2022 Publications

584. Tröger’s Base Chemistry in Solution and in Zr(IV)-Based Metal–Organic Frameworks

Gong, W.; Kazem-Rostami, M.; Son, F. A.; Su, S.; Fahy, K. M.; Xie, H.; Islamoglu, T.; Liu, Y.; Stoddart, J. F.; Cui, Y.; Farha, O. K. J. Am. Chem. Soc. 2022, 144, pp. 22574–22581doi.org/10.1021/jacs.2c08623

583. Active-Site Determination and Mechanistic Insights in a MOF-Supported Polymerization Catalyst

Goetjen, T. A.; Ferrandon, M. S.; Kropf, A. J.; Lamb, J. V.; Delferro, M.; Hupp, J. T.; Farha, O. K. Phys. Chem. C 2022, 126, pp. 20388–20394. doi.org/10.1021/acs.jpcc.2c06643

582. A General Strategy for the Synthesis of Hierarchically Ordered Metal–Organic Frameworks with Tunable Macro-, Meso-, and Micro-Pores

Wang, C.; Zhang H.; Wang, Y; Wu, J.; Kirlikovali, K. O.; Li, P.; Zhou, Y.; Farha, O. K. Small. 2022, 19, pp.  2206116. doi.org/10.1002/smll.202206116 

581. Enhanced Catalytic Performance of a Ce/V Oxo Cluster through Confinement in Mesoporous SBA-15

Wang, X.; Syed, Z. H.;Chen, Z.; Bazak, J. D.; Gong, X.; Wasson, M. C.; Washton, N. M.; Chapman, K. W.; Notestein, J. M.; Farha, O. K. ACS Appl. Mater. Interfaces 2022, 14, pp. 52886–52893. doi.org/10.1021/acsami.2c15046

580. Hydrophobic Melanin via Post-Synthetic Modification for Controlled Self-Assembly

Zhou, X.; Su, T.; Vanthournout, B.; Hu, Z.; Son, F. A.; Zhang, K.; Siwicka, Z. E.; Gong, X.; Paul, N.; Gnanasekaran, K.; Forman, C.; Farha, O. K.; Shawkey, M. D.; Gianneschi, N. C. ACS Nano 2022, 2022, 16, pp. 19087–19095. doi.org/10.1021/acsnano.2c08114

579. The Dependence of Olefin Hydrogenation and Isomerization Rates on Zirconium Metal–Organic Framework Structure

Hicks, K. E.; Wolek, A. T. Y.; Farha, O. K.; Notestein, J. M. ACS Catal. 2022, 12, pp. 13671-13680. doi.org/10.1021/acscatal.2c04303

578. Toward Ideal Metal–Organic Framework Thin-Film Growth via Automated Layer-by-Layer Deposition: Examples Based on Perylene Diimide Linkers

Goswami, S.; Rimoldi, M.; Anderson, R.; Lee, C.; Li, A.; Deria, P.; Chen, L. X.; Schaller, R. D.; Gomez-Gualdron, D. A.; Farha, O. K.; Fupp, J. T. Chem. Mater. 2022, 34, pp. 9446-9454. doi.org/10.1021/acs.chemmater.2c01753

577. Influence of Pore Size on Hydrocarbon Transport in Isostructural Metal–Organic Framework Crystallites

Gaidimas, M. A.; Son, F. A.; Mian, M. R.; Islamoglu, T.; Farha, O. K. ACS Appl. Mater. Interfaces 2022, 14, pp. 47222-47229 doi.org/10.1021/acsami.2c12189

576. Tuning the Product Distribution of Acetylene Dimerization through Bimetallic Metal–Organic Framework-Supported Nanoporous Systems

Goetjen, T. A.; Kropf, A. J.; Alayoglu, S.; Delferro, M.; Hupp, J. T.; Farha, O. K. ACS Appl. Nano Mater. 2022, 5, pp. 14961-14969.

575. Sulfated Zirconium Metal–Organic Frameworks as Well-Defined Supports for Enhancing Organometallic Catalysis

Syed, Z. H.; Mian, M. R.; Patel, R.; Xie, H.; Pengmei, Z.; Chen, Z.; Son, F. A.; Goetjen, T. A.; Chapovetsky, A.; Fahy, K. M.; Sha, F.; Wang, X.; Alayoglu, S.; Kaphan, D. M.; Chapman, K. W.; Neurock, M.; Gagliardi, L. Delferro, M.; Farha, O. K. J. Am. Chem. Soc. 2022, 144, pp. 16883-16897. doi.org/10.1021/jacs.2c05290 

574. Role of Metal Selection in the Radiation Stability of Isostructural M-UiO-66 Metal–Organic Frameworks

Hastings, A. M.; Fairley, M.; Wasson, M. C.; Campisi, D.; Sarkar, A.; Emory, Z. C.; Brunson, K.; Fast, D. B.; Islamoglu, T.; Nyman, M.; Burns, P. C.; Gagliardi, L.; Farha, O. K.; Hixon, A. E.; LaVerne, J. A. Chem. Mater. 2022, 34, pp. 8403-8417. doi.org/10.1021/acs.chemmater.2c02170

573. Noncovalent Surface Modification of Metal–Organic Frameworks: Unscrambling Adsorption Properties via Isothermal Titration Calorimetry

Sheridan, T. R.; Gaidimas, M. A.; Kramar, B. V.; Goswami, S.; Chen, L. X.; Farha, O. K.; Hupp, J. T. Langmuir 2022, 38, pp. 11199-11209 doi.org/10.1021/acs.langmuir.2c01223

572. Leveraging Isothermal Titration Calorimetry to Explore Structure-Property Relationships of Protein Immobilization in Metal-Organic Frameworks

Tai, T.-Y.; Sha, F.; Wang, X.; Wang, X.; Ma, K.; Kirlikovali, K. O.; Su, S.; Islamoglu, T.; Kato, S.; Farha, O. K. Angew. Chem. Int. Ed.202261, pp. e202209110 doi.org/10.1002/anie.202209110

571. Hot Press Synthesis of MOF/Textile Composites for Nerve Agent Detoxification

Turetsky, D.; Alzate-Sanchez, D. M.; Wasson, M. C.; Yang, A.; Noh, H.; Atilgan, A.; Islamoglu, T.; Farha, O. K.; Dichtel, W. R. ACS Materials Lett. 2022, 4, pp. 1511-1515.

570. Interfacial Unit-Dependent Catalytic Activity for CO Oxidation over Cerium Oxysulfate Cluster Assemblies

Wasson, M. C.; Wang, X.; Melix, P.; Alayoglu, S.; Wolek, A. T. Y.; Colliard, I.; Son, F. A.; Xie, H.; Weitz, E.; Islamoglu, T.; Nyman, M.; Snurr, R. Q.; Notestein, J. M.; Farha, O. K. ACS Appl. Mater. Interfaces202214, pp. 33515-33524. doi.org/10.1021/acsami.2c05937

569. Heteroatom-Doped Porous Carbons as Effective Adsorbers for Toxic Industrial Gasses

Richard, A. J.; Chen, Z.; Islamoglu, T.; Farha, O. K.; El-Kaderi, H. M. ACS Appl. Mater. Interfaces2022, 14, pp. 33173-33180.doi.org/10.1021/acsami.2c06556

568. Ultrafine Silver Nanoparticle Encapsulated Porous Molecular Traps for Discriminative Photoelectrochemical Detection of Mustard Gas Simulantsby Synergistic Size-exclusion and Site-specific Recognition

Wang, C.; Wang, Y.; Kirlikovali, K. O.; Ma, K.; Zhou, Y.; Li, P.; Farha, O. K. Advanced Materials 2022, 34, pp. 2202287. doi.org/10.1002/adma.202202287

567. Mechanistic Investigation of Enhanced Catalytic Selectivity toward Alcohol Oxidation with Ce Oxysulfate Clusters

Wang, X.; Xie, H.; Knapp, J. G.; Wasson, M. C.; Wu, Y.; Ma, K.; Stone, A. E. B. S.; Krzyaniak, M. D.; Chen, Y.; Zhang, X.; Notestein, J. M.; Wasielewski, M. R.; Farha, O. K. J. Am. Chem. Soc.2022, 144, pp. 12092-12101 doi.org/10.1021/jacs.2c02625

566. Photocatalytic Biocidal Coatings Featuring Zr6Ti4-Based Metal–Organic Frameworks

Wang, X.; Ma, K.; Goh, T.; Mian, M. R.; Xie, H.; Mao, H.; Duan, J.; Kirlikovali, K. O.; Stone, A. E. B. S.; Ray, D.; Wasielewski, M. R.; Gagliardi, L.; Farha, O. K. J. Am. Chem. Soc.2022, 144, pp. 12192-12201 doi.org/10.1021/jacs.2c03060

565. Separation of Aromatic Hydrocarbons in Porous Materials

Idrees, K. B.; Li, Z.; Xie, H.; Kirlikovali, K. O.; Kazem-Rostami, M.; Wang, X.; Wang, X.; Tai, T. -Y.; Islamoglu, T.; Stoddart, J. F.; Snurr, R. Q.; Farha, O. K. J. Am. Chem. Soc.2022, 144, pp. 12212-12218 doi.org/10.1021/jacs.2c03114

564. Magnetically recyclable nanocomposites via lanthanide-based MOFs grown on natural sea sponge: Screening hydrogenation of nitrophenol to aminophenol

Zhang, K.; Kim, J.; Kirlikovali, K. O.; Wang, J.; Lee, T. H.; Kim, S. Y.; Varma, R. S.; Jan,g H. W.; Farha, O. K.; Shokouhimehr, M. Mol. Catal.2022, 528, pp. 112459 doi.org/10.1016/j.mcat.2022.112459

563. Leveraging Nitrogen Linkages in the Formation of a Porous Thorium–Organic Nanotube Suitable for Iodine Capture

Hastings, A. M.; Ray, D.; Hanna, S. L.; Jeong, W.; Chen, Z.; Oliver, A. G.; Gagliardi, L.; Farha, O. K.; Hixon, A. E. Inorg. Chem.2022, 61, pp. 9480-9492 doi.org/10.1021/acs.inorgchem.2c00427

562. Mechanically interlocked pyrene-based photocatalysts

Garci, A.; Weber, J. A.; Young, R. M.; Kazem-Rostami, M.; Ovalle, M.; Beldjoudi, Y.; Atilgan, A.; Bae, Y. J.; Liu, W.; Jones, L. O.; Stern, C. L.; Schatz, G. C.; Farha, O. K.; Wasielewski, M. R.; Stoddart, J. F. Nat. Catal.2022, 5, pp. 524-533 doi.org/10.1038/s41929-022-00799-y

561. Design Rules of Hydrogen-Bonded Organic Frameworks with High Chemical and Thermal Stabilities

Song, X.; Wang, Y.; Wang, C.; Wang, D.; Zhuang, G.; Kirlikovali, K. O.; Li, P.; Farha, O.K. J. Am. Chem. Soc.2022, 144, pp. 10663-10687 doi.org/10.1021/jacs.2c02598

560. Aggregation-Suppressed Porous Processable Hexa-Zirconium/Polymer Composites for Detoxification of a Nerve Agent Simulant

Su, S.; Jung, D.; Gong, X.; Idrees, K.B.; Hanna, S.L.; Islamoglu, T.; Gianneschi, N.C.; Farha, O.K. Chem. Mater.2022, 34, pp. 4983-4991. doi.org/10.1021/acs.chemmater.2c00262

559. Leveraging Isothermal Titration Calorimetry to Obtain Thermodynamic Insights into the Binding Behavior and Formation of Metal–Organic Frameworks

Sha, F.; Tai, T.-Y.; Gaidimas, M.A.; Son, F.A.; Farha, O.K. Langmuir2022, 38, pp. 6771-6779. doi.org/10.1021/acs.langmuir.2c00812

558. Charge transfer in mixed and segregated stacks of tetrathiafulvalene, tetrathianaphthalene and naphthalene diimide: a structural, spectroscopic and computational study

Leong, C.F.; Chan, B.; Liu, T.; Moore, H.S.; Hod, I.; Solomon, M.B.; Usov, P.M.; Hupp, J.T.; Farha, O.K.; D’Alessandro, D.M. New. J. Chem., 2022, 46, pp. 1026-10036 doi.org/10.1039/d2nj00643j

557. Modulating Chemical Environments of Metal–Organic Framework-Supported Molybdenum(VI) Catalysts for Insights into the Structure–Activity Relationship in Cyclohexene Epoxidation

Chen, Y.; Ahn, S.; Mian, M.R.; Wang, X.; Ma, Q.; Son, F.A.; Yang, L.; Ma, K.; Zhang, X.; Notestein, J.M.;  Farha, O.K. J. Am. Chem. Soc., 2022, 144, pp. 3554-3563 doi.org/10.1021/jacs.1c12421

556. Insights into Mass Transfer Barriers in Metal–Organic Frameworks

Bukowski, B.C.; Son, F.A.; Chen, Y.; Robison, L.; Islamoglu, T.; Sunrr, R.Q.; Farha, O.K. Chem. Mater., 2022, 34, pp. 4134-4141 doi.org/10.1021/acs.chemmater.2c00462

555. Rapid Generation of Metal–Organic Framework Phase Diagrams by High-Throughput Transmission Electron Microscopy

Gong, X.; Gnanasekaran, K.; Ma, K.; Forman, C. J.; Wang, X.; Su, S.; Farha, O.K.; Gianneschi, N. C. J. Am. Chem. Soc., 2022, 144, pp. 6674-6680 doi.org/10.1021/jacs.2c01095

554. Catalytic Degradation of Polyethylene Terephthalate Using a Phase-Transitional Zirconium-Based Metal-Organic Framework

Wu, Y.; Wang, X.; Kirlikovali, K.O.; Gong, X.; Atilgan, A.; Ma, K.; Schweitzer, N.M.; Gianneschi, N.C.; Li, Z.; Zhang, X.; Farha, O.K. Angew. Chem. Int. Ed., 2022, 61, e202117528 doi.org/10.1002/anie.202117528

553. A Catalytically Accessible Polyoxometalate in a Porous Fiber for Degradation of a Mustard Gas Simulant

Jung, D.; Su, S.; Syed, Z.H.; Atilgan, A.; Wang, X.; Sha, F.; Lei, Y.; Gianneschi, N.C.; Islamoglu, T.; Farha, O.K. ACS Appl. Mater. Interfaces, 2022, 14, pp. 16687-16693 doi.org/10.1021/acsami.2c01584

552. BODIPY-Based Polymers of Intrinsic Microporosity for the Photocatalytic Detoxification of a Chemical Threat

Atilgan, A.; Beldjoudi, Y.; Yu, J.; Kirlikovali, K. O.; Weber, J. A.; Liu, J.; Jung, D.; Deria, P.; Islamoglu, T.; Stoddart, J. F.; Farha, O. K.; Hupp, J. T. ACS Appl. Mater. Interfaces, 2022, 14, pp. 12596-12605 doi.org/10.1021/acsami.1c21750

551. Exchange of coordinated carboxylates with azolates as a route to obtain a microporous zinc–azolate framework

Fahy, K. M.; Mian, M. R.; Wasson, M. C.; Son, F. A.; Islamoglu, T.; Farha, O. K.  Chem. Commun, 2022, 58, pp. 4028-4031 doi.org/10.1039/D2CC00925K

550. Environmentally Benign Biosynthesis of Hierarchical MOF/Bacterial Cellulose Composite Sponge for Nerve Agent Protection

Cheung, Y. H.; Ma, K.; Wasson, M. C.; Wang, X.; Idrees, K. B.; Islamoglu, T.; Mahle, J.; Peterson, G. W.; Xin, J. H.; Farha, O. K.  Angew. Chem. Int. Ed., 2022, 61, e202202207 doi.org/10.1002/anie.202202207

549. Creating Optimal Pockets in a Clathrochelate-Based Metal–Organic Framework for Gas Adsorption and Separation: Experimental and Computational Studies

Gong, W.; Xie, Y.; Pham, T.D.; Shetty, S.; Son, F.A.; Idrees, K.B.; Chen, Z.; Xie, H.; Liu, Y.; Snurr, R.Q.; Chen, B.; Alameddine, B.; Cui, Y.; Farha, O.K. J. Am. Chem. Soc., 2022, 144, pp. 3737-3745 doi.org/10.1021/jacs.2c00011

548. Leveraging Chiral Zr(IV)-Based Metal–Organic Frameworks To Elucidate Catalytically Active Rh Species in Asymmetric Hydrogenation Reactions

Gong, W.; Chen, X.; Zhang, W.; Kirlikovali, K.O.; Nan, B.; Chen, Z.; Si, R.; Liu, Y.; Farha, O.K.; Cui, Y. J. Am. Chem. Soc., 2022, 144, pp. 3117-3126 doi.org/10.1021/jacs.1c12117

547. Direct Observation of Modulated Radical Spin States in Metal–Organic Frameworks by Controlled Flexibility

Chen, X.; Xie, H.; Lorenzo, E.R.; Zeman IV, C.J.; Qi, Y.; Syed, Z.H.; Stone, A.E.B.S.; Wang, Y.; Goswami, S.; Li, P.; Islamoglu, T.; Weiss, E.A.; Hupp, J.T.; Schatz, G.C.; Wasielewski, M.R.; Farha, O.K. J. Am. Chem. Soc., 2022, 144, pp. 2685-2693 doi.org/10.1021/jacs.1c11417

546. Ethylene polymerization with a crystallographically well-defined metal–organic framework supported catalyst

Goetjen, T.A.; Knapp, J.G.; Syed, Z.H.; Hackler, R.A.; Zhang, X.; Delferro, M.; Hupp, J.T.; Farha, O.K. Catal. Sci. Technol., 2022, 12, pp. 1619-1627 doi.org/10.1039/D1CY01990B

545. Development of a Metal–Organic Framework/Textile Composite for the Rapid Degradation and Sensitive Detection of the Nerve Agent VX

de Koning, M.C.; Ma, K.; van Grol, M.; Iordanov, I.; Kruijne, M.J.L.; Idrees, K.B.; Xie, H.; Islamoglu, T.; Bross, R.P.T.; Farha, O.K.  Chem. Mater., 2022, 34, pp. 1269-1277 doi.org/10.1021/acs.chemmater.1c03895

544. Understanding Diffusional Charge Transport within a Pyrene-Based Hydrogen-Bonded Organic Framework

Goswami, S.; Ma, K.; Duan, J.; Kirlikovali, K.O.; Bai, J.; Hupp, J.T.; Li, P.; Farha, O.K.  Langmuir, 2022, 38, pp. 1533-1539 doi.org/10.1021/acs.langmuir.1c02915

543. Water Sorption Evolution Enabled by Reticular Construction of Zirconium Metal–Organic Frameworks Based on a Unique [2.2]Paracyclophane Scaffold

Gong, W.; Xie, H.; Idrees, K.B.; Son, F.A.; Chen, Z.; Sha, F.; Liu, Y.; Cui, Y.; Farha, O.K.  J. Am. Chem. Soc., 2022, 144, pp. 1826-184 doi.org/10.1021/jacs.1c11836

542. Investigating the Influence of Hexanuclear Clusters in Isostructural Metal–Organic Frameworks on Toxic Gas Adsorption

Kirlikovali, K.O.; Chen, Z.; Wang, X.; Mian, M.R.; Alayoglu, S.; Islamoglu, T.; Farha, O.K. ACS Appl. Mater. Interfaces, 2022, 14, pp. 3048-3056 doi.org/10.1021/acsami.1c20518

541. Chemically Engineered Porous Molecular Coatings as Reactive Oxygen Species Generators and Reservoirs for Long-Lasting Self-Cleaning Textiles

Wang, Y.; Ma, K.; Bai, J.; Xu, T.; Han, W.; Wang, C.; Chen, Z.; Kirlikovali, K.O.; Li, P.; Xiao, J.; Farha, O.K. Angew. Chem. Int. Ed., 2022, 61, e202115956 doi.org/10.1002/anie.202115956

540. Electron transitions in a Ce(iii)-catecholate metal–organic framework

Knapp, J.G.; Ray, D.; Calio, P.B.; Wasson, M.C.; Scott, T.R.; Gagliardi, L.; Farha, O.K. Chem. Commun., 2022, 58, pp. 525-528 doi.org/10.1039/D1CC06440A

539. Are you using the right probe molecules for assessing the textural properties of metal–organic frameworks?

Islamoglu, T.; Idrees, K.B.; Son, F.A.; Chen, Z.; Lee, S.-J.; Li, P.; Farha, O.K.  J. Mater. Chem. A, 2022, 10, pp. 157-173 doi.org/10.1039/D1TA08021K