Publications

60  
A Dimeric Hydride-Bridged Complex with Geometrically Distinct Iron Centers Giving Rise to an S = 3 Ground State
Hickey, A. K.; Greer, S.; Valdez-Moreira, J.; Lutz, S. A.; Pink, M.; DeGayner, J. A.; Harris, T. D.; Hill, S.; Telser, J.; Smith, J. M. J. Am. Chem. Soc. 2019, Just accepted.
59  
A Series of Early Lanthanide Chloranilate Frameworks with a Square Grid Topology
Hua, C.; Tay, H. M.; He, Q.; Harris, T. D. Aust. J. Chem. 2019, DOI: 10.1071/CH19193.
58  
Thiosemiquinoid Radical-Bridged CrIII2 Complexes with Strong Magnetic Exchange Coupling
Hua, C.; DeGayner, J. A.; Harris, T. D. Inorg. Chem. 2019, 58, 7044–7053.
57  
Selective Binding and Quantitation of Calcium with a Cobalt-Based Magnetic Resonance Probe
Du, K.; Thorarinsdottir, A. E.; Harris, T. D. J. Am. Chem. Soc. 2019, 141, 7163–7172.
56  
Reversible Redox Switching of Magnetic Order and Electrical Conductivity in a 2D Manganese Benzoquinoid Framework
Liu, L.; DeGayner, J. A.; Sun, L.; Zee, D. Z.; Harris, T. D. Chem. Sci. 2019, 10, 4652–4661.
55  
54  
Electronic Effects of Ligand Substitution in a Family of CoII2 PARACEST pH Probes
Thorarinsdottir, A. E.; Tatro, S. M.; Harris, T. D. Inorg. Chem. 2018, 57, 11252–11263.
53  
Harnessing Structural Dynamics in a 2D Manganese-Benzoquinoid Framework to Dramatically Accelerate Metal Transport in Diffusion-Limited Metal Exchange Reactions
Liu, L.; Li, L.; DeGayner, J. A.; Winegar, P.; Fang, Y.; Harris, T. D. J. Am. Chem. Soc. 2018, 140, 11444–11453.
52  
A Ferric Semiquinoid Single-Chain Magnet via Thermally-Switchable Metal-Ligand Electron Transfer
DeGayner, J. A.; Wang, K.; Harris, T. D. J. Am. Chem. Soc. 2018, 140, 6550–6553.
51  
Effect of Magnetic Coupling on Water Proton Relaxivity in a Series of Transition Metal-Gd(III) Complexes
Lilley, L. M.; Du, K.; Krzyaniak, M. D.; Parigi, G.; Luchinat, C.; Harris, T. D.; Meade, T. J. Inorg. Chem. 2018, 57, 5810–5819.
50  
A Structurally-Characterized Peroxomanganese(IV) Porphyrin from Reversible O2 Binding within a Metal-Organic Framework
Gallagher, A. T.; Lee, J. Y.; Kathiresan, V.; Anderson, J. S.; Hoffman, B. M.; Harris, T. D. Chem. Sci. 2018, 9, 1596–1603.
49  
pH-Dependent Spin State Population and 19F NMR Chemical Shift via Remote Ligand Protonation in an Iron(II) Complex
Gaudette, A. I.; Thorarinsdottir, A. E.; Harris, T. D. Chem. Commun. 2017, 53, 12962–12965.
48  
Ratiometric pH Imaging with a CoII2 MRI Probe via CEST Effects of Opposing pH Dependences
Thorarinsdottir, A. E.; Du, K.; Collins, J. H. P.; Harris, T. D. J. Am. Chem. Soc. 2017, 139, 15836–15847.
47  
A Porous Array of Clock Qubits
Zadrozny, J. M.; Gallagher, A. T.; Harris, T. D.; Freedman, D. E. J. Am. Chem. Soc. 2017, 139, 7089–7094.
46  
Ratiometric Quantitation of Redox Status with a Molecular Fe2 Magnetic Resonance Probe
Du, K.; Waters, E. A.; Harris, T. D. Chem. Sci. 2017, 8, 4424–4430.
45  
Spectroscopic and Computational Studies of Spin States of Iron(IV) Nitrido and Imido Complexes
Bucinsky, L.; Breza, M.; Lee, W.-T.; Hickey, A. K.; Dickie, D. A.; Nieto, I.; DeGayner, J. A.; Harris, T. D.; Meyer, K.; Krzystek, J.; Ozarowski, A.; Nehrkorn, J.; Schnegg, A.; Holldack, K.; Herber, R. H.; Telser, J.; Smith, J. M. Inorg. Chem. 2017, 56, 4751–4768.
44  
43  
2D Conductive Iron-Quinoid Magnets Ordering up to Tc = 105 K via Heterogenous Redox Chemistry
DeGayner, J. A.; Jeon, I.-R.; Sun, L.; Dincă, M.; Harris, T. D. J. Am. Chem. Soc. 2017, 139, 4175–4184.
42  
Spin-Crossover and High-Spin Iron(II) Complexes as Chemical Shift 19F Magnetic Resonance Thermometers
Thorarinsdottir, A. E.; Gaudette, A. I.; Harris, T. D. Chem. Sci. 2017, 8, 2448–2456.
41  
A Structurally-Characterized Zinc 2,5-Diiminobenzoquinoid Chain Compound
Liu, L.; Harris, T. D. Inorg. Chim. Acta 2016, 460, 108–113. (Invited “Inorganic Chemistry – The Next Generation” Article).
40  
39  
High-Throughput Synthesis and Characterization of Nanocrystalline Porphyrinic Zirconium Metal-Organic Frameworks
Kelty, M. L.; Morris, W.; Gallagher, A. T.; Anderson, J. S.; Brown, K. A.; Mirkin, C. A.; Harris, T. D. Chem. Commun. 2016, 52, 7854–7857.
38  
Solid-State Redox Switching of Magnetic Exchange and Electronic Conductivity in a Benzoquinoid-Bridged MnII Chain Compound
Jeon, I.-R.; Sun, L.; Negru, B.; Van Duyne, R. P.; Dincă, M.; Harris, T. D. J. Am. Chem. Soc. 2016, 138, 6583–6590.
37  
Metal-Organic Frameworks as Potential Catalysts for Industrial 1-Butene Production
Liu, L.; Harris, T. D. ACS Cent. Sci. 2016, 2, 125–127 (Invited “First Reaction” Article).
36  
Dioxygen Binding at a Four-Coordinate Cobaltous Porphyrin Site in a Metal-Organic Framework: Structural, EPR, and O2 Adsorption Analysis
Gallagher, A. T.; Kelty, M. L.; Park, J. G.; Anderson, J. S.; Mason, J. A.; Walsh, J. P. S.; Collins, S. L.; Harris, T. D. Inorg. Chem. Front. 2016, 3, 536–540 (Invited “Emerging Investigators Issue” Article).
34  
A 2D Semiquinone Radical-Containing Microporous Magnet with Solvent-Induced Switching from Tc = 26 to 80 K
Jeon, I.-R.; Negru, B.; Van Duyne, R. P.; Harris, T. D. J. Am. Chem. Soc. 2015, 137, 15699–15702.
33  
Electron Hopping through Double-Exchange Coupling in a Mixed-Valence Diiminobenzoquinone-Bridged Fe2 Complex
Gaudette, A. I.; Jeon, I.-R.; Anderson, J. S.; Grandjean, F.; Long, G. J.; Harris, T. D. J. Am. Chem. Soc. 2015, 137, 12617–12626.
32  
31  
Radical Ligand-Containing Single-Molecule Magnets
Demir, S.; Jeon, I.-R.; Long, J. R.; Harris, T. D. Coord. Chem. Rev. 2015, 289, 149–176.
30  
29  
A Five-Coordinate Heme Dioxygen Adduct Isolated within a Metal-Organic Framework
Anderson, J. S.; Gallagher, A. T.; Mason, J. A.; Harris, T. D. J. Am. Chem. Soc. 2014, 136, 16489–16492.
28  
Spin Crossover Iron(II) Complexes as PARACEST MRI Thermometers
Jeon, I.-R.; Park, J. G.; Haney, C. R.; Harris, T. D. Chem. Sci. 2014, 5, 2461–2465.
27  
An Azophenine Radical-Bridged Fe2 Single-Molecule Magnet with Record Magnetic Exchange Coupling
Jeon, I.-R.; Park, J. G.; Xiao, D. J.; Harris, T. D. J. Am. Chem. Soc. 2013, 135, 16845–16848.
26  
Low-Spin Hexa-Coordinate Mn(III): Synthesis and Spectroscopic Investigation of Homoleptic Tris(pyrazolyl)borate and Tris(carbene)borate Complexes
Forshaw, A. P.; Smith, J. M.; Ozarowski, A.; Krzystek, J.; Smirnov, D.; Zvyagin, S. A.; Harris, T. D.; Karunadasa, H. I.; Zadrozny, J. M.; Schnegg, A.; Holldack, K.; Jackson, T. A.; Alamiri, A.; Barnes, D. M.; Telser, J. Inorg. Chem. 2013, 52, 144–159.

Publications from Previous Research
25  
Trigonal Mn3 and Co3 Clusters Supported by Weak-Field Ligands: A Structural, Spectroscopic, Magnetic, and Computational Investigation into the Correlation of Molecular and Electronic Structure
Fout, A. R.; Xiao, D. J.; Zhao, Q.; Harris, T. D.; King, E. R.; Eames, E. V.; Zheng, S.-L.; Betley, T. A. Inorg. Chem. 2012, 51, 10290–10299.
24  
A Canted Antiferromagnetic Ordered Phase of Cyanido-Bridged MnIII2ReIV Single-Chain Magnets
Bhowmick, I.; Dechambenoit, P.; Hillard, E. A.; Coulon, C.; Harris, T. D. Chem. Commun. 2012, 48, 9717–9719.
23  
Cyanido-Bridged One-Dimensional Systems Assembled from [ReIVCl4(CN)2]2− and [MII(cyclam)]2+ (M = Ni, Cu) Precursors
Bhowmick, I.; Harris, T. D.; Dechambenoit, P.; Hillard, E.; Pichon, C.; Jeon, I.-R.; Clérac, R. Science China Chem. 2012, 55, 1004–1012.
22  
Slow Magnetic Relaxation Induced by a Large Transverse Zero-Field Splitting in a MnIIReIV(CN)2 Single-Chain Magnet
Feng, X.; Liu, J.; Harris, T. D.; Hill, S.; Long, J. R. J. Am. Chem. Soc. 2012, 134, 7521–7529.
21  
19  
18  
Expanded Redox Accessibility via Ligand Substitution in an Octahedral Fe6Br6 Cluster
Harris, T. D.; Zhao, Q.; Hernández Sánchez, R.; Betley, T. A. Chem. Commun. 2011, 47, 6344–6346.
16  
Slow Magnetic Relaxation and Electron Delocalization in an S = 9/2 Iron(II/III) Complex with Two Crystallographically Inequivalent Iron Sites
Hazra, S.; Sasmal, S.; Fleck, M.; Grandjean, F.; Sougrati, M. T.; Ghosh, M.; Harris, T. D.; Bonville, P.; Long, G. J.; Mohanta, S. J. Chem. Phys. 2011, 134, 174507/1-13.
15  
A Cyano-Bridged FeIIReIV Cluster Incorporating Two High-Magnetic Anisotropy Building Units
Harris, T. D.; Soo, H. S.; Chang, C. J.; Long, J. R. Inorg. Chim. Acta 2011, 369, 91–96.
14  
Spin Crossover in a Four-Coordinate Iron(II) Complex
Scepaniak, J. J.; Harris, T. D.; Vogel, C. S.; Sutter, J.; Meyer, K.; Smith, J. M. J. Am. Chem. Soc. 2011, 133, 3824–3827.
13  
Record Ferromagnetic Exchange Through Cyanide and Elucidation of the Magnetic Phase Diagram for a CuIIReIV Chain Compound
Harris, T. D.; Coulon, C.; Clérac, R.; Long, J. R. J. Am. Chem. Soc. 2011, 133, 123–130.
12  
Slow Magnetic Relaxation in a Family of Trigonal Pyramidal Iron(II) Pyrrolide Complexes
Harman, W. H.; Harris, T. D.; Freedman, D. E.; Fong, H.; Chang, A.; Rinehart, J. R.; Ozarowski, A.; Sougrati, M. T.; Grandjean, F.; Long, G. J.; Long, J. R.; Chang, C. J. J. Am. Chem. Soc. 2010, 132, 18115–18126.
11  
Slow Magnetic Relaxation and Charge Transfer in Cyano-Bridged Coordination Clusters Incorporating [Re(CN)7]3−/4−
Zadrozny, J. M.; Freedman, D. E.; Jenkins, D. M.; Harris, T. D.; Iavarone, A. T.; Mathonière, C.; Clérac, R.; Long, J. R. Inorg. Chem. 2010, 49, 8886–8896.
10  
Reversible Luminescent Surface Reaction of Amines with Copper(I) Cyanide
Ley, A. N.; Dunaway, L. E.; Brewster, T. P.; Dembo, M. D.; Harris, T. D.; Baril-Robert, F.; Patterson, H. H.; Pike, R. D. Chem. Commun. 2010, 46, 4565–4567.
9  
[ReCl4(CN)2]2−: A High Magnetic Anisotropy Building Unit Giving Rise to the Single-Chain Magnets (DMF)4MReCl4(CN)2 (M = Mn, Fe, Co, Ni)
Harris, T. D.; Bennett, M. V.; Clérac, R.; Long, J. R. J. Am. Chem. Soc. 2010, 132, 3980–3988.
8  
Slow Magnetic Relaxation in a High-Spin Iron(II) Complex
Freedman, D. E.; Harman, W. H.; Harris, T. D.; Long, G. J.; Chang, C. J.; Long, J. R. J. Am. Chem. Soc. 2010, 132, 1224–1225.
7  
A Four-Shell 136-Metal 3d–4f Heterometallic Cluster Approximating a Rectangular Parallelepiped
Kong, X.-J.; Long, L.-S.; Huang, R.-B.; Zheng, L.-S.; Harris, T. D.; Zheng, Z. Chem. Commun. 2009, 4354–4356.
6  
Magnetic Exchange Coupling in Actinide-Containing Molecules
Rinehart, J. D.; Harris, T. D.; Kozimor, S. A.; Bartlett, B. M.; Long. J. R. Inorg. Chem. 2009, 48, 3382–3395.
5  
Synthesis and Characterization of the Cubic Coordination Cluster [CoIII6CoII2(IBT)12]14− (H3IBT = 4,5-bis(tetrazol-5-yl)imidazole)
Dincă, M.; Harris, T. D.; Iavarone, A. T.; Long, J. R. J. Mol. Struct. 2008, 890, 139–143.
4  
High-Spin Ni3Fe2(CN)6 and Cu3Cr2(CN)6 Clusters Based on a Trigonal Bipyramidal Geometry
Bartlett, B. M.; Harris, T. D.; DeGroot, M. W.; Long, J. R. Z. Anorg. Allg. Chem. 2007, 2380–2385.
3  
Synthesis and X-ray Crystal Structure of [(C5Ph5)CrCl(µ-Cl)2Tl]2: An Example of the Rare M-X-TlI Linkage (X = Halide)
Davis, K. B.; Harris, T. D.; Castellani, M. P.; Golen, J. A.; Rheingold, A. L. Organometallics 2007, 26, 4843–4845.
2  
Linkage Isomerism in a Face-Centered Cubic Cu6Cr8(CN)24 Cluster with an S = 15 Ground State
Harris, T. D.; Long, J. R. Chem. Commun. 2007, 1360–1362.
1  
1,1′-Diethyl-2,2′,3,3′,4,4′,5,5′-Octamethylferrocenium Tetracyanoethylenide, [Fe(C5EtMe4)2]+[TCNE], A Charge-Transfer Salt Magnetic Solid with a Novel Structural Motif
Harris, T. D.; Castellani, M. P.; Rheingold, A. L.; Reiff, W. M.; Yee, G. T. Inorg. Chim. Acta 2006, 359, 4651–4654.