarkfarha/files/2023/01/images_large_ja2c13171_0010.jpeg)
![jacsat_v145i005](https://sites.northwestern.edu/omarkfarha/files/2023/03/jacsat_v145i005.jpg)
585. Back to the Basics: Developing Advanced Metal–Organic Frameworks Using Fundamental Chemistry Concepts
Kirlikovali, K. O.; Hanna, S. L.; Son, F. A.; Farha, O. K. ACS Nanosci. Au 2023, 145, pp. 37-45. doi.org/10.1021/acsnanoscienceau.2c00046
![images_large_ng2c00046_0005](https://sites.northwestern.edu/omarkfarha/files/2023/01/images_large_ng2c00046_0005.jpeg)
![anaccx_v003i001](https://sites.northwestern.edu/omarkfarha/files/2023/03/anaccx_v003i001.jpg)