2021

112) Postsynthetically Modified Polymers of Intrinsic Microporosity (PIMs) for Capturing Toxic Gases

Jung, D.; Chen, Z.; Alayoglu, S.; Mian, M.R.; Goetjen, T.A.; Idrees, K.B.; Kirlikovali, K.O.; Islamoglu, T.; Farha, O.K. ACS Appl. Mater. Interfaces, 2021, Just Accepted Article doi.org/10.1021/acsami.0c21741

111) Small Molecules, Big Effects: Tuning Adsorption and Catalytic Properties of Metal–Organic Frameworks

Liu, X.; Kirlikovali, K.O.; Chen, Z.; Ma, K.; Idrees, K.B.; Cao, R.; Zhang, X.; Islamoglu, T.; Liu, Y.; Farha, O.K. Chem. Mater., 2021, Just Accepted Article doi.org/10.1021/acs.chemmater.0c04675

110) Transient Catenation in a Zirconium-Based Metal–Organic Framework and Its Effect on Mechanical Stability and Sorption Properties

Robison, L.; Gong, X.; Evans, A.M.; Son, F.A.; Wang, X.; Redfern, L.R.; Wasson, M.C.; Syed, Z.H.; Chen, Z.; Idrees, K.B.; Islamoglu, T.; Delferro, M.; Dichtel, W.R.; Coudert, F.-X.; Gianneschi, N.C.; Farha, O.K.  J. Am. Chem. Soc., 2021, 143, pp. 1503-1512 doi.org/10.1021/jacs.0c11266

109) Proton Conductivity via Trapped Water in Phosphonate-Based Metal–Organic Frameworks Synthesized in Aqueous Media

Afrin, U.; Mian, M.R.; Otake, K.; Drout, R.J.; Redfern, L.R.; Horike, S.; Islamoglu, T.; Farha, O.K. Inorg. Chem, 2021, 60, pp. 1086-1091 doi.org/10.1021/acs.inorgchem.0c03206

2020

108) Structural Diversity of Zirconium Metal–Organic Frameworks and Effect on Adsorption of Toxic Chemicals

Chen, Y.; Xuan, Z.; Mian, M.R.; Son, F.A.; Zhang, K.; Cao, R.; Chen, Z.; Lee, S.-J.; Idrees, K.B.; Goetjen, T.A.; Lyu, J.; Li, P.; Xia, Q.; Li, Z.; Hupp, J.T.; Islamoglu, T.; Napolitano, A.; Peterson, G.W.; Farha, O.K.  J. Am. Chem. Soc., 2020, 142, pp. 21428-21438 doi.org/10.1021/jacs.0c10400

107) Modulation of crystal growth and structure within cerium-based metal–organic frameworks

Wasson, M.C.; Otake, K.; Gong, X.; Strathman, A.R.; Islamoglu, T.; Gianneschi, N.C.; Farha, O.K.  CrystEngComm., 2020, 22, pp. 8182-8188 doi.org/10.1039/D0CE01223H

106) Reactive Porous Polymers for Detoxification of a Chemical Warfare Agent Simulant 

Jung, D.; Das, P.; Atilgan, A.; Li, P.; Hupp, J.T.; Islamoglu, T.; Kalow, J.A.; Farha, O.K.  Chem. Mater., 2020, 32, pp. 9299-9306 doi.org/10.1021/acs.chemmater.0c03160

105) Benign Integration of a Zn-Azolate Metal−Organic Framework onto Textile Fiber for Ammonia Capture 

Ran, C.; Chen, Z.; Chen, Y.; Idrees, K.B.; Hanna, S.L.; Wang, X.; Goetjen, T.A.; Sun, Q.; Islamoglu, T.; Farha, O.K.  ACS Appl. Mater. Interfaces, 2020, 12, pp. 47747-47753 doi.org/10.1021/acsami.0c14316

104) Post-Synthetically Elaborated BODIPY-based Porous Organic Polymers (POPs) for Photochemical Detoxification of a Sulfur Mustard Simulant

Atilgan, A.; Cetin, M.M.; Yu, J.; Beldjoudi, Y.; Liu, J.; Stern, C.L.; Cetin, F.M.; Islamoglu, T.; Farha, O.K.; Deria, P.; Stoddart, J.F.; Hupp, J.T. J. Am. Chem. Soc., 2020, 142, pp. 18554-18564 doi.org/10.1021/jacs.0c07784

103) Supramolecular Porous Assemblies of Atomically Precise Catalytically Active Cerium-Based Clusters

Wasson, M.C.; Zhang, X.; Otake, K.; Rosen, A.S.; Alayoglu, S.; Krzyaniak, M.D.; Chen, Z.; Redfern, L.R.; Robison, L.; Son, F.A. Chen, Y.; Islamoglu, T.; Notestein, J.M.; Snurr, R.Q.; Wasielewski, M.R.; Farha, O.K. Chem. Mater., 2020, 32, pp. 8522-8529 doi.org/10.1021/acs.chemmater.0c02740

102) Tuning the Atrazine Binding Sites in An Indium-Based Flexible Metal-Organic Framework

Chen, Y.; Zhang, X.; Chen, H.; Drout, R.J.; Chen, Z.; Mian, M.R.; Maldonado, R.R.; Ma, K.; Wang, X.; Xia, Q.; Li, Z.; Islamoglu, T.; Snurr, R.Q.; Farha, O.K.  ACS Appl. Mater. Interfaces, 2020, 12, pp. 44762-44768 doi.org/10.1021/acsami.0c13022

101) Maximizing Magnetic Resonance Contrast in Gd(III) Nanoconjugates: Investigation of Proton Relaxation in Zirconium Metal–Organic Frameworks

McLeod, S.M.; Robison, L.; Parigi, G.; Olszewski, A.; Drout, R.J.; Gong, X.; Islamoglu, T.; Luchinat, C.;  Farha, O.K.; Meade, T.J.  ACS Appl. Mater. Interfaces 2020, 12, pp. 41157-41166 doi.org/10.1021/acsami.0c13571

100) Observation of reduced thermal conductivity in a metal-organic framework due to the presence of adsorbates 

Babaei, H.; DeCoster, M.E.; Jeong, M.; Hassan, Z.M.; Islamoglu, T.; Baumgart, H.; McGaughey, A.J.H.; Redel, E.; Farha, O.K.; Hopkins, P.E.; Malen, J.A.; Wilmer, C.E.  Nat. Commun., 2020, 11, 4010 doi.org/10.1038/s41467-020-17822-0

99) Catalytic Degradation of an Oraganophosphorus Agent at Zn-OH Sites in a Metal-Organic Framework 

Mian, M.R.; Islamoglu, T.; Afrin, U.; Goswami, S.; Cao, R.; Kirlikovali, K.O.; Hall, M.G.; Peterson, G.W.; Farha, O.K.  Chem. Mater., 2020, 32, pp. 6998-7004 doi.org/10.1021/acs.chemmater.0c02373 

(Co-first and corresponding author)

98) Insights into the Structure–Activity Relationships in Metal–Organic Framework-Supported Nickel Catalysts for Ethylene Hydrogenation

Wang, X.; Zhang, X.; Pandharkar, R.; Lyu, J.; Ray, D.; Yang, Y.; Kato, S.; Liu, J.; Wasson, M.C.; Islamoglu, T.; Li, Z.; Hupp, J.T.; Cramer, C.J.; Gagliardi, L.; Farha, O.K.  ACS Catal., 2020, 10, pp. 8995-9005 doi.org/10.1021/acscatal.0c01844 

97) Isothermal Titration Calorimetry to Explore the Parameter Space of Organophosphorus Agrochemical Adsorption in MOFs

Drout, R.J.; Kato, S.; Chen, H.; Son, F.A.; Otake, K.; Islamoglu, T.; Snurr, R.Q.; Farha, O.K. J. Am. Chem. Soc., 2020, 142, pp.12375-12366 doi.org/10.1021/jacs.0c04668 

96) Process-level modelling and optimization to evaluate metal-organic frameworks for post-combustion capture of CO2

Yancy-Caballero, D.; Leperi, K.T.; Bucior, B.J.; Richardson, R.K.; Islamoglu, T.; Farha, O.K.; You, F.; Snurr, R.Q. Mol. Syst. Des. Eng., 2020, Just Accepted Article doi.org/10.1039/d0me00060d 

95) Time-Resolved in Situ Polymorphic Transformation from One 12-Connected Zr-MOF to Another

Lee, S.-J.; Mancuso, J.L.; Le, K.N.; Malliakas, C.D.; Bae, Y.-S.; Hendon, C.H.; Islamoglu, T.; Farha, O.K. ACS  Materials Lett., 2020, 2, pp. 499-504 doi.org/10.1021/acsmaterialslett.0c00012 

(Corresponding author)

Highlighted on the front cover

94) Control of the Porosity in Manganese Trimer-Based Metal−Organic Frameworks by Linker Functionalization

Mian, M.R.; Afrin, U.; Fataftah, M.S.; Idrees, K.B.; Islamoglu, T.; Freedman, D.E.; Farha, O.K.; Inorg. Chem., 2020, 59, pp. 8444-8450 dx.doi.org/10.1021/acs.inorgchem.0c00885

93) Uncovering the Role of Metal-Organic Framework Topology on the Capture and Reactivity of Chemical Warfare Agents

Son, F.A.; Wasson, M.C.; Islamoglu, T.; Chen, Z.; Gong, X.; Hanna, S.L.; Lyu, J.; Wang, X.; Idrees, K.B.; Mahle, J.J.; Peterson, G.W.; Farha, O.K.;  Chem. Mater., 2020, 32, pp. 4609-4617. doi.org/10.1021/acs.chemmater.0c00986

92) Balancing volumetric and gravimetric uptake in highly porous materials for clean energy   

Chen, Z.; Li, P.; Anderson, R.; Wang, X.; Zhang, X.; Robison, L.; Redfern, L.R.; Moribe, S.; Islamoglu, T.; Gómez-Gualdrón, D.A.; Yildirim, T.; Stoddart, J.F.; Farha, O.K.; Science, 2020, 368, pp. 297-303 doi.org/10.1126/science.aaz8881

Featured in c&en article “Hydrogen and methane-adsorbing MOF boasts impressive combination of properties”

91) Designing Porous Materials to Resist Compression: Mechanical Reinforcement of a Zr-MOF with Structural Linkers   

Robison, L.; Drout, R.J.; Redfern, L.R.; Son, F.A.; Wasson, M.C.; Goswami, S.; Chen, Z.; Olszewski, A.; Idrees, K.B.; Islamoglu, T.; Farha, O.K.; Chem. Mater., 2020, 32, pp.3545-3552. doi.org/10.1021/acs.chemmater.0c00634

90) Structural Features of Zirconium-Based Metal-Organic Frameworks Affecting Radiolytic Stability   

Hanna, S.L.; Rademacher, D.X.; Hanson, D.J.; Islamoglu, T.; Olszewski, A.K.; Nenoff, T.M.; Farha, O.K.; Ind. Eng. Chem. Res., 2020, 59, pp. 7520-7526. doi.org/10.1021/acs.iecr.9b06820

89) Precise Control of Cu Nanoparticle Size and Catalytic Activity through Pore Templating in Zr Metal-Organic Frameworks

Mian, M.R.; Redfern, L.R.; Pratik, S.M.; Ray, D.; Liu, J.; Idrees, K.B.; Islamoglu, T.; Gagliardi, L.; Farha, O.K.; Chem. Mater., 2020, 32, pp. 3078-3086 doi.org/10.1021/acs.chemmater.0c00059

Chemistry of Materials “most read articles” for April 2020

88) Tailoring Pore Aperture and Structural Defects in Zirconium-Based Metal-Organic Frameworks for Krypton/Xenon Separation 

Idrees, K.B.; Chen, Z.; Zhang, X.; Mian, M.R.; Drout, R.J.; Islamoglu, T.; Farha, O.K.; Chem. Mater., 2020, 32, pp. 3776-3782 doi.org/10.1021/acs.chemmater.9b05048

87) A Flexible Interpenetrated Zirconium-Based Metal-Organic-Framework with High Affinity toward Ammonia 

Zhang, Y.; Zhang, X.; Chen, Z.; Otake, K.; Peterson, G.; Chen, Y.; Wang, X.; Redfern, L.; Goswami, S.; Li, P.; Islamoglu, T.; Wang, B.; Farha, O.K.; ChemSusChem, 2020, 13, pp. 1710-1714 doi.org/10.1002/cssc.202000306

86) Solvent-assisted linker exchange enabled preparation of cerium-based metal–organic frameworks constructed from redox active linkers

Son, F.A.; Atilgan, A.; Idrees, K.B.; Islamoglu, T.; Farha, O.K.; Inorg. Chem. Front., 2020, 7, pp. 984-990 doi.org/10.1039/c9qi01218d

85) Tuning the Redox Activity of Metal−Organic Frameworks for Enhanced, Selective O2 Binding: Design Rules and Ambient Temperature O2 Chemisorption in a Cobalt-Triazolate Framework

Rosen, A.S.; Mian, M.R.; Islamoglu, T.; Chen, H.; Farha, O.K.; Notestein, J.M.; Snurr, R.Q.; J. Am. Chem. Soc., 2020, 142, pp. 4317-4328 doi.org/10.1021/jacs.9b12401 

Available on ChemRxiv 

2019

84) Metal–Organic-Framework-Supported and -Isolated Ceria Clusters with Mixed Oxidation States

Liu, J.; Redfern, L.R.; Liao, Y.; Islamoglu, T.; Atilgan, A.; Farha, O.K.; Hupp, J.T.; ACS Appl. Mater. Interfaces,  2019, 11, pp. 47822-47829 doi.org/10.1021/acsami.9b12261

83) Integration of Metal–Organic Frameworks on Protective Layers for Destruction of Nerve Agents under Relevant Conditions

Chen, Z.; Ma, K.; Mahle, J.J.; Wang, H.; Syed, Z.H.; Atilgan, A.; Chen, Y.; Xin, J.H.; Islamoglu, T.; Peterson, G.W.; Farha, O.K.; J. Am. Chem. Soc., 2019, 141, pp. 20016-20021 doi.org/10.1021/jacs.9b11172

Featured in c&en article “MOFs neutralize nerve agents without needing liquid water”

82) Scalable and Template-Free Aqueous Synthesis of Zirconium-Based Metal–Organic Framework Coating on Textile Fiber

Ma, K.; Islamoglu, T.; Chen, Z.; Li, P.; Wasson, M.C.; Chen, Y.; Wang, Y.; Peterson, G.W.; Xin, J.H.; Farha, O.K.; J. Am. Chem. Soc.; 2019, 141, pp. 15626-15633 doi.org/10.1021/jacs.9b07301

81) Controlling the Polymorphism and Topology Transformation in Porphyrinic Zirconium Metal-Organic Frameworks via Mechanochemistry

Karadeniz, B.; Žilić, D.; Huskić, I.; Germann, L.S.; Fidelli, A.M.; Muratović, S.; Lončarić, I.; Etter, M.; Dinnebier, R.E.; Barišić, D.; Cindro, N.; Islamoglu, T.; Farha, O.K.; Friscic, T.; Uzarevic, K.; J. Am. Chem. Soc.; 2019, 141, pp. 19214-19220 doi.org/10.1021/jacs.9b10251

Available on ChemRxiv

80) Zirconium-Based Metal–Organic Framework with 9-Connected Nodes for Ammonia Capture

Chen, Y.; Zhang, X.; Ma, K.; Chen, Z.; Wang, X.; Knapp, J.; Alayoglu, S.; Wang, F.; Xia, Q.; Li, Z.; Islamoglu, T.; Farha, O.K.; ACS Appl. Nano Mater.; 2019, 2, pp. 6098-6102 doi.org/10.1021/acsanm.9b01534\

Available on ChemRxiv

79) Interplay of Lewis and Brønsted Acid Sites in Zr-Based Metal-Organic Frameworks for Efficient Esterification of Biomass-Derived Levulinic Acid 

Wang, F.; Chen, Z.; Chen, H.; Goetjen, T.A.; Li, P.; Wang, X.; Alayoglu, S.; Ma, K.; Chen, Y.; Wang, T.; Islamoglu, T.; Fang, Y.; Snurr, R.Q.; Farha, O.K.; ACS Appl. Mater. Interfaces; 2019, 11, pp. 32090-32096 doi.org/10.1021/acsami.9b07769

 

78) Metal-Organic Frameworks: A Tunable Platform to Access Single-Site Heterogeneous Catalysts

Wasson, M.C.; Buru, C.T.; Chen, Z.; Islamoglu, T.; Farha, O.K.; Applied Catalysis A, General; 2019, 586, pp. 117214 doi.org/10.1016/j.apcata.2019.117214

 

77) Air Oxidation of Sulfur Mustard Gas Simulant Using a Pyrene-Based Metal-Organic Framework Photocatalyst

Ayoub, G.; Arhangelskis, M.; Zhang, X.; Son, F.A.; Islamoglu, T.; Friščić, T.; Farha, O.K.; Beilstein J. Nanotechnol., 2019, 10, pp. 2422-2427 doi.org/10.3762/bjnano.10.232

 

 

    76) Mechanistic Study on the Origin of the Trans Selectivity in Alkyne Semihydrogenation by a Heterobimetallic Rhodium-Gallium Catalyst in a Metal-Organic Framework
    Desai, S.; Ye, J.; Islamoglu, T.; Farha, O.K.; Lu, C.C.; Organometallics; 2019, 38, pp. 3466-3473 doi.org/10.1021/acs.organomet.9b00331

     

       

      75) Modular Synthesis of Highly Porous Zr-MOFs Assembled from Simple Building Blocks for Oxygen StorageLyu, J.; Zhang, X.; Chen, Z.; Anderson, R.; Wang, X.; Wasson, M.C.; Bai, P.; Guo, X.; Islamoglu, T.; Gómez-Gualdrón, D.A.; Farha, O.K.; ACS Appl. Mater. Interfaces, 2019, 11, pp. 42179-42185 doi.org/10.1021/acsami.9b144

       

       

       

      74) “Ammonia Capture within Isoreticular Metal–Organic Frameworks with Rod Secondary Building Units” Moribe, S.; Chen, Z.; Alayoglu, S.; Syed, Z. H.; Islamoglu, T.; Farha, O. K., ACS Materials Letters 2019, 1, (4), 476-480. doi.org/10.1021/acsmaterialslett.9b00307

      Abstract Image

      73) “Air oxidation of sulfur mustard gas simulants using a pyrene-based metal–organic framework photocatalyst” Ayoub, G.; Arhangelskis, M.; Zhang, X.; Son, F.; Islamoglu, T.; Friščić, T.; Farha, O. K., Beilstein Journal of Nanotechnology 2019, 10, 2422-2427. doi:10.3762/bjnano.10.232

      72) “Controlling the Polymorphism and Topology Transformation in Porphyrinic Zirconium Metal–Organic Frameworks via Mechanochemistry” Karadeniz, B.; Žilić, D.; Huskić, I.; Germann, L. S.; Fidelli, A. M.; Muratović, S.; Lončarić, I.; Etter, M.; Dinnebier, R. E.; Barišić, D.; Cindro, N.; Islamoglu, T.; Farha, O. K.; Friščić, T.; Užarević, K., J Am Chem Soc 2019, 141, (49), 19214-19220. 

      Abstract Image

      71) Metal-Organic Frameworks: A Tunable Platform to Access Single-Site Heterogeneous Catalysts

      Wasson, M.C.; Buru, C.T.; Chen, Z.; Islamoglu, T.; Farha, O.K.; Applied Catalysis A, General; 2019, 586, pp. 117214 doi.org/10.1016/j.apcata.2019.117214

      70) “Interplay of Lewis and Brønsted Acid Sites in Zr-Based Metal-Organic Frameworks for Efficient Esterification of Biomass-Derived Levulinic Acid” 

      Wang, F.; Chen, Z.; Chen, H.; Goetjen, T.A.; Li, P.; Wang, X.; Alayoglu, S.; Ma, K.; Chen, Y.; Wang, T.; Islamoglu, T.; Fang, Y.; Snurr, R.Q.; Farha, O.K.; ACS Appl. Mater. Interfaces; 2019, 11, pp. 32090-32096 doi.org/10.1021/acsami.9b07769

       

      69) “Mechanistic Study on the Origin of the Trans Selectivity in Alkyne Semihydrogenation by a Heterobimetallic Rhodium–Gallium Catalyst in a Metal–Organic Framework” Desai, S. P.; Ye, J.; Islamoglu, T.; Farha, O. K.; Lu, C. C., Organometallics 2019, 38, (18), 3466-3473.

       Abstract Image

      68) “Modular Synthesis of Highly Porous Zr-MOFs Assembled from Simple Building Blocks for Oxygen Storage” Lyu, J.; Zhang, X.; Chen, Z.; Anderson, R.; Wang, X.; Wasson, M. C.; Bai, P.; Guo, X.; Islamoglu, T.; Gómez-Gualdrón, D. A.; Farha, O. K., ACS Applied Materials & Interfaces 2019, 11, (45), 42179-42185.

      Abstract Image

      67) “Realization of Lithium-Ion Capacitors with Enhanced Energy Density via the Use of Gadolinium Hexacyanocobaltate as a Cathode Material” Zhang, K.; Lee, T. H.; Noh, H.; Islamoglu, T.; Farha, O. K.; Jang, H. W.; Choi, J.-W.; Shokouhimehr, M., ACS Applied Materials & Interfaces 2019, 11, (35), 31799-31805.

       Abstract Image

      66) “Zirconium-Based Metal–Organic Framework with 9-Connected Nodes for Ammonia Capture” Chen, Y.; Zhang, X.; Ma, K.; Chen, Z.; Wang, X.; Knapp, J.; Alayoglu, S.; Wang, F.; Xia, Q.; Li, Z.; Islamoglu, T.; Farha, O. K., ACS Applied Nano Materials 2019, 2, (10), 6098-6102.

      Abstract Image

      65) “Ligand-Directed Reticular Synthesis of Catalytically Active Missing Zirconium-Based Metal–Organic Frameworks” Chen, Z.; Li, P.; Wang, X.; Otake, K.-i.; Zhang, X.; Robison, L.; Atilgan, A.; Islamoglu, T.; Hall, M. G.; Peterson, G. W.; Stoddart, J. F.; Farha, O. K., J. Am. Chem. Soc. 2019, 141, (31), 12229-12235. 

      Abstract Image 

      64) “Uniform, Binary Functionalization of a Metal–Organic Framework Material” Samarakoon, K. P.; Satterfield, C. S.; McCoy, M. C.; Pivaral-Urbina, D. A.; Islamoglu, T.; Day, V. W.; Gadzikwa, T., Inorganic Chemistry 2019, 58, (14), 8906-8909. https://doi.org/10.1021/acs.inorgchem.9b00838

      63) Integration of Metal-Organic Frameworks on Protective Layers for Destruction of Nerve Agents under Relevant Conditions

      Chen, Z.; Ma, K.; Mahle, J.J.; Wang, H.; Syed, Z.H.; Atilgan, A.; Chen, Y.; Xin, J.H.; Islamoglu, T.; Peterson, G.W.; Farha, O.K.; J. Am. Chem. Soc. 2019, 141, 51, 20016-20021 doi.org/10.1021/jacs.9b11172

      • 62) Metal-Organic-Framework-Supported and -Isolated Ceria Clusters with Mixed Oxidation States 

        Liu J.; Redfern L.R.; Liao, Y.; Islamoglu, T.; Atilgan, A.; Farha, O.K.; Hupp, J.T.; ACS Appl. Mater. Interfaces 2019, 11, 51, 47822-47829 doi.org/10.1021/acsami.9b12261

      • 61) Tuning the Redox Activity of Metal-Organic Frameworks for Enhanced, Selective O2 Biniding

        Rosen, A.; Mian, M.R.; Islamoglu, T.; Chen, H.; Farha, O.K.; Notestein, J.; Snurr, R.Q.; ChemRxiv; 2019, preprint doi.org/10.26434/chemrxiv.10316681.v1

      60) Facile and Scalable Coating of Metal-Organic Frameworks on Fibrous Substrates by a Coordination Replication Method at Room Temperature

      Ma, K.; Wang, Y.; Chen, Z.; Islamoglu, T.; Lai, C.; Wang, X.; Fei, B.; Farha, O.K.; Xin, J.H.; ACS Appl. Mater. Interfaces; 2019, 11, pp. 22714-22721 doi.org/10.1021/acsami.9b04780

      • 59) Cross-linked porous polyurethane materials featuring dodecaborate clusters as inorganic polyol equivalents

        Jung, D.; Raffan-Montoya, F.; Ramachandran, R.; Zhang, Y.; Islamoglu, T.; Marin, G.; Qian, E.A.; Dziedzic, R.M.; Farha, O.K.; Stoliarov, S.I.; Spokoyny, A.M.; Chem. Commun.; 2019, 55, pp. 8852-8855 doi.org/

        10.1039/C9CC03350E

      • 58) Vanadium Catalyst on Isostructural Transition Metal, Lanthanide, and Actinide Based Metal-Organic Frameworks for Alcohol Oxidation

        Wang, X.; Zhang, X.; Li, P.; Otake, K.I.; Cui, Y.; Lyu, J.; Krzyaniak, M.D.; Zhang, Y.; Li, Z.; Liu, J.; Buru, C.T.; Islamoglu, T.; Wasielewski, M.R.; Li, Z.; Farha, O.K.; J. Am. Chem. Soc.; 2019, 141, pp. 8306-8314 doi.org/10.1021/jacs.9b02603

      • 57) Zirconium Metal-Organic Frameworks for Organic Pollutant Adsorption

        Drout, R.J.; Robison, L.; Chen, Z.; Islamoglu, T.;  Farha, O.K.; Trends in Chemistry; 2019, 3, pp. 304-317 doi.org/10.1016/j.trechm.2019.03.010

        Featured on the cover

      •  56) Enhanced Activity of Heterogeneous Pd(II) Catalysts on Acid-Functionalized Metal-Organic Frameworks 

        Otake, K.I.; Ye, J.; Mandal, M.; Islamoglu, T.; Buru, C.T.; Hupp, J.T.; Delferro, M.; Truhlar, D.; Cramer, C.J.; Farha, O.K.; ACS Catal.; 2019, 9, pp. 5383-5390 doi.org/10.1021/acscatal.9b01043

      • 54) Torsion Angle Effect on the Activation of UiO Metal-Organic Frameworks 

        Ayoub, G.; Islamoglu, T.; Goswami, S.; Friščić, T.; Farha, O.K.; ACS Appl. Mater. Interfaces; 2019, 11, pp. 15788-15794 doi.org/10.1021/acsami.9b02764

      • 53) Scalable, room temperature, and water-based synthesis of functionalized zirconium-based metal-organic frameworks for toxic chemical removal

        Chen, Z.; Wang, X.; Noh, H.; Ayoub, G.; Peterson, G.W.; Buru, C.T.; Islamoglu, T.; Farha, O.K.; CrystEngComm.; 2019, 21, pp. 2409-2415 doi.org/10.1039/c9ce00213h

      • 52) Synthetic Control of Thorium Polyoxo-Clusters in Metal-Organic Frameworks toward New Thorium-Based Materials

        Li, P.; Wang, X.; Otake, K.; Lyu, J.; Hanna, S.L.; Islamoglu, T.; Farha, O.K.; ACS. Appl. Nano. Mater.; 2019, 2, pp. 2260-2265 doi.org/10.1021/acsanm.9b00188

        Featured on the cover

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      51) Porosity Dependence of Compression and Lattice Rigidity in Metal-Organic Framework Series

      Redfern, L.R.; Robison, L.; Wasson, M.C.; Goswami, S.; Lyu, J.; Islamoglu, T.; Chapman, K.W.; Farha, O.K. J. Am. Chem. Soc., 2019, 141, pp. 4365-4371 doi.org/10.1021/jacs.8b13009

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      50) A Bismuth Metal-Organic Framework as a Contrast Agent for X-ray Computed Tomography

      Robison, L.; Zhang, L.; Drout, R.J.; Li, P.; Haney, C.R.; Brikha, A.; Noh, H.; Mehdi, B.L.; Browning, N.D.; Dravid, V.P.; Cui, Q.; Islamoglu, T.; Farha, O.K. ACS Appl. Bio Mater., 2019, 2, pp. 1197-1203 doi.org/10.1021/acsabm.8b00778

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      49) Energy-based descriptors to rapidly predict hydrogen storage in metal-organic frameworks

      Bucior, B.J.; Bobbitt, N.S.; Islamoglu, T.; Goswami, S.; Gopalan, A.; Yildrim, T.; Farha, O.K.; Bagheri, N.; Snurr, R.Q. Mol. Syst. Des. Eng., 2019, 4, pp. 162-174 doi.org/10.1039/C8ME00050F

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      48) Reticular chemistry in the rational synthesis of functional zirconium cluster-based MOFs

      Chen, Z.; Hanna, S.L.; Redfern, L.R.; Alezi, D.; Islamoglu, T.; Farha, O.K. Coordin. Chem. Rev., 2019, 386, pp. 32-49 doi.org/10.1016/j.ccr.2019.01.017

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      47) Reticular Access to Highly Porous acs-MOFs with Rigid Trigonal Prismatic Linkers for Water Sorption

      Chen, Z.; Li, P.; Zhang, X.; Li, P.; Wasson, M.C.; Islamoglu, T.; Stoddart, J.F.; Farha, O.K.  J. Am. Chem. Soc., 2019, 141, pp. 2900-2905 doi.org/10.1021/jacs.8b13710

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      46) Tuning the properties of Zr6O8 nodes in the metal organic framework UiO-66 by selection of node-bound ligands and linkers

      Wei, R.; Gaggioli, C.; Li, G.; Islamoglu, T.; Zhang, Z.; Yu, P.; Farha, O.K.; Cramer, C.J.; Gagliardi, L.; Yang, D.; Gates, B.C.  Chem. Mater., 2019, 31, pp. 1655-1663 doi.org/10.1021/acs.chemmater.8b05037

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      45) Toward Base Heterogenization: A Zirconium Metal-Organic Framework/Dendrimer or Polymer Mixture for Rapid Hydrolysis of a Nerve-Agent Simulant

      Chen, Z.; Islamoglu, T.; Farha, O.K.  ACS Appl. Mater. Interfaces, 2019, 2, pp. 1005-1008 doi.org/10.1021/acsanm.8b02292

       

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      44) Exploiting π-π Interactions to Design an Efficient Sorbent for Atrazine Removal from Water

      Akpinar, I.; Drout, R.J.; Islamoglu, T.; Kato, S.; Lyu, J.; Farha, O.K.  ACS Appl. Mater. Interfaces, 2019, 11, pp. 6097-6103 doi.org/10.1021/acsami.8b20355

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      43) Zirconium-Based Metal-Organic Frameworks for the Removal of Protein-Bound Uremic Toxic from Human Serum Albumin

      Kato, S.; Otake, K.; Chen, H.; Akpinar, I.; Buru, C.T.; Islamoglu, T.; Snurr, R.Q.; Farha, O.K.  J. Am. Chem. Soc., 2019, 141, pp. 2568-2576 doi.org/10.1021/jacs.8b12525

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      42) Direct Imaging of Isolated Single Molecule Magnets in Metal-Organic Frameworks

      Aulakh, D.; Liu, L.; Varghese, J.R.; Xie, H.; Islamoglu, T.; Duell, K.; Kung, C.; Hsiung, C.; Zhang, Y.; Drout, R.J.; Farha, O.K.; Dunbar, K.R.; Han, Y.; Wriedt, M. J. Am. Chem. Soc., 2019, 141, pp. 2997-3005 doi.org/10.1021/jacs.8b11374

       

      41) Linker Competition within a Metal-Organic Framework for Topological Insights

      Wasson, M.C.; Lyu, J.; Islamoglu, T.; Farha, O.K. Inorg. Chem., 2019, 58, pp. 1513-1517 doi.org/10.1021/acs.inorgchem.8b03025

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      40) Guest-Dependent Single-Crystal-to-Single-Crystal Phase Transitions in a Two-Dimensional Uranyl-Based Metal-Organic Framework

      Hanna, S.L.; Zhang, X.; Otake, K.; Drout, R.J.; Li, P.; Islamoglu, T.; Farha, O.K. Cryst. Growth Des., 2019, 19, 506-512. doi.org/10.1021/acs.cgd.8b01689

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      39) Topology and Porosity Control of Metal-Organic Frameworks through Linker Functionalization

      Lyu, J.; Zhang, X.; Otake, K.; Wang, X.; Li, P.; Li, Z.; Chen, Z.; Zhang Y.; Wasson, M.C.; Yang, Y.; Bai, P.; Guo, X.; Islamoglu, T.; Farha, O.K. Chem. Sci., 2019, 10, pp. 1186-1192 doi.org/10.1039/C8SC04220A

      2018

      38) Efficient extraction of inorganic selenium from water by a Zr metal-organic framework: investigation of volumetric uptake capacity and binding motifs

      Drout, R.J.; Howarth, A.J.; Otake, K.; Islamoglu, T.; Farha, O.K. CrystEngComm. 2018, 20, 6140-6145. doi.org/10.1039/C8CE00992A

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      37) Rational Design of Pore Size and Functionality in a Series of Isoreticular Zwitterionic Metal–Organic Frameworks

       

      Aulakh, D.*; Islamoglu, T*.; Bagundes, V. F.; Varghese, J. R.; Duell, K.; Joy, M.; Teat, S. J.; Farha, O. K.; Wriedt, M. Chem. Mater., 2018, 30, 8332-8342 DOI: 10.1021/acs.chemmater.8b03885

      (*equal contribution)

       

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      36) Benign by Design: Green and Scalable Synthesis of Zirconium UiO-Metal–Organic Frameworks by Water-Assisted Mechanochemistry

       

      Karadeniz, B.; Howarth, A. J.; Stolar, T.; Islamoglu, T.; Dejanovic, I.; Tireli, M.; Wasson, M. C.; Moon, S. Y.; Farha, O. K; Uzarevic, K. ACS Sustainable Chem. Eng., 2018, 6, 15841-15849 DOI: 10.1021/acssuschemeng.8b04458

      3

       

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      35) From Transition Metals to Lanthanides to Actinides: Metal-Mediated Tuning of Electronic Properties of Isostructural Metal–Organic Frameworks

       

      Islamoglu, T.; Ray, D.; Li, P.; Majewski, M. B.; Akpinar, I.; Zhang, X.; Cramer, C. J.; Gagliardi, L.; Farha, O. K. Inorg. Chem., 2018, 57, 13246-13251 DOI: 10.1021/acs.inorgchem.8b01748

       (*corresponding author)

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      34) A Flexible Metal-Organic Framework with 4-connected Zr6 nodes

       

      Zhang, Y.; Zhang, X.; Lyu, J.; Otake, K.; Wang, X.; Redfern, L. R.; Malliakas, C. D.; Li, Z.; Islamoglu, T.; Bo Wang, B.; Farha, O. K. J. Am. Chem., 2018, 140, 11179-11183

      33) Revisiting the Structural Homogeneity of NU-1000, a Zr-based Metal-Organic Framework

      Islamoglu, T.*; Otake, K.; Li, P.; Buru, C. T.; Peters, A. W.; Akpinar, I.; Garibay, S. J.; Farha, O. K.* CrystEngComm, 2018, 20, 5913-5918 (*corresponding author)

      32) NanoMOFs: little crystallites for substantial applications

      Majewski, M. B.; Noh, H.; Islamoglu, T.; Farha, O. K., Journal of Materials Chemistry A 2018, 6, 7338-7350.

      31) A porous, electrically conductive hexa- zirconium(iv) metal-organic framework

      Goswami, S.; Ray, D.; Otake, K.-i.; Kung, C.-W.; Garibay, S. J.; Islamoglu, T.; Atilgan, A.; Cui, Y.; Cramer, C. J.; Farha, O. K.; Hupp, J. T., Chemical Science 2018.

          

      30) “Computer-aided discovery of a metal-organic framework with superior oxygen uptake”

      Moghadam, P. Z.; Islamoglu, T.; Goswami, S.; Exley, J.; Fantham, M.; Kaminski, C. F.; Snurr, R. Q.; Farha, O. K.; Fairen-Jimenez, D., Nat. Commun. 2018, 9, (1), 1378.

      MOF Explorer Tool: http://aam.ceb.cam.ac.uk/mof-explorer/

       

      29) “Presence vs. proximity: the role of pendant amines in the catalytic hydrolysis of a nerve agent simulant”

      Islamoglu, T.: Ortuño, M. A.; Proussaloglou, E.; Howarth, A. J.; Vermeulen, N. A.; Atilgan, A.; Asiri, A.; Cramer, C. J.; Farha, O. K.,  Angew. Chem. Int. Ed. 2018, 57, (7), 1949-1953.

      Selected as Hot Paper

       

      28) “Photoexcited Naphthalene Diimide Radical Anion Linking the Nodes of a Metal-Organic Framework: A Heterogeneous Super-reductant”

      Goswami, S.; Nelson, J. N.; Islamoglu, T.; Wu, Y.-L.; Farha, O. K.; Wasielewski, M. R.,  Chem. Mater. 2018.  DOI: 10.1021/acs.chemmater.8b00720

       

      27) “Room Temperature Synthesis of an 8-Connected Zr-Based Metal-Organic Framework for Top-Down Nanoparticle Encapsulation”

      Noh, H.; Kung, C.-W.; Islamoglu, T.; Peters, A. W.; Liao, Y.; Li, P.; Garibay, S. J.; Zhang, X.; DeStefano, M. R.; Hupp, J. T.; Farha, O. K., Chem. Mater. 2018, 30, (7), 2193-2197.

       

      26) “Benchmark Study of Hydrogen Storage in Metal-Organic Frameworks under Temperature and Pressure Swing Conditions”

      García-Holley, P.; Schweitzer, B.; Islamoglu, T.; Liu, Y.; Lin, L.; Rodriguez, S.; Weston, M. H.; Hupp, J. T.; Gómez-Gualdrón, D. A.; Yildirim, T.; Farha, O. K., ACS Energy Lett. 2018, 3, (3), 748-754.

      Energy Focus

       

      25) “Efficient Capture of Perrhenate and Pertechnetate by a Mesoporous Zr Metal-Organic Framework and Examination of Anion Binding Motifs.”

      Drout, R. J.; Otake, K.; Howarth, A. J.; Islamoglu, T.; Zhu, L.; Xiao, C.; Wang, S.; Farha, O. K., Chem. Mater. 2018, 30, (4), 1277-1284.

      Featured as Front Cover

       

      24) “Lignin‐derived heteroatom‐doped porous carbons for supercapacitor and CO2 capture applications”

      Demir, M.; Tessema, T. D.; Farghaly, A. A.; Nyankson, E.; Saraswat, S. K.; Aksoy, B.; Islamoglu, T.; Collinson, M. M.; El‐Kaderi, H. M.; Gupta, R. B., Int. J. Energy Res. 2018, https://doi.org/10.1002/er.4058

       

      Joseph T. Hupp 60th Birthday Forum 

      About the Cover:

      Self-assembled atomically ordered porous materials, metal–organic frameworks (MOFs), have been employed as platform materials for many potential applications such as catalysis, gas storage/separation, energy storage, and drug delivery because of the highly tunable nature of MOFs.

      Cover art by Dr. Timur Islamoglu.

       

      23) “Cerium(IV) Vs Zirconium(IV) Based Metal-Organic Frameworks for Detoxification of a Nerve Agent“

      Islamoglu, T.; Atilgan, A.; Moon, S. Y.; Peterson, G. W.; DeCoste, J. B.; Hall, M.; Hupp, J. T.; Farha, O. K. Chem. Mater. 2017, 29, 2672-2675.

      Link

      22) “Postsynthetic Tuning of Metal-Organic Frameworks for Targeted Applications“

      Islamoglu, T.; Goswami, S.; Li, Z.; Howarth, A. J.; Farha, O. K.; Hupp, J. T. Acc. Chem. Res. 2017, 50, 805-813.

      Link

      21) “Selective Metal–Organic Framework Catalysis of Glucose to 5-Hydroxymethylfurfural Using Phosphate-Modified NU-1000“

      Yabushita, M.; Li, P.; Islamoglu, T.; Kobayashi, H.; Fukuoka, A.; Farha, O. K.; Katz, A. Ind. Eng. Chem. Res. 2017, 56, 7141-7148.

      Link

      20) “Improvement of Methane–Framework Interaction by Controlling Pore Size and Functionality of Pillared MOFs“

      Razavi, S. A. A.; Masoomi, M. Y.; Islamoglu, T.; Morsali, A.; Xu, Y.; Hupp, J. T.; Farha, O. K.; Wang, J.; Junk, P. C. Inorg. Chem. 2017, 56, 2581-2588.

      Link

      19) “Benzothiazole- and Benzoxazole-Linked Porous Polymers for Carbon Dioxide Storage and Separation“

      Rabbani, M. G.; Islamoglu, T.; El-Kaderi, H. M. J. Mater. Chem. A 2017, 5, 258-265.

      Link

      18) “Noninvasive Substitution of K+ Sites in Cyclodextrin Metal–Organic Frameworks by Li+ Ions“

      Patel, H. A.; Islamoglu, T.; Liu, Z.; Nalluri, S. K. M.; Samanta, A.; Anamimoghadam, O.; Malliakas, C. D.; Farha, O. K.; Stoddart, J. F. J. Am. Chem. Soc. 2017, 139, 11020-11023.

      Link

      17) “Atomistic Approach toward Selective Photocatalytic Oxidation of a Mustard-Gas Simulant: A Case Study with Heavy-Chalcogen-Containing PCN-57 Analogues“

      Goswami, S.; Miller, C. E.; Logsdon, J. L.; Buru, C. T.; Wu, Y. L.; Bowman, D. N.; Islamoglu, T.; Asiri, A. M.; Cramer, C. J.; Wasielewski, M. R.; Hupp, J. T.; Farha, O. K. ACS Appl. Mater. Interfaces 2017, 9, 19535-19540.

      Link

      16) “Room-Temperature Synthesis of Uio-66 and Thermal Modulation of Densities of Defect Sites“

      DeStefano, M. R.; Islamoglu, T.; Garibay, S. J.; Hupp, J. T.; Farha, O. K. Chem. Mater. 2017, 29, 1357-1361.

      Link

      15) “Metal-Organic Frameworks for the Removal of Toxic Industrial Chemicals and Chemical Warfare Agents“

      Bobbitt, N. S.; Mendonca, M. L.; Howarth, A. J.; Islamoglu, T.; Hupp, J. T.; Farha, O. K.; Snurr, R. Q. Chem. Soc. Rev. 2017, 46, 3357-3385.

      Link

      14) “Detoxification of a Sulfur Mustard Simulant Using a Bodipy-Functionalized Zirconium-Based Metal-Organic Framework“

      Atilgan, A.; Islamoglu, T.; Howarth, A. J.; Hupp, J. T.; Farha, O. K. ACS Appl. Mater. Interfaces 2017, 9, 24555-24560.

      Link

      13) “Enhanced Carbon Dioxide Capture from Landfill Gas Using Bifunctionalized Benzimidazole-Linked Polymers“

      Islamoglu, T.; Behera, S.; Kahveci, Z.; Tessema, T. D.; Jena, P.; El-Kaderi, H. M. ACS Appl. Mater. Interfaces 2016, 8, 14648-14655.

      Link

      12) “Systematic Postsynthetic Modification of Nanoporous Organic Frameworks for Enhanced CO2 Capture from Flue Gas and Landfill Gas“

      Islamoglu, T.; Kim, T.; Kahveci, Z.; El-Kadri, O. M.; El-Kaderi, H. M. J. Phys. Chem. C 2016, 120, 2592-2599.

      Link

      11) “Tuning the Surface Chemistry of Metal Organic Framework Nodes: Proton Topology of the Metal-Oxide-Like Zr6 Nodes of Uio-66 and NU-1000“

      Yang, D.; Bernales, V.; Islamoglu, T.; Farha, O. K.; Hupp, J. T.; Cramer, C. J.; Gagliardi, L.; Gates, B. C. J. Am. Chem. Soc. 2016, 138, 15189-15196.

      Link

      10) “Combining Solvent-Assisted Linker Exchange and Transmetallation Strategies to Obtain a New Non-Catenated Nickel (Ii) Pillared-Paddlewheel MOF“

      Xu, Y.; Howarth, A. J.; Islamoglu, T.; da Silva, C. T.; Hupp, J. T.; Farha, O. K. Inorg. Chem. Commun. 2016, 67, 60-63.

      Link

      9) “A Cost-Effective Synthesis of Heteroatom-Doped Porous Carbons as Efficient CO2 Sorbents“

      Ashourirad, B.; Arab, P.; Islamoglu, T.; Cychosz, K. A.; Thommes, M.; El-Kaderi, H. M. J. Mater. Chem. A 2016, 4, 14693-14702.

      Link

      8) “An Ultra-Microporous Organic Polymer for High Performance Carbon Dioxide Capture and Separation“

      Sekizkardes, A. K.; Culp, J. T.; Islamoglu, T.; Marti, A.; Hopkinson, D.; Myers, C.; El-Kaderi, H. M.; Nulwala, H. B. Chem. Commun. 2015, 51, 13393-13396.

      Link

      7) “Synthesis and Evaluation of Porous Azo-Linked Polymers for Carbon Dioxide Capture and Separation“

      Arab, P.; Parrish, E.; Islamoglu, T.; El-Kaderi, H. M. J. Mater. Chem. A 2015, 3, 20586-20594.

      Link

      6) “Effect of Acid-Catalyzed Formation Rates of Benzimidazole-Linked Polymers on Porosity and Selective CO2 Capture from Gas Mixtures“

      Altarawneh, S.; Islamoglu, T.; Sekizkardes, A. K.; El-Kaderi, H. M. Environ. Sci. Technol. 2015, 49, 4715-4723.

       

      Link

      5) “Application of Pyrene-Derived Benzimidazole-Linked Polymers to CO2 Separation under Pressure and Vacuum Swing Adsorption Settings“

      Sekizkardes, A. K.; Islamoglu, T.; Kahveci, Z.; El-Kaderi, H. M. J. Mater. Chem. A 2014, 2, 12492-12500.

      Link

      4) “Highly Selective CO2 Capture by Triazine-Based Benzimidazole-Linked Polymers“

      Sekizkardes, A. K.; Altarawneh, S.; Kahveci, Z.; Islamoglu, T.; El-Kaderi, H. M. Macromolecules 2014, 47, 8328-8334.

      Link

      3) “Copper(I)-Catalyzed Synthesis of Nanoporous Azo-Linked Polymers: Impact of Textural Properties on Gas Storage and Selective Carbon Dioxide Capture“

      Arab, P.; Rabbani, M. G.; Sekizkardes, A. K.; Islamoglu, T.; El-Kaderi, H. M. Chem. Mater. 2014, 26, 1385-1392.

       

       

      Front cover is designed by Timur Islamoglu

      Link

      2) “Impact of Post-Synthesis Modification of Nanoporous Organic Frameworks on Small Gas Uptake and Selective CO2 Capture“

      Islamoglu, T.; Rabbani, M. G.; El-Kaderi, H. M. J. Mater. Chem. A 2013, 1, 10259-10266.

      Link

      1) “Targeted Synthesis of a Mesoporous Triptycene-Derived Covalent Organic Framework“

      Kahveci, Z.; Islamoglu, T.; Shar, G. A.; Ding, R.; El-Kaderi, H. M. CrystEngComm 2013, 15, 1524-1527.

       

      Link