Selected publications are provided below. Click here to see a full list of publications from the Schaller group via Google Scholar.
2024
Coherent Phonon Dynamics in Plasmonic Gold Tetrahedral Nanoparticle Ensembles B. M. Chandler, D. Dey, Y. Wang, X. Ye, G. C. Schatz, L. X. Chen, and R. D. Schaller. J. Phys. Chem. Lett., 2024, 15 (38), 9686–9691 |
Intraband Cooling and Auger Recombination in Weakly to Strongly Quantum-Confined CsPbBr3 Perovskite Nanocrystals E. H. Oriel, D. N. Dirin, K. Shcherbak, M. I. Bodnarchuk, M. V. Kovalenko. L. X. Chen, and R. D. Schaller. J. Phys. Chem. Lett., 2024, 15 (23), 6062–6068 |
2023
Cyclic versus Linear Alkylammonium Cations: Preventing Phase Transitions at Operational Temperatures in 2D Perovskites S. A. Cuthriell, C. D. Malliakas, M. G. Kanatzidis, and R. D. Schaller. J. Am. Chem. Soc., 2023, 145 (21), 11710 |
Light-Induced Transient Lattice Dynamics and Metastable Phase Transition in CH3NH3PbI3 Nanocrystals A. A. Leonard, B. T. Diroll, N. C. Flanders, S. Panuganti, A. Brumberg, M. S. Kirschner, S. A. Cuthriell, S. M. Harvey, N. E. Watkins, J. Yu, M. R. Wasielewski, M. G. Kanatzidis, W. R. Dichtel, X. Zhang, L. X. Chen and R. D. Schaller.> ACS Nano, 2023, 17 (6), 5306 |
Excitonic Spin-Coherence Lifetimes in CdSe Nanoplatelets Increase Significantly with Core/Shell Morphology P. I. Martin, S. Panuganti, J. C. Portner, N. E. Watkins, M. G. Kanatzidis, D. V. Talapin, and R. D. Schaller. Nano Lett., 2023, 23 (4), 1467 |
Reexamination of the Giant Oscillator Strength Effect in CdSe Nanoplatelets B. T. Diroll and R. D. Schaller. J. Phys. Chem. C, 2023, 127 (9), 4601 |
2022
Transient X-ray Diffraction Reveals Nonequilibrium Phase Transition in Thin Films of CH3NH3PbI3 Perovskite S. Panuganti, S. A. Cuthriell, A. A. Leonard, M. A. Quintero, C. C. Laing, B. Gurzelturk, X. Zhang, L. X. Chen, M. G. Kanatzidis, and R. D. Schaller. ACS Energy Lett., 2023, 8 (1), 691-698 |
Nonequilibrium Lattice Dynamics in Photoexcited 2D Perovskites S. A. Cuthriell, S. Panuganti, C. C. Laing, M. A. Quintero, B. Gurzelturk, N. Yazdani, B. Traore, A. Brumberg, C. D. Malliakas, A. M. Lindenberg, V. Wood, C. Katan, J. Even, X. Zhang, M. G. Kanatzidis, and R. D. Schaller. Adv. Mat., 2022, 34 (44), 2202709 |
Acceleration of Biexciton Radiative Recombination at Low Temperature in CdSe Nanoplatelets A. Brumberg, N. E. Watkins, B. T. Diroll, and R. D. Schaller. Nano. Lett., 2022, 22 (17), 6997 |
Gain roll-off cadmium selenide colloidal quantum wells under intense optical excitation B. T. Diroll, A. Brumberg, and R. D. Schaller. Sci. Rep., 2022, 12 (8016) |
2021
Synthetic Ligand Selection Affects Stoichiometry, Carrier Dynamics, and Trapping in CuInSe2 Nanocrystals S. M. Harvey, D. W. Houck, W. Liu, Y. Liu, D. J. Gosztola, B. A. Korgel, M. R. Wasielewski, and R. D. Schaller. ACS Nano , 2021, 15 (12), 19588 |
Surface Normal Lasing from CdSe Nanoplatelets Coupled to Aluminum Plasmonic Nanoparticle Lattices N. E. Watkins, J. Guan, B. T. Diroll, K. R. Williams, R. D. Schaller, and T. W. Odom J. Phys. Chem. C , 2021, 125 (36), 19874 |
Distance Dependence of Förster Resonance Energy Transfer Rates in 2D Perovskite Quantum Wells via Control of Organic Spacer Length S. Panuganti, L. V. Bestiero, E. S. Vasileiadou, J. M. Hoffman, A. O. Govorov, S. K. Gray, M. G. Kanatzidis, and R. D. Schaller J. Am. Chem. Soc. , 2021, 143 (11), 4244 |
Photothermal behavior of titanium nitride nanoparticles evaluated by transient X-ray diffraction B. T. Diroll, A. Brumberg, A. A. Leonard, S. Panuganti, N. E. Watkins, S. A. Cuthriell, S. M. Harvey, E. D. Kinigstein, J. Yu, X. Zhang, M. G. Kanatzidis, M. R. Wasielewski, L. X. Chen, and R. D. Schaller Nanoscale, 2021, 4 (13), 2658 |
Anisotropic Transient Disordering of Colloidal, Two-Dimensional CdSe Nanoplatelets upon Optical Excitation A. Brumberg, M. S. Kirschner, B. T. Diroll, K. R. Williams, N. C. Flanders, S. M. Harvey, A. A. Leonard, N. E. Watkins, C. Liu, E. D. Kinigstein, J. Yu, A. M. Evans, Y. Liu, S. A. Cuthriell, S. Panuganti, W. R. Dichtel, M. G. Kanatzidis, M. R. Wasielewski, X. Zhang, L. X. Chen, and R. D. Schaller Nano Lett., 2021, 21 (3), 1288 |
2020
Transient Lattice Response upon Photoexcitation in CuInSe2 Nanocrystals with Organic or Inorganic Surface Passivation S. M. Harvey, D. W. Houck, M. S. Kirschner, N. C. Flanders, A. Brumberg, A. A. Leonard, N. E. Watkins, L. X. Chen, W. R. Dichtel, X. Zhang, B. A. Korgel, M. R. Wasielewski, and R D. Schaller ACS Nano, 2020, 14 (10), 13548 |
Intersubband Relaxation in CdSe Colloidal Quantum Wells B. T. Diroll and R. D. Schaller ACS Nano, 2020, 14 (9), 12082 |
Direct Observation of Bandgap Oscillations Induced by Optical Phonons in Hybrid Lead Iodide Perovskites P. Guo, Y. Xia, J. Gong, D. H. Cao, X. Li, X. Li, Q. Zhang, C. C. Stoumpos, M. S. Kirschner, H. Wen, V. B. Prakapenka, J. B. Ketterson, A. B. F. Martinson, T. Xu M. G. Kanatzidis, M. K. Y. Chan, and R D. Schaller Adv. Funct. Mater., 2020, 30 (22), 1907982 |
Broadband Ultrafast Dynamics of Refractory Metals: TiN and ZrN B. T. Diroll, S. Saha, V. M. Shalaev, A. Boltasseva, and R. D. Schaller Adv. Opt. Mater., 2020, 8 (9), 2000652 |
Phase control of coherent acoustic phonons in gold bipyramids for optical memory and manipulating plasmon–exciton coupling M. S. Kirschner, X.-M. Lin, L. X. Chen, and R. D. Schaller Appl. Phys. Lett., 2020, 116 (15), 153102 |
Photophysical implications of ring fusion, linker length, and twisting angle in a series of perylenediimide-thienoacene dimers A. A. Leonard, M. A. Mosquera, L. O. Jones, Z. Cai, T. J. Fauvell, M. S. Kirschner, D. J. Gosztola, G. C. Schatz, R. D. Schaller, L. Yu, and L. X. Chen Chem. Sci., 2020, 11 7133 |
Heat-driven acoustic phonons in lamellar nanoplatelet assemblies B. T. Diroll, V. Kamysbayev, I. Coropceanu, D. V. Talapin, and R. D. Schaller Nanoscale, 2020, 12, 9661 |
2019
Phonon-Induced Plasmon-Exciton Coupling Changes Probed via Oscillation-Associated Spectra M. S. Kirschner, Y. Jeong, A. P. Spencer, N. E. Watkins, X. Lin, G. C. Schatz, L. X. Chen, and R. D. Schaller Appl. Phys. Lett., 2019, 115, 111903 |
Polarized Near-Infrared Intersubband Absorptions in CdSe Colloidal Quantum Wells B. T. Diroll, M. Chen, I. Coropceanu, K. R. Williams, D. V. Talapin, P. Guyot-Sionnest, and R. D. Schaller Nat. Commun., 2019, 10, 4511 |
Spectroscopic Comparison of Thermal Transport at Organic–Inorganic and Organic-Hybrid Interfaces Using CsPbBr3 and FAPbBr3 (FA = Formamidinium) Perovskite Nanocrystals B. T. Diroll, A. Mannodi-Kanakkithodi, M. K. Y. Chan, and R. D. Schaller Nano Lett. , 2019, 19 (11), 8155 |
Heating and Cooling of Ligand-Coated Colloidal Nanocrystals in Solid Films and Solvent Matrices B. T. Diroll and R. D. Schaller Nanoscale, 2019, 11, 8204 |
Intraband Cooling in All‐Inorganic and Hybrid Organic–Inorganic Perovskite Nanocrystals B. T. Diroll and R. D. Schaller Adv. Funct. Mater., 2019, 29 (37), 1901725 |
Determination of the In-Plane Exciton Radius in 2D CdSe Nanoplatelets via Magneto-Optical Spectroscopy A. Brumberg, S. M. Harvey, J. P. Philbin, B. T. Diroll, B. Lee, S. A. Crooker, M. R. Wasielewski, E. Rabani, and R. D. Schaller ACS Nano, 2019, 13 (8), 8589 |
Optical and Physical Probing of Thermal Processes in Semiconductor and Plasmonic Nanocrystals B. T. Diroll, M. S. Kirschner, P. Guo, and R. D. Schaller Annu. Rev. Phys. Chem., 2019, 70 (1), 353 |
Shape-Selective Optical Transformations of CdSe Nanoplatelets Driven by Halide Ion Ligand Exchange B. T. Diroll and R. D. Schaller Chem. Mater., 2019, 31 (9), 3556 |
Thermal Excitation Control over Photon Emission Rate of CdSe Nanocrystals B. T. Diroll and R. D. Schaller Nano Lett., 2019, 19 (4), 2322 |
Synthesis of Type I PbSe/CdSe Dot-on-Plate Heterostructures with Near-Infrared Emission K. R. Williams, B. T. Diroll, N. E. Watkins, X. Rui, A. Brumberg, R. F. Klie, and R. D. Schaller J. Am. Chem. Soc., 2019, 141 (13), 5092 |
Photoinduced, Reversible Phase Transition in All-Inorganic Perovskite Nanocrystals M. S. Kirschner, B. T. Diroll, P. Guo, S. M. Harvey, W. Helweh, N. C. Flanders, A. Brumberg, N. E. Watkins, A. A. Leonard, A. M. Evans, M. R. Wasielewski, W. R. Dichtel, X. Zhang, L. X. Chen, and R. D. Schaller Nat. Commun., 2019, 10, 504 |
Infrared-Pump Electronic-Probe of Methylammonium Lead Iodide Reveals Electronically Decoupled Organic and Inorganic Sublattices P. Guo, A. Mannodi-Kanakkithodi, J. Gong, Y. Xia, C. C. Stoumpos, D. H. Cao, B. T. Diroll, J. B. Ketterson, G. P. Wiederrecht, T. Xu, M. K. Y. Chan, M. G. Kanatzidis, and R. D. Schaller Nat. Commun. 2019, 10, 482 |
2018
Heat Transfer at Hybrid Interfaces: Interfacial Ligand-to-Nanocrystal Heating Monitored with Infrared Pump, Electronic Probe Spectroscopy B. T. Diroll, P. Guo, and R. D. Schaller Nano Lett, 2018, 18 (12), 7863 |
Semiconductor Nanoplatelet Excimers B. T. Diroll, W. Cho, I. Coropceanu, S. M. Harvey, A. Brumberg, N. Holtgrewe, S. A. Crooker, M. R. Wasielewski, V. B. Parakapenka, D. V. Talapin, and R. D. Schaller Nano Lett, 2018, 18 (11), 6948 |
Optical Signatures of Transiently Disordered Semiconductor Nanocrystals M. S. Kirschner, B. T. Diroll, A. Brumberg, A. A. Leonard, D. C. Hannah, L. X. Chen, and R. D. Schaller ACS Nano, 2018, 12 (10), 10008 |
Slow Thermal Equilibration in Methylammonium Lead Iodide Revealed by Transient Mid-Infrared Spectroscopy P. Guo, J. Gong, S. Sadasivam, Y. Xia, T.-B. Song, B. T. Diroll, C. C. Stoumpos, J. B. Ketterson, M. G. Kanatzidis, M. K. Y. Chan, P. Darancet, T. Xu, and R. D. Schaller Nat. Commun. 2018, 9, 2792 |
Auger Heating and Thermal Dissipation in Zero-Dimensional CdSe Nanocrystals Examined Using Femtosecond Stimulated Raman Spectroscopy S. M. Harvey, B. T Phelan, D. C. Hannah, K. E Brown, R. M. Young, M. S. Kirschner, M. R. Wasielewski, and R. D. Schaller J. Phys. Chem. Lett. 2018, 9 (16), 4481 |
Hyperbolic Dispersion Arising from Anisotropic Excitons in Two-Dimensional Perovskites P. Guo, W. Huang, C. C. Stoumpos, L. Mao, J. Gong, L. Zeng, B. T. Diroll, Y. Xia, X. Ma, D. J. Gosztola, T. Xu, J. B. Ketterson, M. J. Bedzyk, A. Facchetti, T. J. Marks, M. G. Kanatzidis, and R. D. Schaller Phys. Rev. Lett. 2018, 121 (12), 127401 |
Material Dimensionality Effects on Electron Transfer Rates Between CsPbBr3 and CdSe Nanoparticles A. Brumberg, B. T. Diroll, G. Nedelcu, M. E. Sykes, Y. Liu, S. M. Harvey, M. R. Wasielewski, M. V. Kovalenko, and R. D. Schaller Nano Lett. 2018, 18 (8), 4771 |
Low‐Temperature Absorption, Photoluminescence, and Lifetime of CsPbX3 (X = Cl, Br, I) Nanocrystals B. T. Diroll, H. Zhou, and R. D. Schaller Adv. Funct. Mater. 2018, 28 (30), 1800945 |
Cross-Plane Coherent Acoustic Phonons in Two-Dimensional Organic-Inorganic Hybrid Perovskites P. Guo, C. C. Stoumpos, L. Mao, S. Sadasivam, J. B. Ketterson, P. Darancet, M. G. Kanatzidis, and R. D. Schaller Nat. Commun. 2018, 9, 2019 |
Low-Loss Near-Infrared Hyperbolic Metamaterials with Epitaxial ITO-In2O3 Multilayers P. Guo, B. T. Diroll, W. Huang, L. Zeng, B. Wang, M. J. Bedzyk, A. Facchetti, T. J. Marks, R. P. H. Chang, and R. D. Schaller ACS Photonics 2018, 5 (5), 2000 |
Elevated Temperature Photophysical Properties and Morphological Stability of CdSe and CdSe/CdS Nanoplatelets C. E. Rowland, I. Fedin, B. T. Diroll, Y. Liu, D. V. Talapin, and R. D. Schaller J. Phys. Chem. Lett. 2018, 9 (2), 286 |
Phonon-Driven Oscillatory Plasmonic Excitonic Nanomaterials M. S. Kirschner, W. Ding, Y. Li, C. T. Chapman, A. Lei, X. Lin, L. X. Chen, G. C. Schatz, and R. D. Schaller Nano Lett. 2018, 18 (1), 442 |
Unique Optical Properties of Methylammonium Lead Iodide Nanocrystals Below the Bulk Tetragonal-Orthorhombic Phase Transition B. T. Diroll, P. Guo, and R. D. Schaller Nano Lett. 2018, 18 (2), 846 |
2017
Polar Fluctuations in Metal Halide Perovskites Uncovered by Acoustic Phonon Anomalies P. Guo, Y. Xia, J. Gong, C. C. Stoumpos, K. M. McCall, G. C. B. Alexander, Z. Mall, H. Zhoull, D. J. Gosztola, J. B. Ketterson, M. G. Kanatzidis, T. Xu, M. K. Y. Chan, and R. D. Schaller ACS Ener. Lett. 2017, 2 (10), 2463 |
Ultrafast Silicon Photonics with Visible to Mid-Infrared Pumping of Silicon Nanocrystals B. T. Diroll, K. S. Schramke, P. Guo, U. R. Kortshagen, and R. D. Schaller Nano Lett. 2017, 17 (10), 6409 |
Transient Melting and Recrystallization of Semiconductor Nanocrystals Under Multiple Electron–Hole Pair Excitation M. S. Kirschner, D. C. Hannah, B. T. Diroll, X. Zhang, M. J. Wagner, D. Hayes, A. Y. Chang, C. E. Rowland, C. M. Lethiec, G. . Schatz, L. X. Chen, and R. D. Schaller Nano Lett. 2017, 17 (9), 5314 |
Tunable Infrared Hyperbolic Metamaterials with Periodic Indium-Tin-Oxide Nanorods P. Guo, R. P. H. Chang, and R. D. Schaller Appl. Phys. Lett. 2017, 111, 021108 |
Transient Negative Optical Nonlinearity of Indium Oxide Nanorod Arrays in the Full-Visible Range P. Guo, R. P. H. Chang, and R. D. Schaller ACS Photonics 2017, 4 (6), 1494 |
High‐Temperature Photoluminescence of CsPbX3 (X= Cl, Br, I) Nanocrystals B. T. Diroll, G. Nedelcu, M. V. Kovalenko, and R. D. Schaller Adv. Funct. Mater. 2017, 27 (21), 1606750 |
Violet-to-Blue Gain and Lasing from Colloidal CdS Nanoplatelets: Low-Threshold Stimulated Emission Despite Low Photoluminescence Quantum Yield B. T. Diroll, D. V. Talapin, and R. D. Schaller ACS Photonics 2017, 4 (3), 576 |
2016
Conformal Coating of a Phase Change Material on Ordered Plasmonic Nanorod Arrays for Broadband All-Optical Switching P. Guo, M. S. Weimer, J. D. Emery, B. T. Diroll, X. Chen, A. S. Hock, R. P. H. Chang, A. B. F. Martinson, and R. D. Schaller ACS Nano 2017, 11 (1), 693 |
Large Transient Optical Modulation of Epsilon-Near-Zero Colloidal Nanocrystals B. T. Diroll, P. Guo, R. P. H. Chang, and R. D. Schaller ACS Nano 2016, 10 (11), 10099 |
Large Optical Nonlinearity of Indium-Tin-Oxide Nanorods for Sub-Picosecond All-Optical Modulation of the Full Visible Spectrum P. Guo, R.D. Schaller, L.E. Ocola, B.T. Diroll, J.B. Ketterson, R.P.H. Chang Nat. Commun. 2016, 7, 12892 |
Surface-Area Dependent Electron Transfer Between Isoenergetic 2D Quantum Wells and a Molecular Acceptor B.T. Diroll, I. Fedin, P. Darancet, D.V. Talapin, R. D. Schaller J. Am. Chem. Soc. 2016, 138 (35), 11109 |
Gigahertz Acoustic Vibrations of Elastically Anisotropic Indium-Tin-Oxide Nanorod Arrays P. Guo, R.D. Schaller, L.E. Ocola, J.B. Ketterson, and R.P.H. Chang Nano Lett. 2016, 16 (9), 5639 |
Slow Organic-to-Inorganic Sub-Lattice Thermalization in Methylammonium Lead Iodide Perovskites Observed by Ultrafast Photoluminescence A.Y. Chang, Y.-J. Cho, K.-C. Chen, C.-W. Chen, A. Kinaci, M.K.Y. Chan, H.-W. Lin, and R.D. Schaller Adv. Energy Mater. 2016, 6, 1600422 |
Size-Dependent Coherent Phonon Plasmon Modulations and Deformation Characterization in Gold Bipyramids and Nanojavelins M.S. Kirschner, C.M. LeThiec, X.-M. Lin, G.C. Schatz, L.X. Chen, and R.D. Schaller ACS Photonics 2016, 3 (5), 758 |
Ultrafast Switching of Tunable Infrared Plasmons in Indium Tin Oxide Nanorod Arrays with Large Absolute Amplitude P. Guo, R.D. Schaller, J.B. Ketterson, and R.P.H. Chang Nat. Photonics 2016, 14, 267 |
2015
Reverse Non-Equilibrium Molecular Dynamics Demonstrates that Surface Passivation Controls Thermal Transport at Semiconductor-Solvent Interfaces D.C. Hannah, J.D. Gezelter, R.D. Schaller, and G.C. Schatz ACS Nano 2015, 9 (6), 6278 |
Picosecond Energy Transfer and Multiexciton Transfer Outpaces Auger Recombination in Binary CdSe Nano-Platelet Solids C.E. Rowland, I. Fedin, H. Zhang, A.O. Govorov, S.K. Gray, D.V. Talapin, and R.D. Schaller Nat. Mater. 2015, 14, 484 |
2014
Ultrafast Photoluminescence in Quantum-Confined Silicon Nanoparticles Arises from an Amorphous Surface Layer D.C. Hannah, J. Yang, G.C. Schatz, U. Kortshagen, and R.D. Schaller ACS Photonics 2014, 1 (10), 960 |
Silicon Nanocrystals at Elevated Temperatures: Retention of Photoluminescence and Diamond- to β-Silicon Carbide Phase Transition C.E. Rowland, D.C. Hannah, A. Demortiere, J. Yang, R.E. Cook, V.B. Prakapenka, U. Kortshagen, and R.D. Schaller ACS Nano 2014, 8 (9), 9219 |
Carrier Dynamics of Highly Quantum-Confined Indium Antimonide Nanocrystals A.Y. Chang, W. Liu, D.V. Talapin, and R.D. Schaller ACS Nano 2014, 8 (8), 8513 |
Thermal Stability of Colloidal InP Nanocrystals: Small Inorganic Ligands Boost High-Temperature Photoluminescence C.E. Rowland, W. Liu, D.C. Hannah, M.K.Y. Chan, D.V. Talapin, and R.D. Schaller ACS Nano 2014, 8 (1), 977 |
2013
Direct Measurement of Lattice Dynamics and Optical Phonon Generation in Semiconductor Nanocrystals via Femtosecond Stimulated Raman Spectroscopy D.C. Hannah, K. Brown, R.Young, M.R. Wasielewski, G.C. Schatz, D.T. Co, and R.D. Schaller Phys. Rev. Lett. 2013, 111, 107401 |
Exciton Fate in Semiconductor Nanocrystals at Elevated Temperatures: Hole Trapping Outcompetes Exciton Deactivation C.E. Rowland and R.D. Schaller J. Phys. Chem. C 2013, 117 (33), 17337 |
Ultrafast Dynamics of a Vapor-Deposited Small Molecule Organic Solar Cell A.Y. Chang, Y.-H. Chen, H.-W. Lin and R.D. Schaller J. Am. Chem. Soc. 2013, 135 (24), 8790 |
2012
Particle-level Control of Effective Thermal Conductivity in Matrix-Embedded Semiconductor Nanocrystals D.C. Hannah, Sandrine Ithurria, G. Krylova, E. Shevchenko, D.V. Talapin, G.C. Schatz and R. D. Schaller Nano Lett. 2012, 12 (11), 5797 |
On the Origin of Photoluminescence in Silicon Nanocrystals: Pressure-Dependent Structural and Optical Studies D.C. Hannah, J.Yang, P. Podsiadlo, M. Chan, A. Demortiere, D.J. Gosztola, V.B. Prakapenka, G.C. Schatz, U. Kortshagen, and R.D. Schaller Nano Lett. 2012, 12 (8), 4200 |
2011
Observation of Size-Dependent Thermalization in CdSe Nanocrystals using Time-Resolved Photoluminescence Spectroscopy D.C. Hannah, N.J. Dunn, S. Ithurria, D.V. Talapin, L.X. Chen, M. Pelton, G.C. Schatz and R.D. Schaller Phys. Rev. Lett. 2011, 107, 177403 |