Publications

Selected publications are provided below. Click here to see a full list of publications from the Schaller group via Google Scholar.

2024

Coherent Phonon Dynamics in Plasmonic Gold Tetrahedral Nanoparticle Ensembles
B. M. Chandler, D. Dey, Y. Wang, X. Ye, G. C. Schatz, L. X. Chen, and R. D. Schaller.
J. Phys. Chem. Lett., 2024, 15 (38), 9686–9691
Intraband Cooling and Auger Recombination in Weakly to Strongly Quantum-Confined CsPbBr3 Perovskite Nanocrystals
E. H. Oriel, D. N. Dirin, K. Shcherbak, M. I. Bodnarchuk, M. V. Kovalenko. L. X. Chen, and R. D. Schaller.
J. Phys. Chem. Lett., 2024, 15 (23), 6062–6068

2023

Cyclic versus Linear Alkylammonium Cations: Preventing Phase Transitions at Operational Temperatures in 2D Perovskites
S. A. Cuthriell, C. D. Malliakas, M. G. Kanatzidis, and R. D. Schaller.
J. Am. Chem. Soc., 2023, 145 (21), 11710
Light-Induced Transient Lattice Dynamics and Metastable Phase Transition in CH3NH3PbI3 Nanocrystals
A. A. Leonard, B. T. Diroll, N. C. Flanders, S. Panuganti, A. Brumberg, M. S. Kirschner, S. A. Cuthriell, S. M. Harvey, N. E. Watkins, J. Yu, M. R. Wasielewski, M. G. Kanatzidis, W. R. Dichtel, X. Zhang, L. X. Chen and R. D. Schaller.
ACS Nano, 2023, 17 (6), 5306
Excitonic Spin-Coherence Lifetimes in CdSe Nanoplatelets Increase Significantly with Core/Shell Morphology
P. I. Martin, S. Panuganti, J. C. Portner, N. E. Watkins, M. G. Kanatzidis, D. V. Talapin, and R. D. Schaller.
Nano Lett., 2023, 23 (4), 1467
Reexamination of the Giant Oscillator Strength Effect in CdSe Nanoplatelets
B. T. Diroll and R. D. Schaller.
J. Phys. Chem. C, 2023, 127 (9), 4601

2022

Transient X-ray Diffraction Reveals Nonequilibrium Phase Transition in Thin Films of CH3NH3PbI3 Perovskite
S. Panuganti, S. A. Cuthriell, A. A. Leonard, M. A. Quintero, C. C. Laing, B. Gurzelturk, X. Zhang, L. X. Chen, M. G. Kanatzidis, and R. D. Schaller.
ACS Energy Lett., 2023, 8 (1), 691-698
Nonequilibrium Lattice Dynamics in Photoexcited 2D Perovskites
S. A. Cuthriell, S. Panuganti, C. C. Laing, M. A. Quintero, B. Gurzelturk, N. Yazdani, B. Traore, A. Brumberg, C. D. Malliakas, A. M. Lindenberg, V. Wood, C. Katan, J. Even, X. Zhang, M. G. Kanatzidis, and R. D. Schaller.
Adv. Mat., 2022, 34 (44), 2202709
Acceleration of Biexciton Radiative Recombination at Low Temperature in CdSe Nanoplatelets
A. Brumberg, N. E. Watkins, B. T. Diroll, and R. D. Schaller.
Nano. Lett., 2022, 22 (17), 6997
Gain roll-off cadmium selenide colloidal quantum wells under intense optical excitation
B. T. Diroll, A. Brumberg, and R. D. Schaller.
Sci. Rep., 2022, 12 (8016)

2021

Synthetic Ligand Selection Affects Stoichiometry, Carrier Dynamics, and Trapping in CuInSe2 Nanocrystals
S. M. Harvey, D. W. Houck, W. Liu, Y. Liu, D. J. Gosztola, B. A. Korgel, M. R. Wasielewski, and R. D. Schaller.
ACS Nano , 2021, 15 (12), 19588
Surface Normal Lasing from CdSe Nanoplatelets Coupled to Aluminum Plasmonic Nanoparticle Lattices
N. E. Watkins, J. Guan, B. T. Diroll, K. R. Williams, R. D. Schaller, and T. W. Odom
J. Phys. Chem. C , 2021, 125 (36), 19874
Distance Dependence of Förster Resonance Energy Transfer Rates in 2D Perovskite Quantum Wells via Control of Organic Spacer Length
S. Panuganti, L. V. Bestiero, E. S. Vasileiadou, J. M. Hoffman, A. O. Govorov, S. K. Gray, M. G. Kanatzidis, and R. D. Schaller
J. Am. Chem. Soc. , 2021, 143 (11), 4244
Photothermal behavior of titanium nitride nanoparticles evaluated by transient X-ray diffraction
B. T. Diroll, A. Brumberg, A. A. Leonard, S. Panuganti, N. E. Watkins, S. A. Cuthriell, S. M. Harvey, E. D. Kinigstein, J. Yu, X. Zhang, M. G. Kanatzidis, M. R. Wasielewski, L. X. Chen, and R. D. Schaller
Nanoscale, 2021, 4 (13), 2658
Anisotropic Transient Disordering of Colloidal, Two-Dimensional CdSe Nanoplatelets upon Optical Excitation
A. Brumberg, M. S. Kirschner, B. T. Diroll, K. R. Williams, N. C. Flanders, S. M. Harvey, A. A. Leonard, N. E. Watkins, C. Liu, E. D. Kinigstein, J. Yu, A. M. Evans, Y. Liu, S. A. Cuthriell, S. Panuganti, W. R. Dichtel, M. G. Kanatzidis, M. R. Wasielewski, X. Zhang, L. X. Chen, and R. D. Schaller
Nano Lett., 2021, 21 (3), 1288

2020

Transient Lattice Response upon Photoexcitation in CuInSe2 Nanocrystals with Organic or Inorganic Surface Passivation
S. M. Harvey, D. W. Houck, M. S. Kirschner, N. C. Flanders, A. Brumberg, A. A. Leonard, N. E. Watkins, L. X. Chen, W. R. Dichtel, X. Zhang, B. A. Korgel, M. R. Wasielewski, and R D. Schaller
ACS Nano, 2020, 14 (10), 13548
Intersubband Relaxation in CdSe Colloidal Quantum Wells
B. T. Diroll and R. D. Schaller
ACS Nano, 2020, 14 (9), 12082
Direct Observation of Bandgap Oscillations Induced by Optical Phonons in Hybrid Lead Iodide Perovskites
P. Guo, Y. Xia, J. Gong, D. H. Cao, X. Li, X. Li, Q. Zhang, C. C. Stoumpos, M. S. Kirschner, H. Wen, V. B. Prakapenka, J. B. Ketterson, A. B. F. Martinson, T. Xu M. G. Kanatzidis, M. K. Y. Chan, and R D. Schaller
Adv. Funct. Mater., 2020, 30 (22), 1907982
Broadband Ultrafast Dynamics of Refractory Metals: TiN and ZrN
B. T. Diroll, S. Saha, V. M. Shalaev, A. Boltasseva, and R. D. Schaller
Adv. Opt. Mater., 2020, 8 (9), 2000652
Phase control of coherent acoustic phonons in gold bipyramids for optical memory and manipulating plasmon–exciton coupling
M. S. Kirschner, X.-M. Lin, L. X. Chen, and R. D. Schaller
Appl. Phys. Lett., 2020, 116 (15), 153102
Photophysical implications of ring fusion, linker length, and twisting angle in a series of perylenediimide-thienoacene dimers
A. A. Leonard, M. A. Mosquera, L. O. Jones, Z. Cai, T. J. Fauvell, M. S. Kirschner, D. J. Gosztola, G. C. Schatz, R. D. Schaller, L. Yu, and L. X. Chen
Chem. Sci., 2020, 11 7133
Heat-driven acoustic phonons in lamellar nanoplatelet assemblies
B. T. Diroll, V. Kamysbayev, I. Coropceanu, D. V. Talapin, and R. D. Schaller
Nanoscale, 2020, 12, 9661

2019

Phonon-Induced Plasmon-Exciton Coupling Changes Probed via Oscillation-Associated Spectra
M. S. Kirschner, Y. Jeong, A. P. Spencer, N. E. Watkins, X. Lin, G. C. Schatz, L. X. Chen, and R. D. Schaller
Appl. Phys. Lett., 2019, 115, 111903
Polarized Near-Infrared Intersubband Absorptions in CdSe Colloidal Quantum Wells
B. T. Diroll, M. Chen, I. Coropceanu, K. R. Williams, D. V. Talapin, P. Guyot-Sionnest, and R. D. Schaller
Nat. Commun., 2019, 10, 4511
Spectroscopic Comparison of Thermal Transport at Organic–Inorganic and Organic-Hybrid Interfaces Using CsPbBr3 and FAPbBr3 (FA = Formamidinium) Perovskite Nanocrystals
B. T. Diroll, A. Mannodi-Kanakkithodi, M. K. Y. Chan, and R. D. Schaller
Nano Lett. , 2019, 19 (11), 8155
Heating and Cooling of Ligand-Coated Colloidal Nanocrystals in Solid Films and Solvent Matrices
B. T. Diroll and R. D. Schaller
Nanoscale, 2019, 11, 8204
Intraband Cooling in All‐Inorganic and Hybrid Organic–Inorganic Perovskite Nanocrystals
B. T. Diroll and R. D. Schaller
Adv. Funct. Mater., 2019, 29 (37), 1901725
Determination of the In-Plane Exciton Radius in 2D CdSe Nanoplatelets via Magneto-Optical Spectroscopy
A. Brumberg, S. M. Harvey, J. P. Philbin, B. T. Diroll, B. Lee, S. A. Crooker, M. R. Wasielewski, E. Rabani, and R. D. Schaller
ACS Nano, 2019, 13 (8), 8589
Optical and Physical Probing of Thermal Processes in Semiconductor and Plasmonic Nanocrystals
B. T. Diroll, M. S. Kirschner, P. Guo, and R. D. Schaller
Annu. Rev. Phys. Chem., 2019, 70 (1), 353
Shape-Selective Optical Transformations of CdSe Nanoplatelets Driven by Halide Ion Ligand Exchange
B. T. Diroll and R. D. Schaller
Chem. Mater., 2019, 31 (9), 3556
Thermal Excitation Control over Photon Emission Rate of CdSe Nanocrystals
B. T. Diroll and R. D. Schaller
Nano Lett., 2019, 19 (4), 2322
Synthesis of Type I PbSe/CdSe Dot-on-Plate Heterostructures with Near-Infrared Emission
K. R. Williams, B. T. Diroll, N. E. Watkins, X. Rui, A. Brumberg, R. F. Klie, and R. D. Schaller
J. Am. Chem. Soc., 2019, 141 (13), 5092
Photoinduced, Reversible Phase Transition in All-Inorganic Perovskite Nanocrystals
M. S. Kirschner, B. T. Diroll, P. Guo, S. M. Harvey, W. Helweh, N. C. Flanders, A. Brumberg, N. E. Watkins, A. A. Leonard, A. M. Evans, M. R. Wasielewski, W. R. Dichtel, X. Zhang, L. X. Chen, and R. D. Schaller
Nat. Commun., 2019, 10, 504
Infrared-Pump Electronic-Probe of Methylammonium Lead Iodide Reveals Electronically Decoupled Organic and Inorganic Sublattices
P. Guo, A. Mannodi-Kanakkithodi, J. Gong, Y. Xia, C. C. Stoumpos, D. H. Cao, B. T. Diroll, J. B. Ketterson, G. P. Wiederrecht, T. Xu, M. K. Y. Chan, M. G. Kanatzidis, and R. D. Schaller
Nat. Commun. 2019, 10, 482

2018

Heat Transfer at Hybrid Interfaces: Interfacial Ligand-to-Nanocrystal Heating Monitored with Infrared Pump, Electronic Probe Spectroscopy
B. T. Diroll, P. Guo, and R. D. Schaller
Nano Lett, 2018, 18 (12), 7863
Semiconductor Nanoplatelet Excimers
B. T. Diroll, W. Cho, I. Coropceanu, S. M. Harvey, A. Brumberg, N. Holtgrewe, S. A. Crooker, M. R. Wasielewski, V. B. Parakapenka, D. V. Talapin, and R. D. Schaller
Nano Lett, 2018, 18 (11), 6948
Optical Signatures of Transiently Disordered Semiconductor Nanocrystals
M. S. Kirschner, B. T. Diroll, A. Brumberg, A. A. Leonard, D. C. Hannah, L. X. Chen, and R. D. Schaller
ACS Nano, 2018, 12 (10), 10008
Slow Thermal Equilibration in Methylammonium Lead Iodide Revealed by Transient Mid-Infrared Spectroscopy
P. Guo, J. Gong, S. Sadasivam, Y. Xia, T.-B. Song, B. T. Diroll, C. C. Stoumpos, J. B. Ketterson, M. G. Kanatzidis, M. K. Y. Chan, P. Darancet, T. Xu, and R. D. Schaller
Nat. Commun. 2018, 9, 2792
Auger Heating and Thermal Dissipation in Zero-Dimensional CdSe Nanocrystals Examined Using Femtosecond Stimulated Raman Spectroscopy
S. M. Harvey, B. T Phelan, D. C. Hannah, K. E Brown, R. M. Young, M. S. Kirschner, M. R. Wasielewski, and R. D. Schaller
J. Phys. Chem. Lett. 2018, 9 (16), 4481
Hyperbolic Dispersion Arising from Anisotropic Excitons in Two-Dimensional Perovskites
P. Guo, W. Huang, C. C. Stoumpos, L. Mao, J. Gong, L. Zeng, B. T. Diroll, Y. Xia, X. Ma, D. J. Gosztola, T. Xu, J. B. Ketterson, M. J. Bedzyk, A. Facchetti, T. J. Marks, M. G. Kanatzidis, and R. D. Schaller
Phys. Rev. Lett. 2018, 121 (12), 127401
Material Dimensionality Effects on Electron Transfer Rates Between CsPbBr3 and CdSe Nanoparticles
A. Brumberg, B. T. Diroll, G. Nedelcu, M. E. Sykes, Y. Liu, S. M. Harvey, M. R. Wasielewski, M. V. Kovalenko, and R. D. Schaller
Nano Lett. 2018, 18 (8), 4771
Low‐Temperature Absorption, Photoluminescence, and Lifetime of CsPbX3 (X = Cl, Br, I) Nanocrystals
B. T. Diroll, H. Zhou, and R. D. Schaller
Adv. Funct. Mater. 2018, 28 (30), 1800945
Cross-Plane Coherent Acoustic Phonons in Two-Dimensional Organic-Inorganic Hybrid Perovskites
P. Guo, C. C. Stoumpos, L. Mao, S. Sadasivam, J. B. Ketterson, P. Darancet, M. G. Kanatzidis, and R. D. Schaller
Nat. Commun. 2018, 9, 2019
Low-Loss Near-Infrared Hyperbolic Metamaterials with Epitaxial ITO-In2O3 Multilayers
P. Guo, B. T. Diroll, W. Huang, L. Zeng, B. Wang, M. J. Bedzyk, A. Facchetti, T. J. Marks, R. P. H. Chang, and R. D. Schaller
ACS Photonics 2018, 5 (5), 2000
Elevated Temperature Photophysical Properties and Morphological Stability of CdSe and CdSe/CdS Nanoplatelets
C. E. Rowland, I. Fedin, B. T. Diroll, Y. Liu, D. V. Talapin, and R. D. Schaller
J. Phys. Chem. Lett. 2018, 9 (2), 286
Phonon-Driven Oscillatory Plasmonic Excitonic Nanomaterials
M. S. Kirschner, W. Ding, Y. Li, C. T. Chapman, A. Lei, X. Lin, L. X. Chen, G. C. Schatz, and R. D. Schaller
Nano Lett. 2018, 18 (1), 442
Unique Optical Properties of Methylammonium Lead Iodide Nanocrystals Below the Bulk Tetragonal-Orthorhombic Phase Transition
B. T. Diroll, P. Guo, and R. D. Schaller
Nano Lett. 2018, 18 (2), 846

2017

Polar Fluctuations in Metal Halide Perovskites Uncovered by Acoustic Phonon Anomalies
P. Guo, Y. Xia, J. Gong, C. C. Stoumpos, K. M. McCall, G. C. B. Alexander, Z. Mall, H. Zhoull, D. J. Gosztola, J. B. Ketterson, M. G. Kanatzidis, T. Xu, M. K. Y. Chan, and R. D. Schaller
ACS Ener. Lett. 2017, 2 (10), 2463
Ultrafast Silicon Photonics with Visible to Mid-Infrared Pumping of Silicon Nanocrystals
B. T. Diroll, K. S. Schramke, P. Guo, U. R. Kortshagen, and R. D. Schaller
Nano Lett. 2017, 17 (10), 6409
Transient Melting and Recrystallization of Semiconductor Nanocrystals Under Multiple Electron–Hole Pair Excitation
M. S. Kirschner, D. C. Hannah, B. T. Diroll, X. Zhang, M. J. Wagner, D. Hayes, A. Y. Chang, C. E. Rowland, C. M. Lethiec, G. . Schatz, L. X. Chen, and R. D. Schaller
Nano Lett. 2017, 17 (9), 5314
Tunable Infrared Hyperbolic Metamaterials with Periodic Indium-Tin-Oxide Nanorods
P. Guo, R. P. H. Chang, and R. D. Schaller
Appl. Phys. Lett. 2017, 111, 021108
Transient Negative Optical Nonlinearity of Indium Oxide Nanorod Arrays in the Full-Visible Range
P. Guo, R. P. H. Chang, and R. D. Schaller
ACS Photonics 2017, 4 (6), 1494
High‐Temperature Photoluminescence of CsPbX3 (X= Cl, Br, I) Nanocrystals
B. T. Diroll, G. Nedelcu, M. V. Kovalenko, and R. D. Schaller
Adv. Funct. Mater. 2017, 27 (21), 1606750
Violet-to-Blue Gain and Lasing from Colloidal CdS Nanoplatelets: Low-Threshold Stimulated Emission Despite Low Photoluminescence Quantum Yield
B. T. Diroll, D. V. Talapin, and R. D. Schaller
ACS Photonics 2017, 4 (3), 576

2016

Conformal Coating of a Phase Change Material on Ordered Plasmonic Nanorod Arrays for Broadband All-Optical Switching
P. Guo, M. S. Weimer, J. D. Emery, B. T. Diroll, X. Chen, A. S. Hock, R. P. H. Chang, A. B. F. Martinson, and R. D. Schaller
ACS Nano 2017, 11 (1), 693
Large Transient Optical Modulation of Epsilon-Near-Zero Colloidal Nanocrystals
B. T. Diroll, P. Guo, R. P. H. Chang, and R. D. Schaller
ACS Nano 2016, 10 (11), 10099
Large Optical Nonlinearity of Indium-Tin-Oxide Nanorods for Sub-Picosecond All-Optical Modulation of the Full Visible Spectrum
P. Guo, R.D. Schaller, L.E. Ocola, B.T. Diroll, J.B. Ketterson, R.P.H. Chang
Nat. Commun. 2016, 7, 12892
Surface-Area Dependent Electron Transfer Between Isoenergetic 2D Quantum Wells and a Molecular Acceptor
B.T. Diroll, I. Fedin, P. Darancet, D.V. Talapin, R. D. Schaller
J. Am. Chem. Soc. 2016, 138 (35), 11109
Gigahertz Acoustic Vibrations of Elastically Anisotropic Indium-Tin-Oxide Nanorod Arrays
P. Guo, R.D. Schaller, L.E. Ocola, J.B. Ketterson, and R.P.H. Chang
Nano Lett. 2016, 16 (9), 5639
Slow Organic-to-Inorganic Sub-Lattice Thermalization in Methylammonium Lead Iodide Perovskites Observed by Ultrafast Photoluminescence
A.Y. Chang, Y.-J. Cho, K.-C. Chen, C.-W. Chen, A. Kinaci, M.K.Y. Chan, H.-W. Lin, and R.D. Schaller
Adv. Energy Mater. 2016, 6, 1600422
Size-Dependent Coherent Phonon Plasmon Modulations and Deformation Characterization in Gold Bipyramids and Nanojavelins
M.S. Kirschner, C.M. LeThiec, X.-M. Lin, G.C. Schatz, L.X. Chen, and R.D. Schaller
ACS Photonics 2016, 3 (5), 758
Ultrafast Switching of Tunable Infrared Plasmons in Indium Tin Oxide Nanorod Arrays with Large Absolute Amplitude
P. Guo, R.D. Schaller, J.B. Ketterson, and R.P.H. Chang
Nat. Photonics 2016, 14, 267

2015

Reverse Non-Equilibrium Molecular Dynamics Demonstrates that Surface Passivation Controls Thermal Transport at Semiconductor-Solvent Interfaces
D.C. Hannah, J.D. Gezelter, R.D. Schaller, and G.C. Schatz
ACS Nano 2015, 9 (6), 6278
Picosecond Energy Transfer and Multiexciton Transfer Outpaces Auger Recombination in Binary CdSe Nano-Platelet Solids
C.E. Rowland, I. Fedin, H. Zhang, A.O. Govorov, S.K. Gray, D.V. Talapin, and R.D. Schaller
Nat. Mater. 2015, 14, 484

2014

Ultrafast Photoluminescence in Quantum-Confined Silicon Nanoparticles Arises from an Amorphous Surface Layer
D.C. Hannah, J. Yang, G.C. Schatz, U. Kortshagen, and R.D. Schaller
ACS Photonics 2014, 1 (10), 960
Silicon Nanocrystals at Elevated Temperatures: Retention of Photoluminescence and Diamond- to β-Silicon Carbide Phase Transition
C.E. Rowland, D.C. Hannah, A. Demortiere, J. Yang, R.E. Cook, V.B. Prakapenka, U. Kortshagen, and R.D. Schaller
ACS Nano 2014, 8 (9), 9219
Carrier Dynamics of Highly Quantum-Confined Indium Antimonide Nanocrystals
A.Y. Chang, W. Liu, D.V. Talapin, and R.D. Schaller
ACS Nano 2014, 8 (8), 8513
Thermal Stability of Colloidal InP Nanocrystals: Small Inorganic Ligands Boost High-Temperature Photoluminescence
C.E. Rowland, W. Liu, D.C. Hannah, M.K.Y. Chan, D.V. Talapin, and R.D. Schaller
ACS Nano 2014, 8 (1), 977

2013

Direct Measurement of Lattice Dynamics and Optical Phonon Generation in Semiconductor Nanocrystals via Femtosecond Stimulated Raman Spectroscopy
D.C. Hannah, K. Brown, R.Young, M.R. Wasielewski, G.C. Schatz, D.T. Co, and R.D. Schaller
Phys. Rev. Lett. 2013, 111, 107401
Exciton Fate in Semiconductor Nanocrystals at Elevated Temperatures: Hole Trapping Outcompetes Exciton Deactivation
C.E. Rowland and R.D. Schaller
J. Phys. Chem. C 2013, 117 (33), 17337
Ultrafast Dynamics of a Vapor-Deposited Small Molecule Organic Solar Cell
A.Y. Chang, Y.-H. Chen, H.-W. Lin and R.D. Schaller
J. Am. Chem. Soc. 2013, 135 (24), 8790

2012

Particle-level Control of Effective Thermal Conductivity in Matrix-Embedded Semiconductor Nanocrystals
D.C. Hannah, Sandrine Ithurria, G. Krylova, E. Shevchenko, D.V. Talapin, G.C. Schatz and R. D. Schaller
Nano Lett. 2012, 12 (11), 5797
On the Origin of Photoluminescence in Silicon Nanocrystals: Pressure-Dependent Structural and Optical Studies
D.C. Hannah, J.Yang, P. Podsiadlo, M. Chan, A. Demortiere, D.J. Gosztola, V.B. Prakapenka, G.C. Schatz, U. Kortshagen, and R.D. Schaller
Nano Lett. 2012, 12 (8), 4200

2011

Observation of Size-Dependent Thermalization in CdSe Nanocrystals using Time-Resolved Photoluminescence Spectroscopy
D.C. Hannah, N.J. Dunn, S. Ithurria, D.V. Talapin, L.X. Chen, M. Pelton, G.C. Schatz and R.D. Schaller
Phys. Rev. Lett. 2011, 107, 177403

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